US3932333A — Emulsified phenolic resin system containing an an…

Claim 1

Independent Claim 149 words

A composition of matter comprising in combination: A. a stable emulsified phenol-formaldehyde resole resin having a water dilutability of from 15 percent to 2000 percent based on the resin solids, a formaldehyde to phenol combined mole ratio of from about 0.85 to 3.0 and a viscosity in methanol solution at 60 weight percent solids of not greater than about 10,000 centipoises and in the form of spherules dispersed in aqueous medium of which at least about 80 weight percent of the spherules have a maximum dimension from about 0.01 to 0.8 microns and containing: 1. a quantity of solids ranging from about 5 to 45 parts by weight; 2. a quantity of organic liquid ranging from about 0 to 20 parts by weight, and 3. a quantity of water ranging from 35 to 95 parts by weight; and B. a water soluble polyelectrolyte selected from the group consisting of:

Claim 2

Dependent Claim 149 words

A composition of matter comprising in combination: A. a stable emulsified phenol-formaldehyde resole resin having a water dilutability of from 15 percent to 2000 percent based on the resin solids, a formaldehyde to phenol combined mole ratio of from about 0.85 to 3.0 and a viscosity in methanol solution at 60 weight percent solids of not greater than about 10,000 centipoises and in the form of spherules dispersed in aqueous medium of which at least about 80 weight percent of the spherules have a maximum dimension from about 0.01 to 0.8 microns and containing: 1. a quantity of solids ranging from about 5 to 45 parts by weight; 2. a quantity of organic liquid ranging from about 0 to 20 parts by weight, and 3. a quantity of water ranging from 35 to 95 parts by weight; and B. a water soluble polyelectrolyte selected from the group consisting of:

Claim 3

Dependent Claim 93 words

polyacrylic acid and copolymers of acrylic acid and vinyl acetate containing up to 50 mole percent of vinyl acetate and the ammonium and alkali metal salts thereof, 2. polymethacrylic acid and copolymers of methacrylic acid and vinyl acetate containing up to 50 mole percent of vinyl acetate and the ammonium and alkali metal salts thereof, 3. copolymers of maleic anhydride and a comonomer selected from the group consisting of ethylene, propylene, butylene, styrene, chlorostyrene, vinyl toluene, vinyl formate, vinyl acetate, vinyl propionate, and vinyl benzoate and the ammonium and alkali metal salts thereof,

Claim 4

Dependent Claim 93 words

polyacrylic acid and copolymers of acrylic acid and vinyl acetate containing up to 50 mole percent of vinyl acetate and the ammonium and alkali metal salts thereof, 2. polymethacrylic acid and copolymers of methacrylic acid and vinyl acetate containing up to 50 mole percent of vinyl acetate and the ammonium and alkali metal salts thereof, 3. copolymers of maleic anhydride and a comonomer selected from the group consisting of ethylene, propylene, butylene, styrene, chlorostyrene, vinyl toluene, vinyl formate, vinyl acetate, vinyl propionate, and vinyl benzoate and the ammonium and alkali metal salts thereof,

Claim 5

Dependent Claim 99 words

copolymers of a monoalkyl maleate wherein the alkyl group is methyl, ethyl, propyl, or butyl and a comonomer selected from the group consisting of ethylene, propylene, butylene, styrene, chlorostyrene, vinyltoluene, vinyl formate, vinyl acetate, vinyl propionate, and vinyl benzoate and the ammonium and alkali metal salts thereof, and 5. copolymers of acrylic acid and 2-ethylhexyl acrylate containing 93.5 to 98.5 mole percent of acrylic and 6.5 -1.5 mole percent of 2-ethylhexyl acrylate; wherein the amount of water soluble polyelectrolyte is in the range from 0.04 to 20 percent by weight based on the total solids weight of phenol-formaldehyde resin.

Claim 6

Dependent Claim 99 words

copolymers of a monoalkyl maleate wherein the alkyl group is methyl, ethyl, propyl, or butyl and a comonomer selected from the group consisting of ethylene, propylene, butylene, styrene, chlorostyrene, vinyltoluene, vinyl formate, vinyl acetate, vinyl propionate, and vinyl benzoate and the ammonium and alkali metal salts thereof, and 5. copolymers of acrylic acid and 2-ethylhexyl acrylate containing 93.5 to 98.5 mole percent of acrylic and 6.5 -1.5 mole percent of 2-ethylhexyl acrylate; wherein the amount of water soluble polyelectrolyte is in the range from 0.04 to 20 percent by weight based on the total solids weight of phenol-formaldehyde resin.

Claim 7

Dependent Claim 13 words

The composition of claim 1 wherein the polyelectrolyte is ethylene maleic anhydride copolymer.

Claim 8

Dependent Claim 41 words

The composition of claim 1 containing in addition from 0 to 30 parts by weight of an inorganic salt selected from the group consisting of the ammonium and alkali metal salts of hydrochloric and sulfuric acid per 100 parts of solids.

Claim 9

Dependent Claim 20 words

The composition of claim 3 wherein the water soluble polyelectrolyte is sodium polyacrylate and the inorganic salt is ammonium chloride.

Claim 10

Dependent Claim 18 words

The composition of claim 1 wherein the emulsion solids comprise 5 to 30 weight percent of the composition.

Claim 11

Dependent Claim 26 words

The composition of claim 3 wherein there are between 5 and 20 parts by weight of the inorganic salt per 100 parts by weight of solids.

Annuity Stage	Window Opens	Payment Deadline	Surcharge Period Until	Estimated Fee	Status
3.5 Years (Year 4)	1979-01-12	1979-07-14	1980-01-13	$2000.00	Window Closed / Lapsed
7.5 Years (Year 8)	1983-01-12	1983-07-14	1984-01-13	$3760.00	Window Closed / Lapsed
11.5 Years (Year 12)	1987-01-12	1987-07-14	1988-01-13	$7700.00	Window Closed / Lapsed

Emulsified phenolic resin system containing an anti-migratory additive

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