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US3922464A Expired / Lapsed US ⏱️ 0.0 years remaining

Removable pressure-sensitive adhesive sheet material

Assignee: 3M Co
•
Filing: 1973-02-06
•
Granted: 1975-11-25
•
Expires: 1993-02-06
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Abstract

Abstract A flexible self-sustaining backing is coated with a stable viscous copolymer latex formed from monomers of (1) major amounts of certain alkyl acrylates, (2) minor amounts of certain emulsifier monomers, and (3) if desired, minor amounts of zwitterionic monomers, and the water evaporated from the latex to leave a tacky and pressure-sensitive adhesive. When tape prepared in this way is applied to enameled or lacquered substrates, it can be removed without leaving an adhesive residue, even after extended exposure to heat and light. Other sheet materials (e.g., floor tile, carpeting, label stock, etc.) are similarly removable when provided with this adhesive.

Inventors

  • 👤 Spencer F Silver
  • 👤 Louis E Winslow
  • 👤 Alvin R Zigman

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 20:45
CPC Classifications
C; C09; C09J; C09J133/00; C09J133/04; C09J133/06; C09J133/08; C09J7/00; C09J7/20; C09J7/21; C09J7/30; C09J7/38; C09J2301/00; C09J2301/30; C09J2301/302; Y; Y10; Y10T; Y10T428/00; Y10T428/28; Y10T428/2852; Y10T428/2878; Y10T428/2891; Y10T428/31504; Y10T428/31855

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 248 words
IN ADHESIVE-COATED SHEET MATERIAL COMPRISING IN COMBINATION A SELF-SUSTAINING BACKING SHEET HAVING A LAYER OF NORMALLY TACKY AND PRESSURE-SENSITIVE ADHESIVE BONDED TO AT LEAST ONE FACE THEREOF, THE IMPROVEMENT WHICH COMPRISES USING AS SAID ADHESIVE A COPOLYMER OF MONOMERS CONSISTING ESSENTIALLY OF A. FROM 88 TO 99 PARTS BY WEIGHT OF AT LEAST ONE TERMINALLY UNSATURATED VINYL MONOMER, 70 TO 100 WEIGHT PERCENT OF SAID VINYL MONOMER BEING SELECTED FROM THE CLASS OF NON-TERITARY ALKYL ACRYLATES WHEREIN EACH ALKYL GROUP HAS AT LEAST HALF OF ITS CARBON ATOMS IN A SINGLE CHAIN AND THE AVERAGE LENGTH OF THE ALKYL CHAIN IS MORE THAN 4 AND NOT MORE THAN 12. B. FROM 0.2 TO 5 PARTS BY WEIGHT OF AT LELAST ONE VINYLUNSATURATED, HOMOPOLYMERIZABLE EMULSIFIER MONOMER WHICH IS A SURFACTANT HAVING BOTH A HYDROPHOBIC AND A HYDROPHILIC MOIETY, CONTAINS AT LEAST 5 BUT NOT MORE THAN 40 CARBON ATOMS AND IS NONIONIC AND OR WATER-DISPERSIBLE, AND C. FROM 0 TO 10 PARTS BY WEIGHT OF AT LAST ONE ZWITTERION MONOMER HAVING A FREE RADICALLY POLYMERIZABLE UNSATURATED GROUP, THE TOTAL PARTS BY WEIGHT OF (B) PLUS (C) BEING AT LEAST 1 AND NOT MORE THAN 12, AND THE TOTAL PARTS BY WEIGHT OR (A) PLUS (B) PLUS (C) BEING 100, WHEREBY SAID ADHESIVE-COATED SHEET MATERIAL CAN BE SUFFICIENTLY FIRMLY ADHERED TO ENAMELED OR LACQURED SURFACES TO SATISFY THE REQUIREMENTS OF A MASKING TAPE AND REMOVED CLEANLY THEREFROM, EVEN AFTER EXPOSURE TO HEAT, FOR EXAMPLE, 250*F FOR 1 HOUR, AND LIGHT.
Claim 2
Dependent Claim 248 words
IN ADHESIVE-COATED SHEET MATERIAL COMPRISING IN COMBINATION A SELF-SUSTAINING BACKING SHEET HAVING A LAYER OF NORMALLY TACKY AND PRESSURE-SENSITIVE ADHESIVE BONDED TO AT LEAST ONE FACE THEREOF, THE IMPROVEMENT WHICH COMPRISES USING AS SAID ADHESIVE A COPOLYMER OF MONOMERS CONSISTING ESSENTIALLY OF A. FROM 88 TO 99 PARTS BY WEIGHT OF AT LEAST ONE TERMINALLY UNSATURATED VINYL MONOMER, 70 TO 100 WEIGHT PERCENT OF SAID VINYL MONOMER BEING SELECTED FROM THE CLASS OF NON-TERITARY ALKYL ACRYLATES WHEREIN EACH ALKYL GROUP HAS AT LEAST HALF OF ITS CARBON ATOMS IN A SINGLE CHAIN AND THE AVERAGE LENGTH OF THE ALKYL CHAIN IS MORE THAN 4 AND NOT MORE THAN 12. B. FROM 0.2 TO 5 PARTS BY WEIGHT OF AT LELAST ONE VINYLUNSATURATED, HOMOPOLYMERIZABLE EMULSIFIER MONOMER WHICH IS A SURFACTANT HAVING BOTH A HYDROPHOBIC AND A HYDROPHILIC MOIETY, CONTAINS AT LEAST 5 BUT NOT MORE THAN 40 CARBON ATOMS AND IS NONIONIC AND OR WATER-DISPERSIBLE, AND C. FROM 0 TO 10 PARTS BY WEIGHT OF AT LAST ONE ZWITTERION MONOMER HAVING A FREE RADICALLY POLYMERIZABLE UNSATURATED GROUP, THE TOTAL PARTS BY WEIGHT OF (B) PLUS (C) BEING AT LEAST 1 AND NOT MORE THAN 12, AND THE TOTAL PARTS BY WEIGHT OR (A) PLUS (B) PLUS (C) BEING 100, WHEREBY SAID ADHESIVE-COATED SHEET MATERIAL CAN BE SUFFICIENTLY FIRMLY ADHERED TO ENAMELED OR LACQURED SURFACES TO SATISFY THE REQUIREMENTS OF A MASKING TAPE AND REMOVED CLEANLY THEREFROM, EVEN AFTER EXPOSURE TO HEAT, FOR EXAMPLE, 250*F FOR 1 HOUR, AND LIGHT.
Claim 3
Dependent Claim 49 words
The product of claim 1 wherein the adhesive-coated sheet material is normally tacky and pressure-sensitive adhesive tape which is capable of being wound convolutely upon itself in roll form, unwound therefrom without transfer of the adhesive to the opposite surface of the backing, and applied in a desired location.
Claim 4
Dependent Claim 26 words
The tape of claim 2 wherein the copolymer composition is such that the total parts by weight of (b) plus (c) is from 2 to 5.
Claim 5
Dependent Claim 22 words
The tape of claim 3 wherein the copolymer composition is such that the parts by weight of (b) is at least 1.
Claim 6
Dependent Claim 16 words
The tape of claim 4 wherein the terminally unsaturated vinyl monomer consists essentially of iso-octyl acrylate.
Claim 7
Dependent Claim 27 words
The tape of claim 5 wherein the terminally unsaturated vinyl monomer consists essentially of about 85 weight percent iso-octyl acrylate and about 15 weight percent isobutyl acrylate.
Claim 8
Dependent Claim 23 words
The tape of claim 6 wherein the copolymer contains about 1 part by weight emulsifier monomer and 2 parts by weight zwitterion monomer.
Claim 9
Dependent Claim 23 words
The tape of claim 7 wherein the emulsifier monomer is a salt of sulfoethyl methacrylate and the zwitterion monomer is 1,1-dimethyl-1-(2-hydroxyoctyl) amine methacrylimide.
Claim 10
Dependent Claim 14 words
The product of claim 2 wherein the pressure-sensitive adhesive tape product is masking tape.
Claim 11
Dependent Claim 16 words
The tape of claim 9 wherein the pressure-sensitive adhesive contains minor amounts of an external emulsifier.

References Cited (Backward Citations)

US2795515A Cited
US3024221A Cited
US3579490A Cited
US3547852A Cited
US3551479A Cited
US3725122A Cited
US3660431A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-11-24 1979-05-26 1979-11-25 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-11-24 1983-05-26 1983-11-25 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-11-24 1987-05-26 1987-11-25 $7700.00 Window Closed / Lapsed

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