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US3928067A Expired / Lapsed US ⏱️ 0.0 years remaining

Polyalkylene glycol ethers in rechargeable lithium nonaqueous batteries

Assignee: AT&T Inc
•
Filing: 1974-09-06
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Granted: 1975-12-23
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Expires: 1994-09-06
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Abstract

Abstract A lithium nonaqueous secondary battery is described which contains certain dopants to improve the recycling characteristics of the battery. Also, certain of these dopants act as wetting agents for the polypropylene separator. These batteries exhibit increased cycle life and increased cycle efficiency. Also, these batteries are more easily manufactured since vacuum filling to wet the separator is not necessary. These dopants include polyalkylene glycol ethers, tetraalkyl ammonium halides, and certain lithium salts.

Inventors

  • 👤 John Broadhead
  • 👤 Thomas Michael Putvinski
  • 👤 Forrest Allen Trumbore

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 15:53
CPC Classifications
H; H01; H01M; H01M10/00; H01M10/05; H01M10/056; H01M10/0564; H01M10/0566; Y; Y02; Y02E; Y02E60/00; Y02E60/10

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 52 words
A NONAQUEOUS SECONDARY BATTERY COMPRISING A LITHIUM NEGATIVE ELECTRODE, A POSITIVE ELECTRODE, ELECTROLYTE AND MICROPOROUS POLYMER SEPARATORS IN WHICH THE ELECTROLYTE CONSISTS ESSENTAILLY OF A SOLVENT, 0.01-2.0 MOLAR LITHIUM SALT, WHERE THE LITHIUM SALT IS SELECTED FROM THE GROUP CONSISTING OF LII AND LICLO4, AND OTHER DOPANTS CHARACTERIZED IN THAT THE OTHER
Claim 2
Dependent Claim 52 words
A NONAQUEOUS SECONDARY BATTERY COMPRISING A LITHIUM NEGATIVE ELECTRODE, A POSITIVE ELECTRODE, ELECTROLYTE AND MICROPOROUS POLYMER SEPARATORS IN WHICH THE ELECTROLYTE CONSISTS ESSENTAILLY OF A SOLVENT, 0.01-2.0 MOLAR LITHIUM SALT, WHERE THE LITHIUM SALT IS SELECTED FROM THE GROUP CONSISTING OF LII AND LICLO4, AND OTHER DOPANTS CHARACTERIZED IN THAT THE OTHER
Claim 3
Dependent Claim 27 words
The nonaqueous secondary battery of claim 1 in which the solvent is selected from a group consisting of propylene carbonate, butyrolactone, ethylene carbonate, dimethylsulfite, acetonitrile and dimethylsulfoxide.
Claim 4
Dependent Claim 14 words
The nonaqueous secondary battery of claim 2 in which the solvent is propylene carbonate.
Claim 5
Dependent Claim 25 words
The nonaqueous secondary battery of claim 1 in which the lithium negative electrode is a thin film electrode with thickness between 1 and 25 mils.
Claim 6
Dependent Claim 22 words
The noNaqueous secondary battery of claim 1 in which the tetraglyme is used as a wetting agent for the microporous polypropylene separators.
Claim 7
Dependent Claim 17 words
The nonaqueous secondary battery of claim 1 in which the microporous polymer separators consists essentially of polypropylene.

References Cited (Backward Citations)

US3578500A Cited
US3594235A Cited
US3658593A Cited
US3642436A Cited
US3686038A Cited
US3796605A Cited
US3796604A Cited
US3778310A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-12-22 1979-06-23 1979-12-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-12-22 1983-06-23 1983-12-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-12-22 1987-06-23 1987-12-23 $7700.00 Window Closed / Lapsed

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