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US3928294A Expired / Lapsed US ⏱️ 0.0 years remaining

Biocompatible articles including polymeric membranes having high permeability to gases and uses thereof

Assignee: OI Glass Inc
•
Filing: 1973-02-02
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Granted: 1975-12-23
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Expires: 1993-02-02
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Abstract

Abstract There is disclosed the preparation of an alpha-olefin-sulfur dioxide copolymer derived from the C8 to C18 alpha-olefins. The polymers undergo clean thermal degradation, have high permeabilities to oxygen and carbon dioxide, and are readily processed into a membrane article. Maximum permeabilities are obtained with the C16 based polymer. New uses of the copolymer are set forth including perfusion membranes, soft contact lenses and biocompatible articles for contact with human body fluids including surgical tubing, wound dressings, and prosthetic devices such as artificial veins, arteries and heart valves.

Inventors

  • 👤 James E Crawford
  • 👤 Don N Gray

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 20:16
CPC Classifications
B; B01; B01D; B01D71/00; B01D71/06; B01D71/66; B01D71/68; A; A61; A61F; A61F13/00; A61F13/01; A61F13/01008; A61F13/01034; A61F2/00; A61F2/02; A61F2/24; A61F2/2421; A61L; A61L15/00; A61L15/16; A61L15/22; A61L15/26; A61L27/00; A61L27/14; A61L27/18; A61L33/00; A61L33/06; A61L33/068; B01D69/00; B01D69/02; C; C08; C08G; C08G75/00; C08G75/20; C08G75/205; C08G75/22; A61F2013/00089; A61F2013/00217; A61F13/15; A61F2013/15008; A61F2013/15048; A61M; A61M60/00; A61M60/10; A61M60/122; A61M60/196; Y; Y10; Y10S; Y10S128/00; Y10S128/24

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 39 words
AS AN ARTICLE OF MANUFACTURE, A PERSELCTIVE, BIOCOMPATIBLE MEMBRANE ARTICLE HAVING HIGH GASEOUS PERMEABILITY, SAID MEMBRANE CONSISTING OF A POLY(ALPHA-OLEFIN-SULFONE) DERIVED FROM THE SERIES C8 TO C18 ALPHA-OLEFINS AND SULFUR DIOXIDE THE MEMBRANE HAVING AN OXYGEN TRANSMISSION RATE OF
Claim 2
Dependent Claim 39 words
AS AN ARTICLE OF MANUFACTURE, A PERSELCTIVE, BIOCOMPATIBLE MEMBRANE ARTICLE HAVING HIGH GASEOUS PERMEABILITY, SAID MEMBRANE CONSISTING OF A POLY(ALPHA-OLEFIN-SULFONE) DERIVED FROM THE SERIES C8 TO C18 ALPHA-OLEFINS AND SULFUR DIOXIDE THE MEMBRANE HAVING AN OXYGEN TRANSMISSION RATE OF
Claim 3
Dependent Claim 21 words
An article as defined in claim 1 wherein the radical contains fourteen carbon atoms and the alpha-olefin contains sixteen carbon atoms.
Claim 4
Dependent Claim 15 words
An article as defined in claim 1 in which the alpha-olefin contains 14 carbon atoms.
Claim 5
Dependent Claim 60 words
An poly(alpha-olefin-sulfone) as defined in claim 1 in which the permeability to oxygen is measured by an O2 transmission rate of at least about 3.1 X 10 4 cc mil./in2 yr atm; the permeability to CO2 is at least about 13.9 X 10 4 cc mil./in2 yr atm; and the percent elongation at yield point is at least about 13.5.
Claim 6
Dependent Claim 47 words
A membrane article as defined in claim 1 that has an O2 transmission rate of about 3.75 X 10 4 cc mil./in2 yr atm; a CO2 transmission rate of about 16.5 X 10 4 cc mil./in2 yr atm; and an elongation at yield point of about 14%.

References Cited (Backward Citations)

US2652368A Cited
US3442790A Cited
US3563789A Cited
US3651030A Cited
US3728185A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-12-22 1979-06-23 1979-12-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-12-22 1983-06-23 1983-12-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-12-22 1987-06-23 1987-12-23 $7700.00 Window Closed / Lapsed

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