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US3658129A Expired / Lapsed US ⏱️ 0.0 years remaining

In situ gelation of polymers during waterflooding

Assignee: Phillips Petroleum Co
•
Filing: 1970-09-01
•
Granted: 1972-04-25
•
Expires: 1990-09-01
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Abstract

Abstract A method for plugging waterflood zones through the in situ production of gelatinous materials derived from injecting a solution containing a water-soluble bivalent metal salt and a water-soluble polymer of high molecular weight having groups chemically reactive with trivalent metal ions into a waterflood zone followed by the injection of air which converts bivalent metal ions to trivalent metal ions thereby resulting in the aforementioned gelatinous plugging material.

Inventors

  • 👤 William C Lanning
  • 👤 James W Gall

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 13:45
CPC Classifications
C; C09; C09K; C09K8/00; C09K8/50; C09K8/504; C09K8/506; C09K8/508; C09K8/512

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 31 words
The method according to claim 1 wherein the polymer has a molecular weight of at least 100,000 and is selected from at least one of carboxylated cellulose and partly hydrolyzed polyacrylamide.
Claim 2
Dependent Claim 31 words
A method according to claim 1 wherein the bivalent metal salt is selected from at least one of ferrous sulfate, ferrous chloride, ferrous nitrate, chromous chloride, chromous nitrate, and chromous acetate.
Claim 3
Dependent Claim 32 words
A method according to claim 1 wherein the bivalent metal salt is a ferrous salt and the ratio of ferrous salt to polymer by weight is from about 1.0 to about 0.006.
Claim 4
Dependent Claim 33 words
A method according to claim 1 wherein the oxygen content of the solution containing the water-soluble bivalent metal salt and the water-soluble polymer is from about 0.1 to about 4.0 parts per million.
Claim 5
Dependent Claim 26 words
A method according to claim 1 wherein the water-sOluble bivalent metal salt and water-soluble polymer solution is introduced to the waterflood zone in a continuous method.
Claim 6
Dependent Claim 26 words
A method according to claim 1 wherein the water-soluble bivalent metal salt and water-soluble polymer solution is introduced to the waterflood zone through a slug method.

References Cited (Backward Citations)

US3378070A Cited
US3370649A Cited
US3400761A Cited
US3396790A Cited
US3502149A Cited
US3406754A Cited
US3580337A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1975-04-25 1975-10-25 1976-04-25 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1979-04-25 1979-10-25 1980-04-25 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1983-04-25 1983-10-25 1984-04-25 $7700.00 Window Closed / Lapsed

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