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US3926759A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for recovering tin salts from the waste rinse water of a halogen tin plating process

Assignee: Pitt Metals and Chemicals Inc
•
Filing: 1975-02-06
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Granted: 1975-12-16
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Expires: 1995-02-06
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Abstract

Abstract The waste rinse water from a halogen tin plating process contains both tin and fluoride with the mole ratio of fluoride to tin being between 21 and 25 to 1. The plating bath also contains tin and fluoride as a tin fluoride complex in a mole ratio of fluoride to tin of between 6 and 7 to 1. The waste rinse water is first filtered to remove insoluble materials such as iron ferrocyanides. The filtrate is then treated to remove residual organic compounds. The treated solution is then rectified in an electrodialytic cell where the solution is introduced into a depletion compartment which is separated from the anode compartment by one or more anionic membranes with compartments therebetween and by a cationic membrane from the cathode compartment. The anode compartment and the compartments between the anode compartment and the depletion compartment contain an acid solution preferably hydrofluoric acid. The cathode compartment contains a caustic solution preferably a sodium hydroxide solution. An insoluble inert anode is positioned in the anode compartment and the current is impressed across the electrodialytic cell. The halogen ions migrate through the anionic membranes from the depletion compartment to the intermediate or receiving compartment and increase the concentration of the halogen acid therein. The sodium ions migrate through the cationic membrane to increase the concentration of sodium hydroxide therein. The rectified rinse water depleted of excess halogens is withdrawn from the depletion compartment and concentrated by a suitable process, such as reverse osmosis, to provide a solution having the desired concentration as a solution for use in the plating bath. The caustic from the cathode compartment and the acid from the intermediate compartment are withdrawn therefrom and reacted to form sodium bifluoride for reuse in the rinse water of the plating process.

Inventors

  • 👤 Richard E Horn
  • 👤 David W Grenda

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 16:27
CPC Classifications
B; B01; B01D; B01D61/00; B01D61/42; B01D61/44; B01D61/02; B01D61/025; C; C25; C25D; C25D21/00; C25D21/16; C25D21/20

Claims Analysis

Total Claims: 19
Claim 1
Independent Claim 70 words
A PROCESS FOR RECOVERING TIN SALTS FROM THE WASTE RINSE WATER OF A HALOGEN TIN PLATING PROCESS COMPRISING, INTRODUCING THE RINSE WATER INTO A DEPLETION COMPARTMENT OF AN ELECTRODIALYTIC CELL, INTRODUCING AN ELECTROLYTE SOLUTION INTO AND ANODE COMPARTMENT AND A CATHODE COMPARTMENT OF SAID ELECTRODIALYTIC CELL, SAID CATHODE COMPARTMENT SEPARATED FROM SAID DEPLETION COMPARTMENT BY A CATIONIC MEMBRANE, SAID DEPLETION COMPARTMENT SEPARATED FROM THE ANODE COMPARTMENT BY AN ANIONIC MEMBRANE,
Claim 2
Dependent Claim 70 words
A PROCESS FOR RECOVERING TIN SALTS FROM THE WASTE RINSE WATER OF A HALOGEN TIN PLATING PROCESS COMPRISING, INTRODUCING THE RINSE WATER INTO A DEPLETION COMPARTMENT OF AN ELECTRODIALYTIC CELL, INTRODUCING AN ELECTROLYTE SOLUTION INTO AND ANODE COMPARTMENT AND A CATHODE COMPARTMENT OF SAID ELECTRODIALYTIC CELL, SAID CATHODE COMPARTMENT SEPARATED FROM SAID DEPLETION COMPARTMENT BY A CATIONIC MEMBRANE, SAID DEPLETION COMPARTMENT SEPARATED FROM THE ANODE COMPARTMENT BY AN ANIONIC MEMBRANE,
Claim 3
Dependent Claim 49 words
A process for recovering tin salts from the waste rinse water of a halogen tin plating process as set forth in claim 1 which includes, introducing an electrolyte solution into an intermediate compartment of said electrodialytic cell, said intermediate compartment separated from said depletion compartment by an anionic membrane.
Claim 4
Dependent Claim 37 words
A process for recovering tin salts from the waste rinse water of a halogen tin plating process as set forth in claim 1 in which, said electrolyte solution in said anode compartment contains a sulphuric acid solution.
Claim 5
Dependent Claim 37 words
A process for recovering tin salts from the waste rinse water of a halogen tin plating process as set forth in claim 1 in which, said electrolyte solution in said anode compartment contains a hydrofluoric acid solution.
Claim 6
Dependent Claim 36 words
A process for recovering tin salts from the waste rinse water of a halogen tin plating process as set forth in claim 1 in which, said electrolyte solution in said cathode compartment contains a caustic solution.
Claim 7
Dependent Claim 33 words
A process for recovering tin salts from the waste rinse water of a halogen tin plating process as set forth in claim 5 in which, said caustic solution is a sodium hydroxide solution.
Claim 8
Dependent Claim 35 words
A process for recovering tin salts from the waste rinse water of a halogen tin plating process as set forth in claim 2 in which, said electrolyte solution in said intermediate compartment contains hydrofluoric acid.
Claim 9
Dependent Claim 60 words
A process for recovering tin salts from the waste rinse water of a halogen tin plating process as set forth in claim 2 in which, said electrolyte solution in said intermediate compartment contains hydrofluoric acid and said electrolyte solution in said anode compartment contains a sulphuric acid solution, said intermediate compartment separated from said anode compartment by a cationic membrane.
Claim 10
Dependent Claim 37 words
A process for recovering tin salts from the waste rinse water of a halogen tin plating process as set forth in claim 2 in which, said electrolyte solution in said intermediate compartment contains a hydrofluoric acid solution.
Claim 11
Dependent Claim 27 words
A process for recovering tin salts from waste rinse water as set forth in claim 1 which includes, filtering the rinse wateR and removing insoluble materials therefrom.
Claim 12
Dependent Claim 27 words
A process for recovering tin salts from waste rinse water as set forth in claim 1 which includes, treating the rinse water and removing organic materials therefrom.
Claim 13
Dependent Claim 58 words
A process for recovering tin salts from waste rinse water as set forth in claim 1 which includes, subjecting the rinse water solution with a reduced mole ratio of fluoride to tin to reverse osmosis and removing a substantial portion of the water therefrom to form a concentrated solution having the reduced mole ratio of fluoride to tin.
Claim 14
Dependent Claim 32 words
A process for recovering tin salts from waste rinse water as set forth in claim 1 which includes, introducing the concentrated solution into the plating bath of a halogen tin plating process.
Claim 15
Dependent Claim 37 words
A process for recovering tin salts from waste rinse water as set forth in claim 1 which includes, recycling the water removed from the rinse water solution to the recovery section of a halogen tin plating process.
Claim 16
Dependent Claim 55 words
A process for recovering tin salts from waste rinse water as set forth in claim 1 in which, said waste rinse water contains fluoride and tin in a mole ratio of between 25 and 21:1 and said rinse water withdrawn from said electrodialytic cell contains fluoride and tin in a mole ratio below about 8:1.
Claim 17
Dependent Claim 57 words
A process for recovering tin salts from waste rinse water as set forth in claim 9 which includes, withdrawing a portion of the hydrofluoric acid solution from said intermediate compartment, withdrawing a portion of the sodium hydroxide solution from the cathode compartment, reacting said withdrawn sodium hydroxide solution and hydrofluoric acid solutions to form a sodium bifluoride.
Claim 18
Dependent Claim 47 words
A process for reducing the mole ratio of a halogen to tin in a solution containing a halogen and tin comprising, introducing the solution into an electrodialytic cell, passing a current through the electrodialytic cell and reducing the mole ratio of halogen to tin in the solution.
Claim 19
Dependent Claim 47 words
A process for reducing the mole ratio of a halogen to tin in a solution containing a halogen and tin comprising, introducing the solution into an electrodialytic cell, passing a current through the electrodialytic cell and reducing the mole ratio of halogen to tin in the solution.

References Cited (Backward Citations)

US3124520A Cited
US3347761A Cited
US3481851A Cited
US3787293A Cited
US3787304A Cited
US3788959A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-12-15 1979-06-16 1979-12-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-12-15 1983-06-16 1983-12-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-12-15 1987-06-16 1987-12-16 $7700.00 Window Closed / Lapsed

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