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US3928461A Expired / Lapsed US ⏱️ 0.0 years remaining

Production of formaldehyde

Assignee: BASF SE
•
Filing: 1973-06-21
•
Granted: 1975-12-23
•
Expires: 1993-06-21
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Abstract

Abstract A process for producing formaldehyde by oxidizing dehydrogenation of methanol in the presence of a silver catalyst, wherein a vaporous mixture of water and oxygen is introduced into the vaporous starting mixture containing water, methanol and oxygen before entry into the catalyst bed. Formaldehyde produced by the process is a disinfectant, tanning agent, reducing agent and raw material for the production of synthetic resins, adhesives and plastics.

Inventors

  • 👤 Hans Diem
  • 👤 Guenther Matthias
  • 👤 Albrecht Aicher
  • 👤 Hans Haas
  • 👤 Hans Schreiber
  • 👤 Heinrich Sperber

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 20:10
CPC Classifications
D; D06; D06P; D06P3/00; D06P3/34; D06P3/52; D06P3/54; C; C07; C07C; C07C45/00; C07C45/27; C07C45/32; C07C45/37; C07C45/38

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 226 words
A PROCESS PRODUCING FORMALDEHYDE BY OXIDIZING DEHYDROGENATION OF METHANOL IN THE PRESENCE OF A SILVER CATALYST AT ELEVATED TEMPERATURES, WHEREIN THE REACTION IS CARRIED OUT AT A TEMPERATURE OF 550* TO 750*C AND DURING THE REACTION AN ADDITIONAL VAPOR MIXTURE HEATED TO AT LEAST 70*C AND CONSISTING OF 0.05 TO 0.8 MOLE OF WATER AND 0.005 TO 0.6 MOLE OF OXYGEN BASED ON 1 MOLE OF FEED METHANOL IS INTRODUCED, INTO THE VAPOROUS METHANOLIC STARTING MIXTURE WHICH HAS BEEN HEATED TO AT LEAST 60*C AND CONTAINS WATER IN A MOLAR RATIO OF 0.09 TO 1.8 AND OXYGEN IN A MOLAR RATIO OF 0.35 TO 0.5, BASED ON 1 MOLE OF METHANOL, BEFORE SAID STARTING MIXTURE ENTERS THE CATALYST BED, THE SPACE VELOCITY BEING 0.9 TO 3 METRIC TONS OF METHANOL, CALCULATED 100%, PER SQUARE METER OF CATALYST BED CROSS-SECTION PER HOUR, SAID REACTION BEING CARRIED OUT IN A PLURALITY OF REACTORS ARRANGED IN PARALLEL, EACH REACTOR HAVING A BED OF SAID SILVER CATALYST OF A DIAMETER OF AT LEAST 0.5 METER SAID STARTING MIXTURE BEING FED TO THE RESPECTIVE REACTORS VIA A BRANCH LINE CONNECTING EACH RESPECTIVE REACTOR WITH A MAIN SUPPLY PIPE FOR SAID STARTING MIXTURE, AND SAID ADDITIONAL VAPOR MIXTURE BEING FED INTO AT LEAST ONE OF SAID REACTORS AT A POINT AHEAD OF THE ENTRY OF SAID STARTING MIXTURE INTO SAID CATALYST BED.
Claim 2
Dependent Claim 226 words
A PROCESS PRODUCING FORMALDEHYDE BY OXIDIZING DEHYDROGENATION OF METHANOL IN THE PRESENCE OF A SILVER CATALYST AT ELEVATED TEMPERATURES, WHEREIN THE REACTION IS CARRIED OUT AT A TEMPERATURE OF 550* TO 750*C AND DURING THE REACTION AN ADDITIONAL VAPOR MIXTURE HEATED TO AT LEAST 70*C AND CONSISTING OF 0.05 TO 0.8 MOLE OF WATER AND 0.005 TO 0.6 MOLE OF OXYGEN BASED ON 1 MOLE OF FEED METHANOL IS INTRODUCED, INTO THE VAPOROUS METHANOLIC STARTING MIXTURE WHICH HAS BEEN HEATED TO AT LEAST 60*C AND CONTAINS WATER IN A MOLAR RATIO OF 0.09 TO 1.8 AND OXYGEN IN A MOLAR RATIO OF 0.35 TO 0.5, BASED ON 1 MOLE OF METHANOL, BEFORE SAID STARTING MIXTURE ENTERS THE CATALYST BED, THE SPACE VELOCITY BEING 0.9 TO 3 METRIC TONS OF METHANOL, CALCULATED 100%, PER SQUARE METER OF CATALYST BED CROSS-SECTION PER HOUR, SAID REACTION BEING CARRIED OUT IN A PLURALITY OF REACTORS ARRANGED IN PARALLEL, EACH REACTOR HAVING A BED OF SAID SILVER CATALYST OF A DIAMETER OF AT LEAST 0.5 METER SAID STARTING MIXTURE BEING FED TO THE RESPECTIVE REACTORS VIA A BRANCH LINE CONNECTING EACH RESPECTIVE REACTOR WITH A MAIN SUPPLY PIPE FOR SAID STARTING MIXTURE, AND SAID ADDITIONAL VAPOR MIXTURE BEING FED INTO AT LEAST ONE OF SAID REACTORS AT A POINT AHEAD OF THE ENTRY OF SAID STARTING MIXTURE INTO SAID CATALYST BED.
Claim 3
Dependent Claim 17 words
A process according to claim 1, wherein the oxygen necessary for the reaction is introduced as air.
Claim 4
Dependent Claim 29 words
A process according to claim 1, wherein the reaction is carried out with said starting mixture of gases and vapors heated to a temperature of from 70* to 90*C.
Claim 5
Dependent Claim 20 words
A process according to claim 1, wherein the reaction is carried out at a temperature of from 600* to 720*C.
Claim 6
Dependent Claim 22 words
A process according to claim 1, wherein the reaction is carried out at a gauge pressure of from 0.5 to 2 atmospheres.
Claim 7
Dependent Claim 49 words
A process according to claim 1, wherein the reaction is carried out at a molar ratio in said starting mixture of from 0.39 to 0.46 mole of oxygen (O2) per mole of methanol and a molar ratio of 0.2 to 1 mole of water per mole of feed methanol.
Claim 8
Dependent Claim 48 words
A process according to claim 1, wherein the reaction is carried out at a molar ratio in said starting mixture of 0.39 to 0.46 mole of oxygen (O2) per mole of methanol and a molar ratio of 0.3 to 0.5 moles of water per mole of feed methanol.
Claim 9
Dependent Claim 21 words
A process according to claim 1, wherein the reaction is carried out with said additional mixture heated to 100* to 150*C.
Claim 10
Dependent Claim 41 words
A process according to claim 1, wherein the reaction is carried out with said additional mixture containing 0.2 to 0.65 mole of water and 0.01 to 0.045 mole of oxygen (O2) per mole of methanol in the starting mixture (feed methanol).
Claim 11
Dependent Claim 43 words
A process according to claim 1, wherein the reaction is carried out together with said additional mixture containing from 0.3 to 0.5 mole of water and 0.01 to 0.03 mole of oxygen (02) per mole of methanol in the starting mixture (feed methanol).
Claim 12
Dependent Claim 24 words
A process according to claim 1, wherein the additional mixture is introduced at a point 0.5 to 3 meters upstream of the catalyst bed.
Claim 13
Dependent Claim 21 words
A process according to claim 1, wherein said plurality of reactors comprises a twin reactor with two reactors arranged in parallel.
Claim 14
Dependent Claim 30 words
A process according to claim 1 in which said additional vapor mixture is fed into said branch line at a point 0.5 to 3 meters upstream from the catalyst bed.

References Cited (Backward Citations)

US2465498A Cited
US2504402A Cited
US2462413A Cited
US2614125A Cited
US2908715A Cited
US3272868A Cited
US3318955A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-12-22 1979-06-23 1979-12-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-12-22 1983-06-23 1983-12-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-12-22 1987-06-23 1987-12-23 $7700.00 Window Closed / Lapsed

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