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US3925099A Expired / Lapsed US ⏱️ 0.0 years remaining

Fuel cell with a decarbonation cycle, consuming a mixed fuel

Assignee: Cegelec SA
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Filing: 1975-01-16
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Granted: 1975-12-09
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Expires: 1995-01-16
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Abstract

Abstract The invention consists in injecting a formate into the carbonated electrolyte going from the power section of a methanol-air primary battery to the decarbonation section thereof, in a quantity such that formate ions thus generated jointly with the formate ions formed in the power section by oxidation of methanol ensure the decarbonation of the electrolyte in the decarbonation section of the battery and make it possible to obtain a maximum value of the ratio between the reaction surfaces of the power section and the decarbonation section of the primary cell. More particularly, in certain cases, the injection of methyl formate makes it possible to obviate the separate injecting of methanol and of a formate.

Inventors

  • 👤 Pierre Bono
  • 👤 Philippe Demange
  • 👤 Claudine Leclere
  • 👤 Alexis Tissier

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 20:42
CPC Classifications
H; H01; H01M; H01M8/00; H01M8/06; H01M8/0693; Y; Y02; Y02E; Y02E60/00; Y02E60/30; Y02E60/50

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 236 words
METHOD FOR DECARBONATION OF AN ALKALINE ELECTROLYTE OF A FUEL CELL UTILIZING A CARBONACEOUS FUEL AND AN OXYGEN-CONTAINING OXIDANT, THE ELECTROLYTE AND FUEL BEING SUPPLIED TO THE ANODE COMPARTMENT OF THE POWER PORTION OF THE FUEL CELL AND THE OXIDANT BEING FED TO THE CATHODE COMPARTMENT, SEPARATED FROM SAID ANODE COMPARTMENT BY A FIRST MEMBRANE, OF SAID FUEL CELL, THE ELECTROLYTE BEING DECARBONATED DURING OPERATION OF THE CELL, SAID METHOD COMPRISING THE STEPS OF: WITHDRAWING ELECTROLYTE FROM SAID ANODE COMPARTMENT FOR DECARBONATION; ADDING TO THE ELECTROLYTE THUS WITHDRAWN A MATERIAL CONTAINING FORMATE IONS; PASSING THE MIXTURE OF SAID ELECTROLYTE AND SAID FORMATE ION CONTAINING MATERIAL SUCCESSIVELY THROUGH THE ANODE AND CATHODE COMPARTMENTS OF A DECARBONATION PORTION OF SAID FUEL CELL SAID ANODE COMPARTMENT AND SAID CATHODE COMPARTMENT SEPARATED BY A SECOND MEMBRANE PERMITTING PASSAGE OF OH- IONS, CARBON DIOXIDE BEING REMOVED AFTER PASSAGE OF SAID MIXTURE THROUGH SAID ANODE COMPARTMENT AND BEFORE PASSAGE INTO SAID CATHODE COMPARTMENT, AND RETURNING THE DECARBONATED ELECTROLYTE FROM SAID DECARBONATION PORTION OF SAID FUEL CELL TO SAID ANODE COMPARTMENT OF SAID POWER PORTION OF SAID FUEL CELL, THE AMOUNT OF SAID FORMATE ION CONTAINING MATERIAL ADDED TO THE ELECTROLYTE BEING SUCH THAT THE SUM OF THE FORMATE ION CONTENT OF THE WITHDRAWN ELECTROLYTE RESULTING FROM THE OXIDATION OF SAID CARBONACEOUS FUEL AND THE FORMATE ION CONTENT ADDED AS AFORESAID TO THE ELECTROLYTE IS SUFFICIENT TO PRODUCE COOMPLETE DECARBONATION OF THE ELECTROLYTE.
Claim 2
Dependent Claim 236 words
METHOD FOR DECARBONATION OF AN ALKALINE ELECTROLYTE OF A FUEL CELL UTILIZING A CARBONACEOUS FUEL AND AN OXYGEN-CONTAINING OXIDANT, THE ELECTROLYTE AND FUEL BEING SUPPLIED TO THE ANODE COMPARTMENT OF THE POWER PORTION OF THE FUEL CELL AND THE OXIDANT BEING FED TO THE CATHODE COMPARTMENT, SEPARATED FROM SAID ANODE COMPARTMENT BY A FIRST MEMBRANE, OF SAID FUEL CELL, THE ELECTROLYTE BEING DECARBONATED DURING OPERATION OF THE CELL, SAID METHOD COMPRISING THE STEPS OF: WITHDRAWING ELECTROLYTE FROM SAID ANODE COMPARTMENT FOR DECARBONATION; ADDING TO THE ELECTROLYTE THUS WITHDRAWN A MATERIAL CONTAINING FORMATE IONS; PASSING THE MIXTURE OF SAID ELECTROLYTE AND SAID FORMATE ION CONTAINING MATERIAL SUCCESSIVELY THROUGH THE ANODE AND CATHODE COMPARTMENTS OF A DECARBONATION PORTION OF SAID FUEL CELL SAID ANODE COMPARTMENT AND SAID CATHODE COMPARTMENT SEPARATED BY A SECOND MEMBRANE PERMITTING PASSAGE OF OH- IONS, CARBON DIOXIDE BEING REMOVED AFTER PASSAGE OF SAID MIXTURE THROUGH SAID ANODE COMPARTMENT AND BEFORE PASSAGE INTO SAID CATHODE COMPARTMENT, AND RETURNING THE DECARBONATED ELECTROLYTE FROM SAID DECARBONATION PORTION OF SAID FUEL CELL TO SAID ANODE COMPARTMENT OF SAID POWER PORTION OF SAID FUEL CELL, THE AMOUNT OF SAID FORMATE ION CONTAINING MATERIAL ADDED TO THE ELECTROLYTE BEING SUCH THAT THE SUM OF THE FORMATE ION CONTENT OF THE WITHDRAWN ELECTROLYTE RESULTING FROM THE OXIDATION OF SAID CARBONACEOUS FUEL AND THE FORMATE ION CONTENT ADDED AS AFORESAID TO THE ELECTROLYTE IS SUFFICIENT TO PRODUCE COOMPLETE DECARBONATION OF THE ELECTROLYTE.
Claim 3
Dependent Claim 26 words
A method as defined in claim 1 in which said oxidant is air, said carbonaceous fuel is methanol and said alkaline electrolyte is potassium hydroxide solution.
Claim 4
Dependent Claim 51 words
A method as defined in claim 1 in which said sum of formate content is so maintained as to substantially minimize, for the selectivity characteristics of the particular membrane in use in said decarbonation portion, the decarbonation electrode surface requirement relative to the electrode surface of the fuel cell power portion.
Claim 5
Dependent Claim 19 words
A method as defined in claim 1 in which said formate ion containing material consists essentially of formic acid.
Claim 6
Dependent Claim 22 words
A method as defined in claim 1 in which said formate ion containing material contains at least one ester of formic acid.
Claim 7
Dependent Claim 17 words
A method as defined in claim 5 in which said formate ion containing material comprises methyl formate.
Claim 8
Dependent Claim 58 words
A method as defined in claim 6 in which said carbonaceous fuel is methanol and in which the methyl formate content of said formate ion containing material is such as to substantially dispense with the addition of methanol to said anode compartment of said power portion of said fuel cell for maintaining continuing operation of said fuel cell.
Claim 9
Dependent Claim 184 words
A fuel cell comprising a power portion and a decarbonation portion each having an anode compartment and a cathode compartment separated by a membrane; means for circulating an oxygen-containing oxidant gas through the respective cathode compartments of said power portion and said decarbonator portion; means for supplying an alkaline electrolyte solution and a carbonaceous fuel to the anode compartment of said power portion; means for removing carbonated electrolyte from said anode compartment of said power portion; means for adding a formate ion containing material to said carbonated electrolyte and thereafter supplying said carbonated electrolyte and said formate ion containing material to the anode compartment of said decarbonator portion; means for removing electrolyte from the anode compartment of said decarbonator portion and supplying it to the cathode compartment of said decarbonator portion; means for venting carbon dioxide from said electrolyte after passage through the anode compartment of said decarbonator portion; and means for removing decarbonated electrolyte from the cathode compartment of said decarbonator portion and returning it to said means for supplying electrolyte to the anode portion of said power portion of said fuel cell.
Claim 10
Dependent Claim 184 words
A fuel cell comprising a power portion and a decarbonation portion each having an anode compartment and a cathode compartment separated by a membrane; means for circulating an oxygen-containing oxidant gas through the respective cathode compartments of said power portion and said decarbonator portion; means for supplying an alkaline electrolyte solution and a carbonaceous fuel to the anode compartment of said power portion; means for removing carbonated electrolyte from said anode compartment of said power portion; means for adding a formate ion containing material to said carbonated electrolyte and thereafter supplying said carbonated electrolyte and said formate ion containing material to the anode compartment of said decarbonator portion; means for removing electrolyte from the anode compartment of said decarbonator portion and supplying it to the cathode compartment of said decarbonator portion; means for venting carbon dioxide from said electrolyte after passage through the anode compartment of said decarbonator portion; and means for removing decarbonated electrolyte from the cathode compartment of said decarbonator portion and returning it to said means for supplying electrolyte to the anode portion of said power portion of said fuel cell.

References Cited (Backward Citations)

US3511713A Cited
US3703416A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-12-08 1979-06-09 1979-12-09 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-12-08 1983-06-09 1983-12-09 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-12-08 1987-06-09 1987-12-09 $7700.00 Window Closed / Lapsed

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