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US3926718A Expired / Lapsed US ⏱️ 0.0 years remaining

Process of improving water drainage from paper webs by addition of a water soluble block polymer to a cellulosic pulp slurry

Assignee: Calgon Corp
•
Filing: 1974-04-30
•
Granted: 1975-12-16
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Expires: 1994-04-30
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Abstract

Abstract The use of water-soluble block polymers of the A-B-A type wherein the A block is derived from a water-soluble monomer and the B block is derived from N-vinyl pyrrolidone as drainage and retention aids for paper webs wherein the polymer is added to a cellulosic pulp slurry.

Inventors

  • 👤 Lawrence James Guilbault
  • 👤 James Richard Zakrzewski

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 09:18
CPC Classifications
D; D21; D21H; D21H17/00; D21H17/20; D21H17/33; D21H17/34; D21H17/41; D21H17/44; D21H17/45; D21H17/455

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 108 words
A PROCESS OF IMPROVING WATER DRINAGE FROM PAPER WEBS COMPRISING ADDING TO A CELLULOSIC PULP SLURRY ABOUT 0.001 TO ABOUT 1%, BASED ON THE DRY WEIGHT OF PULP FIBERS, OF A POLYMER OF THE FORMULA A-B-A WHEREIN THE A BLOCK REPRESENTS FROM 10 TO 100,000 MER UNITS OF A WATER-SOLUBLE MONOMER SELECTED FROM THE GROUP CONSISTING OF 3-ACRYLAMIDO-3-METHYL BUTYL TRIMETHYL AMMONIUM CHLORIDE, 2-ACRYLAMIDO-2-METHYL PROPANE SULFONIC ACID, DIMETHYL DIALLYL AMMONIUM CHLORIDE, METHACRYLOYLOXYETHYL TRIMETHYL AMMONIUM CHLORIDE, METHACRYLOYLOXYETHYL TRIMETHYL AMMONIUM METHOSULFATE AND ACRYLAMIDE AND THE B BLOCK REPRESENTS FROM 10 TO 5,000 MER UNITS OF N-VINYLPYRROLIDONE, DEPOSITING THE PULP ONTO A FORMING SURFACE AND DRAINING THE WATER FROM THE FIBER NETWORK.
Claim 2
Dependent Claim 108 words
A PROCESS OF IMPROVING WATER DRINAGE FROM PAPER WEBS COMPRISING ADDING TO A CELLULOSIC PULP SLURRY ABOUT 0.001 TO ABOUT 1%, BASED ON THE DRY WEIGHT OF PULP FIBERS, OF A POLYMER OF THE FORMULA A-B-A WHEREIN THE A BLOCK REPRESENTS FROM 10 TO 100,000 MER UNITS OF A WATER-SOLUBLE MONOMER SELECTED FROM THE GROUP CONSISTING OF 3-ACRYLAMIDO-3-METHYL BUTYL TRIMETHYL AMMONIUM CHLORIDE, 2-ACRYLAMIDO-2-METHYL PROPANE SULFONIC ACID, DIMETHYL DIALLYL AMMONIUM CHLORIDE, METHACRYLOYLOXYETHYL TRIMETHYL AMMONIUM CHLORIDE, METHACRYLOYLOXYETHYL TRIMETHYL AMMONIUM METHOSULFATE AND ACRYLAMIDE AND THE B BLOCK REPRESENTS FROM 10 TO 5,000 MER UNITS OF N-VINYLPYRROLIDONE, DEPOSITING THE PULP ONTO A FORMING SURFACE AND DRAINING THE WATER FROM THE FIBER NETWORK.
Claim 3
Dependent Claim 12 words
A process as in claim 1 wherein the water-soluble monomer is acrylamide.
Claim 4
Dependent Claim 15 words
A process as in claim 1 wherein the water-soluble monomer is 2-acrylamido-2-methyl propane sulfonic acid.
Claim 5
Dependent Claim 15 words
A process as in claim 1 wherein the water-soluble monomer is methacryloyloxyethyl trimethyl ammonium chloride.
Claim 6
Dependent Claim 103 words
A process of improving the retention of inorganic fillers in the processing of paper which comprises the step of adding to an aqueous paper pulp suspension about 0.001 to about 1%, based on the dry weight of pulp fibers, of a polymer of the formula A-B-A wherein the A block represents from 10 to 100,000 mer units of a water-soluble monomer selected from the group consisting of 3-acrylamido-3-methyl butyl trimethyl ammonium chloride, 2-acrylamido-2-methyl propane sulfonic acid, dimethyl diallyl ammonium chloride, methacryloyloxyethyl trimethyl ammonium chloride, methacryloyloxyethyl trimethyl ammonium methosulfate and acrylamide and the B block represents from 10 to 5,000 mer units of N-vinyl(pyrrolidone).
Claim 7
Dependent Claim 103 words
A process of improving the retention of inorganic fillers in the processing of paper which comprises the step of adding to an aqueous paper pulp suspension about 0.001 to about 1%, based on the dry weight of pulp fibers, of a polymer of the formula A-B-A wherein the A block represents from 10 to 100,000 mer units of a water-soluble monomer selected from the group consisting of 3-acrylamido-3-methyl butyl trimethyl ammonium chloride, 2-acrylamido-2-methyl propane sulfonic acid, dimethyl diallyl ammonium chloride, methacryloyloxyethyl trimethyl ammonium chloride, methacryloyloxyethyl trimethyl ammonium methosulfate and acrylamide and the B block represents from 10 to 5,000 mer units of N-vinyl(pyrrolidone).
Claim 8
Dependent Claim 12 words
A process as in claim 5 wherein the water-soluble monomer is acrylamide.
Claim 9
Dependent Claim 15 words
A process as in claim 5 wherein the water-soluble monomer is 2-acrylamido-2-methyl propane sulfonic acid.
Claim 10
Dependent Claim 15 words
A process as in claim 5 wherein the water-soluble monomer is methacryloyloxyethyl trimethyl ammonium chloride.

References Cited (Backward Citations)

US2922768A Cited
US3036950A Cited
US3450680A Cited
US3280081A Cited
US3417054A Cited
US3468832A Cited
US3706629A Cited
US3776983A Cited
US3790529A Cited
US3826767A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-12-15 1979-06-16 1979-12-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-12-15 1983-06-16 1983-12-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-12-15 1987-06-16 1987-12-16 $7700.00 Window Closed / Lapsed

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