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US3931077A Expired / Lapsed US ⏱️ 0.0 years remaining

Reactive hot melt adhesive composition and method for use thereof

Assignee: Mitsui Chemicals Inc
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Filing: 1974-01-04
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Granted: 1976-01-06
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Expires: 1994-01-04
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Abstract

Abstract A reactive hot-melt adhesive composition useful for bonding is described comprising a reactive urethane prepolymer, a thermoplastic polymer, and a tackifier. A method for using this composition which melts at lower than hot-melt adhesive temperatures and has good pot-life is also described.

Inventors

  • 👤 Taku Uchigaki
  • 👤 Kenichi Omori
  • 👤 Masataka Okamura

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 11:07
CPC Classifications
C; C09; C09J; C09J175/00; C09J175/04; C08; C08L; C08L2666/00; C08L2666/02

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 193 words
A reactive hot melt-type adhesive composition comprising (a) a reactive compound, (b) a thermoplastic resin and (c) a tackifier; wherein: a. the reactive compound is a urethane prepolymer having terminal isocyanate groups at both ends thereof and a viscosity higher than 300,000 cps at 25°C; resulting from the addition polymerization of at least one diisocyanate and at least one diol b. the thermoplastic resin is an ethylene-vinylacetate co-polymer or an ethylene-acrylic acid copolymer, or an ethyleneacrylate copolymer or an atactic polypropylene or a polyethyleneterephthalate linear polymer; and c. the tackifier is a hydrogenated abietic acid-type rosin or esters thereof having its double bonds removed by hydrogenation in whole or in part, or a terpene-phenol copolymer of a mono- or diterpene wherein the terpene has 10 carbon atoms and having a 1.0 to 3.0 molar ratio of terpene to phenol; said adhesive composition comprising 20 - 73 wt % of said urethane prepolymer (a), 2 - 25 wt % of said thermoplastic resin (b) and 25 - 55 wt % of said tackifier (c) said composition having a viscosity ranging from 9000 cp to 2000 cp in the temperature range of 100° - 130°C.
Claim 2
Dependent Claim 193 words
A reactive hot melt-type adhesive composition comprising (a) a reactive compound, (b) a thermoplastic resin and (c) a tackifier; wherein: a. the reactive compound is a urethane prepolymer having terminal isocyanate groups at both ends thereof and a viscosity higher than 300,000 cps at 25°C; resulting from the addition polymerization of at least one diisocyanate and at least one diol b. the thermoplastic resin is an ethylene-vinylacetate co-polymer or an ethylene-acrylic acid copolymer, or an ethyleneacrylate copolymer or an atactic polypropylene or a polyethyleneterephthalate linear polymer; and c. the tackifier is a hydrogenated abietic acid-type rosin or esters thereof having its double bonds removed by hydrogenation in whole or in part, or a terpene-phenol copolymer of a mono- or diterpene wherein the terpene has 10 carbon atoms and having a 1.0 to 3.0 molar ratio of terpene to phenol; said adhesive composition comprising 20 - 73 wt % of said urethane prepolymer (a), 2 - 25 wt % of said thermoplastic resin (b) and 25 - 55 wt % of said tackifier (c) said composition having a viscosity ranging from 9000 cp to 2000 cp in the temperature range of 100° - 130°C.
Claim 3
Dependent Claim 59 words
The adhesive composition according to claim 1 wherein the urethane prepolymer is an addition polymerization product of a diisocyanate selected from the group consisting of 2,4-tolylenediisocyanate, 2,6-tolylenediisocyanate, 4,4'-diphenylmethanediisocyanate, hexamethylene diisocyanate, or 1,5-naphthylenediisocyanate or a mixture thereof; and a diol selected from the group consisting of ethyleneglycol, propyleneglycol, 1,4-butanediol or 1,4-butinediol or polymers thereof, polytetramethyleneglycol ether or a mixture thereof.
Claim 4
Dependent Claim 25 words
The adhesive composition according to claim 1 wherein said thermoplastic resin is a thermoplastic ethylene-vinylacetate copolymer having a vinylacetate content of 5 - 70 wt.%.
Claim 5
Dependent Claim 25 words
The adhesive composition according to claim 1 wherein said thermoplastic resin is a thermoplastic ethylene-ethylacrylate copolymer having an ethylene content of 70 - 95 wt.%.
Claim 6
Dependent Claim 38 words
The adhesive composition according to claim 1 wherein said tackifier has good miscibility with the urethane prepolymer, is non-reactive, with the terminal isocyanate groups thereof, has a low viscosity at 100° to 130°C. and is solid at 60°C.

References Cited (Backward Citations)

US3242230A Cited
US3703492A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-01-05 1979-07-07 1980-01-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-01-05 1983-07-07 1984-01-06 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-01-05 1987-07-07 1988-01-06 $7700.00 Window Closed / Lapsed

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