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US3931071A Expired / Lapsed US ⏱️ 0.0 years remaining

Compositions of acrylated epoxidized soybean oil amine compounds useful as inks and coatings

Assignee: Union Carbide Corp
•
Filing: 1974-06-03
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Granted: 1976-01-06
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Expires: 1994-06-03
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Abstract

Abstract Compositions of amine derivatives of acrylated epoxidized soybean oil, which are the reaction products of an organic amine with the reaction product of epoxidized soybean oil with acrylic acid or methacrylic acid, and an acrylyl compound are useful as coatings and inks; photosensitizers and/or pigments can optionally be present. The compositions can be cured by radiation.

Inventors

  • 👤 David John Trecker
  • 👤 George Wayne Borden
  • 👤 Oliver Wendell Smith

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 16:32
CPC Classifications
C; C09; C09D; C09D11/00; C09D11/02; C09D11/10; C09D11/101; C08; C08F; C08F220/00; C08F220/02; C08F220/10; C08F220/34; C08F220/36

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 128 words
A composition comprising: I. an acrylated epoxidized soybean oil amine compound having in the molecule the group: ##EQU10## wherein X is hydrogen or methyl and R' taken singly is alkyl of 1 to 15 carbon atoms or aryl having up to 15 carbon atoms and the two R' groups taken together with the nitrogen atom attached thereto form a heterocyclic ring having from 5 to 6 ring atoms, said compound being the reaction product of: A. epoxidized soybean oil reacted with at least 2 moles of acrylic acid or methacrylic acid per mole thereof and B. from 5 to 40 mole percent, based on acrylyl groups of an organic amine of the formula R 2 ' NH wherein R' is as defined above, and Ii. an acrylyl compound.
Claim 2
Dependent Claim 128 words
A composition comprising: I. an acrylated epoxidized soybean oil amine compound having in the molecule the group: ##EQU10## wherein X is hydrogen or methyl and R' taken singly is alkyl of 1 to 15 carbon atoms or aryl having up to 15 carbon atoms and the two R' groups taken together with the nitrogen atom attached thereto form a heterocyclic ring having from 5 to 6 ring atoms, said compound being the reaction product of: A. epoxidized soybean oil reacted with at least 2 moles of acrylic acid or methacrylic acid per mole thereof and B. from 5 to 40 mole percent, based on acrylyl groups of an organic amine of the formula R 2 ' NH wherein R' is as defined above, and Ii. an acrylyl compound.
Claim 3
Dependent Claim 143 words
A composition as claimed in claim 1 wherein said acrylyl compound (II) is present at a concentration up to about 90 weight percent thereof and is acrylonitrile or of the formula: ##EQU11## wherein Z is hydrogen or methyl; t is an integer having a value of 1 to 3; and R'" is alkoxy of 1 to 18 carbon atoms, hydroxyalkoxy of up to 15 carbon atoms, alkoxyalkoxy of up to 15 carbon atoms, cyanoalkoxy of up to 15 carbon atoms, aryloxy, or --(OC n H 2n ) z NR"" wherein n has a value of 1 to 10, z has a value of 0 or 1 and R"" is alkyl of 1 to 10 carbon atoms when t is one or a polyvalent alkylene or oxyalkylene having 2 to 8 carbon atoms in the alkylene moiety thereof when t is other than one.
Claim 4
Dependent Claim 20 words
A composition as claimed in claim 2 wherein (A) is the reaction product of epoxidized soybean oil with acrylic acid.
Claim 5
Dependent Claim 20 words
A composition as claimed in claim 2 wherein (A) is the reaction product of epoxidized soybean oil with methacrylic acid.
Claim 6
Dependent Claim 11 words
A composition as claimed in claim 2 wherein (B) is diethanolamine.
Claim 7
Dependent Claim 11 words
A composition as claimed in claim 2 wherein (B) is morpholine.
Claim 8
Dependent Claim 13 words
A composition as claimed in claim 1 wherein a pigment is additionally present.

References Cited (Backward Citations)

US3673140A Cited
US3713864A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-01-05 1979-07-07 1980-01-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-01-05 1983-07-07 1984-01-06 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-01-05 1987-07-07 1988-01-06 $7700.00 Window Closed / Lapsed

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