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US3921733A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of drilling a borehole using gelled polymers

Assignee: Drilling Specialties Co
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Filing: 1973-06-22
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Granted: 1975-11-25
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Expires: 1993-06-22
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Abstract

Abstract Improvements in secondary recovery operations for the recovery of oil, and improvements in well drilling operations, are accomplished through the use of aqueous mediums comprising aqueous gels prepared from water and certain polymers such as polyacrylamides and related polymers.

Inventors

  • 👤 Richard L Clampitt

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 08:39
CPC Classifications
C; C09; C09K; C09K8/00; C09K8/60; C09K8/84; C09K8/86; C09K8/88; C09K8/887; C09K8/02; C09K8/04; C09K8/14; C09K8/18; C09K8/22; C09K8/24; Y; Y10; Y10S; Y10S507/00; Y10S507/903

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 286 words
IN A METHOD FOR DRILLING A BOREHOLE INTO THE EARTH WHEREIN A DRILL BIT IS ACTUATED IN SAID BOREHOLE AND PENETRATES A SUBTERRANEAN FORMATION IN THE PRESENCE OF A DRILLING FLUID, AND SAID DRILLING FLUID, TOGETHER WITH FORMATION SOLIDS ENTRAINED THEREIN, IS REMOVED FROM SAID BOREHOLE, THE IMPROVEMENT WHEREIN SAID DRILLING FLUID COMPRISES AS AQUEOUS GEL, AND WHEREIN SAID GEL COMPRISES WATER TO WHICH THERE HAS BEEN ADDED: A WATER THICKENING AMOUNT OF A WATER-DISPERSIBLE POLYMER SELECTED FROM THE GROUP CONSISTING OF: POLYACRYLAMIDES AND POLYMETHACRYLAMIDES WHEREIN UP TO ABOUT 75 PERCENT OF THE CARBOXAMIDE GROUPS CAN BE HYDROLYZED TO CARBOXYL GROUPS; CROSSLINKED POLYACRYLAMIDES AND CROSSLINKED POLYMETHACRYLAMIDES WHEREIN UP TO ABOUT 75 PERCENT OF THE CARBOXAMIDE GROUPS CAN BE HYDROLYZED TO CARBOXYL GROUPS; POLYACRYLIC ACID AND POLYMETHACRYLIC ACID; POLYACRYLATES; POLYMERS OF N-SUBSTITUTED ACRYLAMIDES WHEREIN THE NITROGEN ATOMS IN THE CARBOXAMIDE GROUPS CAN HAVE FROM 1 TO 2 ALKYL SUBSTITUTENTS WHICH CONTAIN FROM 1 TO 4 CARBON ATOMS; CAPOLYMERS OF ACRYLAMIDE WITH ANOTHER ETHYLENICALLY UNSATURATED MONOMER COPOLYMERIZABLE THEREWITH, SUFFICIENT ACRYLAMIDE BEING PRESENT IN THE MONOMER MIXTURE TO IMPART SAID WATER-DISPERSIBLE PROPERTIES TO THE RESULTING COPOLYMER WHEN IT IS MIXED WITH WATER, AND WHEREIN UP TO ABOUT 75 PERCENT OF CARBOXAMIDE GROUPS CAN BE HYDROLYZED TO CARBOXYL GROUPS; AND MIXTURES OF SAID POLYMERS; A SENSIBLE AMOUNT OF WATER-SOLUBLE COMPOUND OF A POLYVALENT METAL WHEREIN THE METAL PRESENT IS CAPABLE OF BEING REDUCED TO A LOWER POLYVALENT VALENCE STATE AND WHICH IS SUFFICIENT TO GEL SAID WATER WHEN THE VALENCE OF AT LEAST A PORTION OF SAID METAL IS REDUCED TO SAID LOWER VALENCE STATE; AND AN AMOUNT OF A WATER-SOLUBLE REDUCING AGENT WHICH IS EFFECTIVE TO REDUCE AT LEAST A PORTION OF SAID METAL TO SAID LOWER VALENCE STATE.
Claim 2
Dependent Claim 286 words
IN A METHOD FOR DRILLING A BOREHOLE INTO THE EARTH WHEREIN A DRILL BIT IS ACTUATED IN SAID BOREHOLE AND PENETRATES A SUBTERRANEAN FORMATION IN THE PRESENCE OF A DRILLING FLUID, AND SAID DRILLING FLUID, TOGETHER WITH FORMATION SOLIDS ENTRAINED THEREIN, IS REMOVED FROM SAID BOREHOLE, THE IMPROVEMENT WHEREIN SAID DRILLING FLUID COMPRISES AS AQUEOUS GEL, AND WHEREIN SAID GEL COMPRISES WATER TO WHICH THERE HAS BEEN ADDED: A WATER THICKENING AMOUNT OF A WATER-DISPERSIBLE POLYMER SELECTED FROM THE GROUP CONSISTING OF: POLYACRYLAMIDES AND POLYMETHACRYLAMIDES WHEREIN UP TO ABOUT 75 PERCENT OF THE CARBOXAMIDE GROUPS CAN BE HYDROLYZED TO CARBOXYL GROUPS; CROSSLINKED POLYACRYLAMIDES AND CROSSLINKED POLYMETHACRYLAMIDES WHEREIN UP TO ABOUT 75 PERCENT OF THE CARBOXAMIDE GROUPS CAN BE HYDROLYZED TO CARBOXYL GROUPS; POLYACRYLIC ACID AND POLYMETHACRYLIC ACID; POLYACRYLATES; POLYMERS OF N-SUBSTITUTED ACRYLAMIDES WHEREIN THE NITROGEN ATOMS IN THE CARBOXAMIDE GROUPS CAN HAVE FROM 1 TO 2 ALKYL SUBSTITUTENTS WHICH CONTAIN FROM 1 TO 4 CARBON ATOMS; CAPOLYMERS OF ACRYLAMIDE WITH ANOTHER ETHYLENICALLY UNSATURATED MONOMER COPOLYMERIZABLE THEREWITH, SUFFICIENT ACRYLAMIDE BEING PRESENT IN THE MONOMER MIXTURE TO IMPART SAID WATER-DISPERSIBLE PROPERTIES TO THE RESULTING COPOLYMER WHEN IT IS MIXED WITH WATER, AND WHEREIN UP TO ABOUT 75 PERCENT OF CARBOXAMIDE GROUPS CAN BE HYDROLYZED TO CARBOXYL GROUPS; AND MIXTURES OF SAID POLYMERS; A SENSIBLE AMOUNT OF WATER-SOLUBLE COMPOUND OF A POLYVALENT METAL WHEREIN THE METAL PRESENT IS CAPABLE OF BEING REDUCED TO A LOWER POLYVALENT VALENCE STATE AND WHICH IS SUFFICIENT TO GEL SAID WATER WHEN THE VALENCE OF AT LEAST A PORTION OF SAID METAL IS REDUCED TO SAID LOWER VALENCE STATE; AND AN AMOUNT OF A WATER-SOLUBLE REDUCING AGENT WHICH IS EFFECTIVE TO REDUCE AT LEAST A PORTION OF SAID METAL TO SAID LOWER VALENCE STATE.
Claim 3
Dependent Claim 81 words
A method according to claim 1 wherein said aqueous gel comprises water to which there has been added: from 0.0025 to 5 weight percent of said polymer, based upon the weight of said water; from 0.05 to 60 weight percent of said polyvalent metal compound based upon the weight of said polymer; and from 0.1 to at least about 200 percent of the stoichiometric amount of said reducing agent required to reduce said polyvalent metal to said lower polyvalent valence state.
Claim 4
Dependent Claim 28 words
A method according to claim 2 wherein: said polymer is a substantially linear polyacrylamide; said polyvalent metal compound is sodium dichromate; and said reducing agent is sodium hydrolsulfite.
Claim 5
Dependent Claim 16 words
A method according to claim 2 wherein: said polymer is a substantially linear polymer of acrylamide.
Claim 6
Dependent Claim 41 words
A method according to claim 4 wherein said compound of a polyvalent metal is a compound of chromium wherein the valence of the chromium is +6 and the valence of at least a portion of said chromium is reduced to +3.
Claim 7
Dependent Claim 32 words
A method according to claim 5 wherein said chromium compound is selected from the group consisting of ammonium chromate, ammonium dichromate, the alkali metal chromates and dichromates, chromium trioxide, and mixtures thereof.
Claim 8
Dependent Claim 49 words
A method according to claim 6 wherein said reducing agent is selected from the group consisting of hydroquinone, sodium sulfide, sodium hydrosulfite, sodium metabisulfite, potassium sulfite, sodium bisulfite, potassium metabisulfite, sodium sulfite, sodium thisosulfate, ferrous sulfate, hydrogen sulfide, ferrous chloride, p-hydrazinobenzoic acid, hydrazine phosphite, hydrazine dihydrochloride, and mixtures thereof.
Claim 9
Dependent Claim 39 words
A method according to claim 7 wherein: said polyvalent metal compound is sodium dichromate or potassium dichromate; and said reducing agent is selected from the group consisting of sodium metabisulfite, potassium metabisulfite, sodium hydrosulfite, potassium hydrosulfite, and mixtures thereof.
Claim 10
Dependent Claim 37 words
A method according to claim 1 whErein said drilling fluid is a water base low solids drilling fluid comprising, in addition to said aqueous gel, up to about 5 volume per cent of finely divided clay solids.
Claim 11
Dependent Claim 27 words
A method according to claim 9 wherein said drilling fluid contains from 0.05 to about 1.5 pounds of said aqueous gel per barrel of said drilling fluid.
Claim 12
Dependent Claim 34 words
A method according to claim 9 wherein the amount of said aqueous gel contained in said drilling fluid is within the range of from 0.1 to 1 pound per barrel of said drilling fluid.
Claim 13
Dependent Claim 79 words
A method according to claim 9 wherein said aqueous gel comprises water to which there has been added: from 0.0025 to 5 weight percent of said polymer, based upon the weight of said water; from 0.5 to 30 weight percent of said polyvalent metal compound, based upon the weight of said polymer; and from 0.5 to about 200 percent of the stoichiometric amount of said reducing agent required to reduce said polyvalent metal to said lower polyvalent valvence state.
Claim 14
Dependent Claim 119 words
A method according to claim 12 wherein: said polymer is a substantiually linear polymer of acrylamide; said compound of a polyvalent metal is a compound of chromium wherein the valence of the chromium is +6 and the valence of at least a portion of said chromium is reduced to +3, and said chromium compound is selected from the group consisting of ammonium chromate, ammonium dichromate, the alkali metal chromates and dichromates, chromium trioxide, and mixtures thereof; and said reducing agent is selected from the group consisting of hydroquinone, sodium sulfide, sodium hydrosulfite, sodium metabisulfite, potassium sulfite, sodium bisulfite, potassium metabisulfite, sodium sulfite, sodium thiosulfate, ferrous sulfate, hydrogen sulfide, ferrous chloride, p-hydrazinobenzoic acid, hydrazine phosphite, hydrazine dihydrochloride, and mixtures thereof.
Claim 15
Dependent Claim 57 words
A method according to claim 13 wherein: said drilling fluid is a water base low solids drilling fluid comprising, in addition to said aqueous gel, up to about 5 volume percent of finely divided clay solids; and said drilling fluid contains from 0.05 to about 1.5 pounds of said aqueous gel per barrel of said drilling fluid.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-11-24 1979-05-26 1979-11-25 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-11-24 1983-05-26 1983-11-25 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-11-24 1987-05-26 1987-11-25 $7700.00 Window Closed / Lapsed

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