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US3929969A Expired / Lapsed US ⏱️ 0.0 years remaining

Trivalent metal salts of dodecametal triaconta carbonyls

Assignee: Union Carbide Corp
•
Filing: 1974-03-27
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Granted: 1975-12-30
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Expires: 1994-03-27
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Abstract

Abstract This invention relates to novel carbonyl mixed metal salts, containing more than one metal and having the formula: M2(TyT''12 y (CO)30)3 wherein M is a trivalent metal cation which is one of aluminum, gallium, iridium, scandium, yttrium, and rhenium, T and T'' are each different metals selected from the group consisting of cobalt, iridium and rhodium, and y may be any whole number between 1 and 11. These compounds are useful catalysts in the reaction between carbon monoxide and hydrogen to produce oxygenated compounds such as methanol, ethylene glycol, glycerine and 1,2-propylene glycol.

Inventors

  • 👤 Earle S Brown

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 09:22
CPC Classifications
C; C07; C07C; C07C29/00; C07C29/15; C07C29/151; C07C29/153; C07C29/156; C07C29/157; B; B01; B01J; B01J31/00; B01J31/16; B01J31/20; C01; C01G; C01G1/00; C01G1/04; C07C29/158; B01J2231/00; B01J2231/60; B01J2231/64; B01J2231/641; B01J2231/648; B01J2531/00; B01J2531/02; B01J2531/0202; B01J2531/0211; B01J2531/80; B01J2531/82; B01J2531/822; B01J2531/827; B01J2531/84; B01J2531/845; B01J2531/90; B01J2531/96; Y; Y02; Y02P; Y02P20/00; Y02P20/50; Y02P20/52

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 8 words
PLURAL METAL TRIACONTA CARBONYL SALTS OF THE FORMULA:
Claim 2
Dependent Claim 8 words
PLURAL METAL TRIACONTA CARBONYL SALTS OF THE FORMULA:
Claim 3
Dependent Claim 9 words
The salt of claim 1 wherein M is aluminum.
Claim 4
Dependent Claim 9 words
The salt of claim 1 wherein M is gallium.
Claim 5
Dependent Claim 9 words
The salt of claim 1 wherein M is iridium.
Claim 6
Dependent Claim 9 words
The salt of claim 1 wherein M is scandium.
Claim 7
Dependent Claim 9 words
The salt of claim 1 wherein M is yttrium.
Claim 8
Dependent Claim 9 words
The salt of claim 1 wherein M is rhenium.
Claim 9
Dependent Claim 13 words
The salt of claim 1 wherein T and T'' are rhodium and iridium.
Claim 10
Dependent Claim 9 words
The salt of claim 8 having the formula: M2(Rh9Ir3(CO)30)3
Claim 11
Dependent Claim 9 words
The salt of claim 9 wherein M is aluminum.
Claim 12
Dependent Claim 9 words
The salt of claim 8 having the formula: M2(Rh6Ir6(CO)30)3
Claim 13
Dependent Claim 9 words
The salt of claim 11 wherein M is aluminum.
Claim 14
Dependent Claim 13 words
The salt of claim 1 wherein T and T'' are rhodium and cobalt.
Claim 15
Dependent Claim 9 words
The salt of claim 13 having the formula: M2(Rh9Co3(CO)30)3
Claim 16
Dependent Claim 9 words
The salt of claim 14 wherein M is aluminum.

References Cited (Backward Citations)

No citation records indexed.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-12-29 1979-06-30 1979-12-30 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-12-29 1983-06-30 1983-12-30 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-12-29 1987-06-30 1987-12-30 $7700.00 Window Closed / Lapsed

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