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US3923945A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of making corrosion resistant metal fiber reinforced plastic composites

Assignee: Bethlehem Steel Corp
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Filing: 1974-01-22
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Granted: 1975-12-02
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Expires: 1994-01-22
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Abstract

Abstract A method of making metal fiber reinforced plastic composite from a mixture of ferrous fibers and sacrificial metal fibers. The sacrificial metal fibers may be ferrous fibers coated with a sacrificial metal or may be composed throughout of a sacrificial metal such as zinc having a greater electro negativity than iron. The fibers may also comprise ferrous fibers coated with a sacrificial metal mixed with solid sacrificial metal fibers. The ferrous and sacrificial metal fibers are cut into fairly short lengths and are then blended thoroughly together in predetermined ratios with plastic powder in suitable blenders to form a uniform mix having the sacrificial metal fibers thoroughly dispersed throughout the ferrous metal fibers and the plastic. The blend of metal fibers and plastic is then placed in a mold or other plastic forming apparatus and molded into a desired shape. The final molded plastic composite is corrosion resistant on cut surfaces due to the presence of the sacrificial metal fibers within a distance of the ferrous fibers effective to form galvanic corrosion couples between the ferrous and sacrificial metal fibers.

Inventors

  • 👤 Darral V Humphries

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 03:59
CPC Classifications
B; B29; B29C; B29C70/00; B29C70/04; B29C70/28

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 278 words
A METHOD OF MAKING CORROSION RESISTANT METAL REINFORCED PLASTIC COMPOSITITES COMPRISING: A. SEVERING FERROUS METAL WIRES INTO DISCRETE SEGMENTS OF FERROUS METAL FIBERS, . SEVERING SACRIFICIAL METAL WIRES HAVING A GREATER ELECTRONEGATIVITY THAN IRON INTO DISCRETE SEGMENTS OF SACRIFICAL METAL FIBERS, C. UNIFORMLY BLENDING FOR A TIME IN A BLENDING APPARATUS PREFETERMINED PROPORTIONS OF THE SEGMENTED FERROUS METAL FIBERS, THE SEGMENTED SACRIFICIAL METAL FIBERS AND DRY GRANULES OF A RESIN SELECTED FROM THE GROUP CONSISTING OF THERMOPLASTIC AND THERMOSETTING RESINS TOGETHER INTO A UNIFORM MIX OF FERROUS METAL FIBERS, SACRIFICIAL METAL FIBERS AND RESIN IN A RATIO IN A UNIFORM DRY MIX SUCH THAT UPON SUBSEQUENT FUSION AND SOLIDFICATION OF THE RESIN THE RELATIVE PERCENTAGES AND DISTRIBUTION OF THE FERROUS FIBERS AND SACRIFICAL METAL FIBERS IN THE SOLIDIFIED RESIN ARE SUCH THAT SUBSTANTIALLY NO FERROUS FIBER IS SPACED FROM A SACRIICIAL METAL FIBER ALONG A CUT SURFACE OF THE SOLIDIFIED COMPOSITE MORE THAN THE DISTANCE EFFECTIVE TO FROM A GALVANIC CORROSION COUPLE BETWEEN SUBSTANTIALLY EACH FERROUS FIBER AND THE NEAREST SACRIFICIAL METAL FIBER AND THE FERROUS FIBERS ARE IN AT LEAST OCCASIONAL ELECTRICAL CONTACT WITH THE SACRIFICIAL METAL FIBERS THROUGHOUT THE SOLIDIFIED RESIN, D. DIRECTING SAID BLEND OF FERROUS METAL FIBERS, SACRIFICIAL METAL FIBERS AND RESIN GRANULES INTO A MOLDING DEVICE, E. HEATING AND PRESSURIZING THE RESIN GRANULES IN SAID MOLDING DEVICE TO FUSE AND COALESCE SAID RESIN INTO A PLASTIC MATAX THROUGH WHICH SAID FERROUS AND SACRIFICIAL METAL FIBERS ARE UNIFORMLY DISTRIBUTED IN THE RELATIONSHIP DESCRIBED IN STEP (C) ABOVE, AND F. COOLING SAID PLASTIC MATRIX TO CAUSE SOLIDIFICATION OF SAID PLASTIC MATRIX ABOUT SAID FERROUS AND SACRIFICIAL METAL FIBERS TO FORM A METAL REINFORCED PLASTIC COMPOSITE.
Claim 2
Independent Claim 278 words
A METHOD OF MAKING CORROSION RESISTANT METAL REINFORCED PLASTIC COMPOSITITES COMPRISING: A. SEVERING FERROUS METAL WIRES INTO DISCRETE SEGMENTS OF FERROUS METAL FIBERS, . SEVERING SACRIFICIAL METAL WIRES HAVING A GREATER ELECTRONEGATIVITY THAN IRON INTO DISCRETE SEGMENTS OF SACRIFICAL METAL FIBERS, C. UNIFORMLY BLENDING FOR A TIME IN A BLENDING APPARATUS PREFETERMINED PROPORTIONS OF THE SEGMENTED FERROUS METAL FIBERS, THE SEGMENTED SACRIFICIAL METAL FIBERS AND DRY GRANULES OF A RESIN SELECTED FROM THE GROUP CONSISTING OF THERMOPLASTIC AND THERMOSETTING RESINS TOGETHER INTO A UNIFORM MIX OF FERROUS METAL FIBERS, SACRIFICIAL METAL FIBERS AND RESIN IN A RATIO IN A UNIFORM DRY MIX SUCH THAT UPON SUBSEQUENT FUSION AND SOLIDFICATION OF THE RESIN THE RELATIVE PERCENTAGES AND DISTRIBUTION OF THE FERROUS FIBERS AND SACRIFICAL METAL FIBERS IN THE SOLIDIFIED RESIN ARE SUCH THAT SUBSTANTIALLY NO FERROUS FIBER IS SPACED FROM A SACRIICIAL METAL FIBER ALONG A CUT SURFACE OF THE SOLIDIFIED COMPOSITE MORE THAN THE DISTANCE EFFECTIVE TO FROM A GALVANIC CORROSION COUPLE BETWEEN SUBSTANTIALLY EACH FERROUS FIBER AND THE NEAREST SACRIFICIAL METAL FIBER AND THE FERROUS FIBERS ARE IN AT LEAST OCCASIONAL ELECTRICAL CONTACT WITH THE SACRIFICIAL METAL FIBERS THROUGHOUT THE SOLIDIFIED RESIN, D. DIRECTING SAID BLEND OF FERROUS METAL FIBERS, SACRIFICIAL METAL FIBERS AND RESIN GRANULES INTO A MOLDING DEVICE, E. HEATING AND PRESSURIZING THE RESIN GRANULES IN SAID MOLDING DEVICE TO FUSE AND COALESCE SAID RESIN INTO A PLASTIC MATAX THROUGH WHICH SAID FERROUS AND SACRIFICIAL METAL FIBERS ARE UNIFORMLY DISTRIBUTED IN THE RELATIONSHIP DESCRIBED IN STEP (C) ABOVE, AND F. COOLING SAID PLASTIC MATRIX TO CAUSE SOLIDIFICATION OF SAID PLASTIC MATRIX ABOUT SAID FERROUS AND SACRIFICIAL METAL FIBERS TO FORM A METAL REINFORCED PLASTIC COMPOSITE.
Claim 3
Dependent Claim 34 words
A method of making a corrosion resistant metal reinforced plastic composite according to claim 1 wherein the sacrificial metal fibers are comprised of a ferrous metal core and an outer layer of sacrificial metal.
Claim 4
Dependent Claim 36 words
A method of making a corrosion resistant metal reinforced plastic composite according to claim 2 wherein the ferrous and sacrificial metal fibers are between about one-eighth of an inch and one-half of an inch in length.
Claim 5
Dependent Claim 63 words
A method of making a corrosion resistant metal reinforced plastic composite according to claim 3 wherein the sacrificial metal is zinc and the ratio of the mix of the ferrous fibers, sacrificial metal fibers and resin is such that substantially no ferrous fiber is significantly more than one-eighth of an inch from the nearest adjoining zinc fiber after solidification of the matrix plastic.
Claim 6
Dependent Claim 64 words
A method of making a corrosion resistant metal reinforced plastic composite according to claim 1 wherein the sacrificial metal is zinc and the ratio of the mix of the sacrificial metal fibers, ferrous fibers and resin is such that substantially no ferrous fiber is spaced significantly more than one-eighth of an inch from the nearest adjoining zinc fiber after solidification of the matrix plastic.
Claim 7
Dependent Claim 36 words
A method of making a corrosion resistant metal reinforced plastic composite according to claim 5 wherein the ferrous and sacrificial metal fibers are between about one-eighth of an inch and one-half of an inch in length.
Claim 8
Independent Claim 290 words
A method of making a corrosion resistant metal reinforced plastic composite comprising: a. chopping steel wool into descrete segments of ferrous metal fibers, b. chopping a metal wool comprised of a sacrificial metal having a greater electronegativity than iron into discrete segments of sacrificial metal fibers, c. uniformly blending for a time in a blending apparatus predetermined proportions of the segmented ferrous metal fibers, the segmented sacrificial metal fibers and dry granules of a resin selected from the group consisting of thermoplastic and thermosetting resins together into a uniform mix of ferrous metal fibers, sacrificial metal fibers and resin in a ratio in a uniform dry mix such that upon subsequent fusion and solidification of the resin the relative percentages and distribution of the ferrous fibers and sacrificial metal fibers in the solidified resin are such that substantially no ferrous metal fiber is spaced from a sacrificial metal fiber along a cut surface of the solidified composite more than the distance effective to form a galvanic corrosion couple between substantially each ferrous metal fiber and the nearest sacrificial metal fiber and the ferrous fibers are in at least occasional electrical contact with the sacrificial metal fibers throughout the solidified resin, d. directing said blend of ferrous fibers, sacrificial metal fibers and resin granules into a mold, e. heating and pressurizing the resin granules in said mold to fuse and coalesce said resin into a plastic matrix throughout which said ferrous and sacrificial metal fibers are uniformly distributed in the relationship described in step (c) above, and f. cooling said plastic matrix to cause solidification of the plastic matrix about the ferrous and sacrificial metal fibers in said mold and subsequently removing the solidified corrosion resistant metal reinforced plastic composite therefrom.
Claim 9
Independent Claim 290 words
A method of making a corrosion resistant metal reinforced plastic composite comprising: a. chopping steel wool into descrete segments of ferrous metal fibers, b. chopping a metal wool comprised of a sacrificial metal having a greater electronegativity than iron into discrete segments of sacrificial metal fibers, c. uniformly blending for a time in a blending apparatus predetermined proportions of the segmented ferrous metal fibers, the segmented sacrificial metal fibers and dry granules of a resin selected from the group consisting of thermoplastic and thermosetting resins together into a uniform mix of ferrous metal fibers, sacrificial metal fibers and resin in a ratio in a uniform dry mix such that upon subsequent fusion and solidification of the resin the relative percentages and distribution of the ferrous fibers and sacrificial metal fibers in the solidified resin are such that substantially no ferrous metal fiber is spaced from a sacrificial metal fiber along a cut surface of the solidified composite more than the distance effective to form a galvanic corrosion couple between substantially each ferrous metal fiber and the nearest sacrificial metal fiber and the ferrous fibers are in at least occasional electrical contact with the sacrificial metal fibers throughout the solidified resin, d. directing said blend of ferrous fibers, sacrificial metal fibers and resin granules into a mold, e. heating and pressurizing the resin granules in said mold to fuse and coalesce said resin into a plastic matrix throughout which said ferrous and sacrificial metal fibers are uniformly distributed in the relationship described in step (c) above, and f. cooling said plastic matrix to cause solidification of the plastic matrix about the ferrous and sacrificial metal fibers in said mold and subsequently removing the solidified corrosion resistant metal reinforced plastic composite therefrom.
Claim 10
Dependent Claim 34 words
A method of making a corrosion resistant metal reinforced plastic composite according to claim 7 wherein the sacrificial metal fibers are comprised of a ferrous metal core and an outer layer of sacrificial metal.
Claim 11
Dependent Claim 63 words
A method of making a corrosion resistant metal reinforced plastic composite according to claim 8 wherein the sacrificial metal is zinc and the ratio of the mix of the ferrous fibers, sacrificial metal fibers and resin is such that substantially no ferrous fiber is spaced more than one-eighth of an inch from the nearest adjoining zinc fiber after solidification of the matrix plastic.
Claim 12
Dependent Claim 64 words
A method of making a corrosion resistant metal reinforced plastic composite according to claim 7 wherein the sacrificial metal fibers are zinc fibers and the ratio of the mix of the ferrous fibers, sacrificial metal fibers and resin is such that substantially no ferrous fiber is spaced more than one-eighth of an ich from the nearest adjoining zinc fiber after solidification of the plastic.

References Cited (Backward Citations)

US3410936A Cited
US3539672A Cited
US3678145A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-12-01 1979-06-02 1979-12-02 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-12-01 1983-06-02 1983-12-02 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-12-01 1987-06-02 1987-12-02 $7700.00 Window Closed / Lapsed

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