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US3931346A
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Process for preparing a polymerizable diene polymer
Assignee: Mitsubishi Chemical Corp
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Filing: 1974-04-01
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Granted: 1976-01-06
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Expires: 1994-04-01
Abstract
Abstract A polymerizable diene polymer is prepared by reacting a polymerizable unsaturated carboxylic acid, anhydride, ester or acid halide with a polyhydroxydiene polymer having terminal and pendant hydroxy groups obtained from the reaction of one mole of a living polymer having a molecular weight of 500 to 10,000 which is prepared by reacting a conjugated diolefin or a mixture of said conjugated diolefin and a vinyl compound having the formula: CH 2 = CR 1 R 2 wherein R 1 represents a hydrogen atom or an alkyl group and R 2 represents an aryl group or a pyridyl group in the presence of sodium or lithium metal or an organo sodium or lithium compound with 0.5 mole to 2.0 moles of epichlorohydrin, epibromohydrin, epifluorohydrin, chlorobutylene oxide or bromobutylene oxide.
Inventors
- 👤 Jihei Inomata
- 👤 Seiichi Hino
- 👤 Tatsuo Tani
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-09 22:19
CPC Classifications
C; C08; C08G; C08G65/00; C08G65/02; C08G65/04; C08G65/22; C08G65/223; C08C; C08C19/00; C08C19/30; C08C19/42; C08C19/44; C08F; C08F36/00; C08F36/02; C08F36/04; C08G18/00; C08G18/06; C08G18/28; C08G18/67; C08G18/69; C08G63/00; C08G63/02; C08G63/12; C08G63/52; C08G63/68; C08G63/685; C08G63/6854; C08G63/6858
Claims Analysis
Total Claims: 7
Claim 1
Independent Claim
134 words
A process for preparing a liquid polymerizable diene polymer, which comprises: reacting a liquid polymerizable unsaturated carboxylic acid, anhydride, ester or acid halide with a liquid polydroxydiene polymer having terminal and pendant hydroxy groups obtained from the reaction of one mole of a living polymer having a molecular weight of 500 to 10,000 which is prepared by reacting a conjugated diolefin or a mixture of said conjugated diolefin and a vinyl compound having the formula: CH 2 =CR 1 R 2 , wherein R 1 represents a hydrogen atom or an alkyl group and R 2 represents an aryl group or a pyridyl group in the presence of sodium or lithium metal or an organo sodium or lithium compound with 0.5 mole to 2.0 moles of epichlorohydrin, epibromohydrin, epifluorohydrin, chlorobutylene oxide or bromobutylene oxide.
Claim 2
Dependent Claim
134 words
A process for preparing a liquid polymerizable diene polymer, which comprises: reacting a liquid polymerizable unsaturated carboxylic acid, anhydride, ester or acid halide with a liquid polydroxydiene polymer having terminal and pendant hydroxy groups obtained from the reaction of one mole of a living polymer having a molecular weight of 500 to 10,000 which is prepared by reacting a conjugated diolefin or a mixture of said conjugated diolefin and a vinyl compound having the formula: CH 2 =CR 1 R 2 , wherein R 1 represents a hydrogen atom or an alkyl group and R 2 represents an aryl group or a pyridyl group in the presence of sodium or lithium metal or an organo sodium or lithium compound with 0.5 mole to 2.0 moles of epichlorohydrin, epibromohydrin, epifluorohydrin, chlorobutylene oxide or bromobutylene oxide.
Claim 3
Dependent Claim
18 words
The process of claim 1, which further comprises admixing the polymerizable diene polymer with a polymerizable vinyl monomer.
Claim 4
Dependent Claim
36 words
The process of claim 2, wherein said polymerizable diene polymer is used with 0 to 200 percent by weight of said polymerizable vinyl monomer based on the amount of polymerizable diene polymer at 0° to 250°C.
Claim 5
Dependent Claim
36 words
The process of claim 2, wherein said polymerizable vinyl monomer is styrene, 4-t-butylstyrene, chlorostyrene, divinylbenzene, methylmethacrylate, ethylmethacrylate, propylmethacrylate, butylmethacrylate, octylmethacrylate, methylacrylate, ethylacrylate, propylacrylate, butylacrylate, octylacrylate, ethyleneglycoldiacrylate, diethyleneglycoldiacrylate, ethyleneglycol dimethacrylate, diethyleneglycol dimethacrylate, diallylphthalate, triallylisocyanurate or diallyl ether.
Claim 6
Dependent Claim
18 words
The process of claim 1, which further comprises curing the polymerizable diene polymer with a radical polymerizing initiator.
Claim 7
Dependent Claim
33 words
The process of claim 5, wherein said radical polymerization initiator is dicumyl peroxide, 2,5-dimethyl-2,5-di(t-butylperoxy)benzene, t-butylcumylperoxide, di-t-butylperoxide, cyclohexanone peroxide, methylethylketone peroxide, acetyl peroxide, succinic peroxide, propionyl peroxide, lauroyl peroxide, azobis(isobutyronitrile), azobismethylvaleronitrile or azobiscyclohexane carbonitrile.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-01-05 | 1979-07-07 | 1980-01-06 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-01-05 | 1983-07-07 | 1984-01-06 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-01-05 | 1987-07-07 | 1988-01-06 | $7700.00 | Window Closed / Lapsed |