Patent US3932586A successfully refreshed from Google Patents.
US3932586A
Expired / Lapsed
US
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Removal of oxides of sulfur from gases
Assignee: University of Delaware
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Filing: 1973-10-12
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Granted: 1976-01-13
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Expires: 1993-10-12
Abstract
Abstract A continuous cyclic process and apparatus for removing sulfur dioxide (and if present, sulfur trioxide) from gases produced in the combustion of fossil fuels or in chemical and metallurgical processes by means of an aqueous absorption solution including potassium carbonate to absorb said oxides out of said gases whereby potassium carbonate is converted into potassium sulfite (sulfate). A two component, two stage molten process is employed to recover potassium carbonate for reuse in the absorption step and to liberate hydrogen sulfide which may be converted to elemental sulfur by well known methods.
Inventors
- 👤 Salvatore A. Guerrieri
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 16:06
CPC Classifications
C; C01; C01B; C01B17/00; C01B17/16; C01B17/165; B; B01; B01D; B01D53/00; B01D53/34; B01D53/46; B01D53/48; B01D53/50; B01D53/501; C01B17/164
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
323 words
A process for removing sulfur dioxide from gases which includes; a. contacting said gases and absorbing sulfur dioxide therefrom with an aqueous solution containing potassium carbonate to derive a solution which includes potassium sulfite as well as potassium carbonate and withdrawing said derived solution, b. returning to step (a) a portion of said derived solution from step (a), c. introducing lithium carbonate granules into another portion of said derived solution from step (a) to form with said solution a slurry mixture wherein the molar ratio of lithium to potassium is between 42/58 and 62/38, d. passing said mixture through a first heating zone under pressure and dispersing it into a second heating zone under pressure where water is evaporated and solids are melted, producing a smelt, e. superheating a portion of said smelt by passing it through a third heating zone, dispersing said superheating smelt into the said second heating zone where it supplies the heat needed to evaporate water and to melt the solids of the incoming mixture, f. passing another portion of said smelt through a fourth heating zone and then into a first reaction zone wherein, by contact with hydrogen, the oxygenated sulfur compounds in the smelt are reduced to sulfides, g. transferring the sulfide containing smelt to a second reaction zone wherein, by contact with a mixture of carbon dioxide gas and water vapor, said sulfides react with said gases to produce a smelt including potassium carbonate and lithium carbonate and a gas including hydrogen sulfide, h. transferring a portion of said smelt from step (g) to the second heating zone, aqueous mixing another portion of the said smelt from step (g) with water at elevated temperature to produce an anqueous solution of potassium carbonate and a residue of lithium carbonate, separating said lithium carbonate from said solution of potassium carbonate transferring said lithium carbonate to step (c), and transferring said aqueous solution of potassium carbonate to step (a).
Claim 2
Dependent Claim
323 words
A process for removing sulfur dioxide from gases which includes; a. contacting said gases and absorbing sulfur dioxide therefrom with an aqueous solution containing potassium carbonate to derive a solution which includes potassium sulfite as well as potassium carbonate and withdrawing said derived solution, b. returning to step (a) a portion of said derived solution from step (a), c. introducing lithium carbonate granules into another portion of said derived solution from step (a) to form with said solution a slurry mixture wherein the molar ratio of lithium to potassium is between 42/58 and 62/38, d. passing said mixture through a first heating zone under pressure and dispersing it into a second heating zone under pressure where water is evaporated and solids are melted, producing a smelt, e. superheating a portion of said smelt by passing it through a third heating zone, dispersing said superheating smelt into the said second heating zone where it supplies the heat needed to evaporate water and to melt the solids of the incoming mixture, f. passing another portion of said smelt through a fourth heating zone and then into a first reaction zone wherein, by contact with hydrogen, the oxygenated sulfur compounds in the smelt are reduced to sulfides, g. transferring the sulfide containing smelt to a second reaction zone wherein, by contact with a mixture of carbon dioxide gas and water vapor, said sulfides react with said gases to produce a smelt including potassium carbonate and lithium carbonate and a gas including hydrogen sulfide, h. transferring a portion of said smelt from step (g) to the second heating zone, aqueous mixing another portion of the said smelt from step (g) with water at elevated temperature to produce an anqueous solution of potassium carbonate and a residue of lithium carbonate, separating said lithium carbonate from said solution of potassium carbonate transferring said lithium carbonate to step (c), and transferring said aqueous solution of potassium carbonate to step (a).
Claim 3
Dependent Claim
72 words
The process of claim 1 wherein the potassium carbonate content of the aqueous solution contacting the sulfur dioxide bearing gas is everywhere in excess of the quantity theoretically needed to react with all of the sulfur dioxide to be removed from said gases according to the reaction SO.sub.2 + K.sub.2 CO.sub.3 = K.sub.2 SO.sub.3 + CO.sub.2 said excess of potassium carbonate being at least sufficient to prevent the formation of potassium metabisulfite.
Claim 4
Dependent Claim
36 words
The process of claim 1, wherein the pressure on the suspension at the outlet of the first heating zone is at least 25 pounds per square inch higher than the pressure in the second heating zone.
Claim 5
Dependent Claim
37 words
The process of claim 1, wherein the temperature of the smelt leaving the second heating zone is higher than 530° centigrade and the temperature of the smelt leaving the third heating zone is higher than 600° centigrade.
Claim 6
Dependent Claim
20 words
The process of claim 1, wherein the temperature in the first reaction zone is between 700° centigrade and 800° centigrade.
Claim 7
Dependent Claim
59 words
The process of claim 1, wherein the pressure in the second reaction zone is maintained in the range of zero to 15 pounds per square inch gauge and the temperature is maintained between 525° centigrade and 575° centigrade by introducing water at a plurality of locations in the amount and in the state required to control the reaction temperature.
Claim 8
Dependent Claim
31 words
The process of claim 1, wherein that part of the smelt required for reuse in the sulfur dioxide absorption zone is passed through a third reaction zone in contact with air.
Claim 9
Dependent Claim
37 words
The process of claim 1, wherein that part of the smelt required for reuse in the sulfur dioxide absorption zone is mixed with a minimum amount of water at elevated temperature and produce a saturated solution thereof.
Claim 10
Dependent Claim
38 words
The process of claim 1, wherein the slurry mixture of step (c) includes one to five percent of a metal sulfide reduction catalyst selected from the group consisting of cuprous sulfide, ferrous sulfide, stannous sulfide, and zinc sulfide.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-01-12 | 1979-07-14 | 1980-01-13 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-01-12 | 1983-07-14 | 1984-01-13 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-01-12 | 1987-07-14 | 1988-01-13 | $7700.00 | Window Closed / Lapsed |