Patent US3919134A successfully refreshed from Google Patents.
US3919134A
Expired / Lapsed
US
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Thermal insulation of mineral fiber matrix bound with phenolic resin
Assignee: Monsanto Co
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Filing: 1974-04-10
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Granted: 1975-11-11
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Expires: 1994-04-10
Abstract
Abstract Thermal insulation with improved thermal stability and resistance to punking. The insulation comprises a matrix of mineral fiber bound with a phenolic resin. The phenolic resin is applied to the matrix as an aqueous solution or dispersion of a resole modified with dicyandiamide or melamine, and containing an alkoxymethylaminotriazine and a proteinaceous compound.
Inventors
- 👤 Harold P Higginbottom
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-06 17:03
CPC Classifications
C; C08; C08L; C08L61/00; C08L61/34; F; F16; F16L; F16L59/00; F16L59/02; C08J; C08J5/00; C08J5/24; C08J5/241; C08J5/244; C08J5/249; C08J2361/00; C08J2361/34; Y; Y10; Y10T; Y10T442/00; Y10T442/20; Y10T442/2926; Y10T442/2959; Y10T442/2992
Claims Analysis
Total Claims: 28
Claim 1
Independent Claim
156 words
A THERMAL INSULATION COMPRISING MINERAL FIBERS BONDED WITH A PHENOLIC RESIN SYSTEM WHICH COMPRISES: A. A MODIFIED RESOLE COMPRISING A PHENOL-FORMALDEHYDE CONDENSATE AND A DICYANDIAMIDE OR A MELAMINEFORMALDEHYDE CONDENSATE WHEREIN THE MOLE RATIO OF PHENOL TO DICYANDIAMIDE OR MELAMINE IS IN THE RANGE OF 1:0.2 TO 1:1.2, WHEREIN THERE ARE BETWEEN 1.5 AND 2.5 MOLES OF FORMALDEHYDE PER MOLE OF PHENOL, AND, ADDITIONALLY, BETWEEN 0.9 AND 2.0 MOLES FORMALDEHYDE PER MOLE OF DICYANDIAMIDE OR MELAMINE, B. AN ETHERIFIED METHYLOLAMINOTRIAZINE WHEREIN THE DEGREE OF METHYLOLATION IS AT LEAST 1.5, THE DEGREE OF ETHERIFICATION IS AT LEAST 0.5 AND THE ETHERIFICATION AGENT IS AN ALCOHOL CONTAINING FROM 1 TO 4 CARBON ATOMS, AND C. A PROTEINACEOUS COMPOUND SOLUBLE IN AQUEOUS MEDIA AT A PH OF 7 TO 10, WHEREIN THE WEIGHT RATIO OF THE MODIFIED RESOLE TO THE ETHEERIFIED METHYLOLAMINOTRIAZINE IS IN THE RANGE OF 10:1 TO 1:2 AND WHEREIN THE WEIGHT RATIO OF THE PROTEINNACEOUS COMPOUND TO
Claim 2
Dependent Claim
156 words
A THERMAL INSULATION COMPRISING MINERAL FIBERS BONDED WITH A PHENOLIC RESIN SYSTEM WHICH COMPRISES: A. A MODIFIED RESOLE COMPRISING A PHENOL-FORMALDEHYDE CONDENSATE AND A DICYANDIAMIDE OR A MELAMINEFORMALDEHYDE CONDENSATE WHEREIN THE MOLE RATIO OF PHENOL TO DICYANDIAMIDE OR MELAMINE IS IN THE RANGE OF 1:0.2 TO 1:1.2, WHEREIN THERE ARE BETWEEN 1.5 AND 2.5 MOLES OF FORMALDEHYDE PER MOLE OF PHENOL, AND, ADDITIONALLY, BETWEEN 0.9 AND 2.0 MOLES FORMALDEHYDE PER MOLE OF DICYANDIAMIDE OR MELAMINE, B. AN ETHERIFIED METHYLOLAMINOTRIAZINE WHEREIN THE DEGREE OF METHYLOLATION IS AT LEAST 1.5, THE DEGREE OF ETHERIFICATION IS AT LEAST 0.5 AND THE ETHERIFICATION AGENT IS AN ALCOHOL CONTAINING FROM 1 TO 4 CARBON ATOMS, AND C. A PROTEINACEOUS COMPOUND SOLUBLE IN AQUEOUS MEDIA AT A PH OF 7 TO 10, WHEREIN THE WEIGHT RATIO OF THE MODIFIED RESOLE TO THE ETHEERIFIED METHYLOLAMINOTRIAZINE IS IN THE RANGE OF 10:1 TO 1:2 AND WHEREIN THE WEIGHT RATIO OF THE PROTEINNACEOUS COMPOUND TO
Claim 3
Dependent Claim
21 words
a methoxymethylmelamine wherein the degree of methylolation is at least 1.5 and the degree of methylation is at least 0.5, and
Claim 4
Dependent Claim
21 words
a methoxymethylmelamine wherein the degree of methylolation is at least 1.5 and the degree of methylation is at least 0.5, and
Claim 5
Dependent Claim
20 words
THe thermal insulation of claim 1 wherein the methylolaminotriazine is selected from the group consisting of methylolmelamines, methylolguanamines and methylolbenzoguanamines.
Claim 6
Dependent Claim
35 words
an etherified methylolaminotriazine wherein the degree of methylolation is at least 1.5; the degree of etherification is at least 0.5, and the etherification agent is an alcohol containing from 1 to 4 carbon atoms, and
Claim 7
Dependent Claim
35 words
an etherified methylolaminotriazine wherein the degree of methylolation is at least 1.5; the degree of etherification is at least 0.5, and the etherification agent is an alcohol containing from 1 to 4 carbon atoms, and
Claim 8
Dependent Claim
17 words
The thermal insulation of claim 1 wherein methylolaminotriazine is a methylolmelamine and the alcohol is methyl alcohol.
Claim 9
Dependent Claim
81 words
a proteinaceous compound selected from the group consisting of casein and soya protein, wherein the weight ratio of the modified resole to the methoxymethylmelamine is in the range of 10:1 to 1:2 and wherein the weight ratio of the proteinaceous compound to the modified resole and the methoxymethylmelamine is in the range of 1:1000 to 1:20; B. drying the matrix of mineral fiber; and C. heating the matrix at a temperature in the range of 400*-500*F. to cure the phenolic resin.
Claim 10
Dependent Claim
81 words
a proteinaceous compound selected from the group consisting of casein and soya protein, wherein the weight ratio of the modified resole to the methoxymethylmelamine is in the range of 10:1 to 1:2 and wherein the weight ratio of the proteinaceous compound to the modified resole and the methoxymethylmelamine is in the range of 1:1000 to 1:20; B. drying the matrix of mineral fiber; and C. heating the matrix at a temperature in the range of 400*-500*F. to cure the phenolic resin.
Claim 11
Dependent Claim
84 words
a proteinaceous compound soluble in aqueous media at a pH of 7 to 10, wherein the weight ratio of the modified resole to the etherified methylolaminotriazine is in the range of 10:1 to 1:2 and wherein the weight ratio of the proteinaceous compound to the modified resole and the etherified methylolaminotriazine is in the range of 1:1000 to 1:20; B. drying the matrix of mineral fiber; and C. heating the matrix at a temperature in the range of 200*-500*F. to cure the phenolic resin.
Claim 12
Dependent Claim
84 words
a proteinaceous compound soluble in aqueous media at a pH of 7 to 10, wherein the weight ratio of the modified resole to the etherified methylolaminotriazine is in the range of 10:1 to 1:2 and wherein the weight ratio of the proteinaceous compound to the modified resole and the etherified methylolaminotriazine is in the range of 1:1000 to 1:20; B. drying the matrix of mineral fiber; and C. heating the matrix at a temperature in the range of 200*-500*F. to cure the phenolic resin.
Claim 13
Dependent Claim
12 words
The thermal insulation of claim 1 wherein the proteinaceous compound is casein.
Claim 14
Dependent Claim
13 words
The thermal insulation of claim 1 wherein the proteinaceous compound is soya protein.
Claim 15
Dependent Claim
22 words
The thermal insulation of claim 1 wherein the phenolic resin system comprises additionally up to 0.7 mole urea per mole of phenol.
Claim 16
Dependent Claim
12 words
The thermal insulation of claim 1 wherein the mineral fibers are glass.
Claim 17
Dependent Claim
148 words
A thermal insulation comprising mineral fibers bonded with a phenolic resin system which comprises: A. a modified resole comprising a phenol-formaldehyde condensate and a dicyandiamide-formaldehyde condensate wherein the mole ratio of phenol to dicyandiamide is in the range of 1:0.2 to 1: 1.2, wherein there are between 1.5 and 2.5 moles of formaldehyde per mole of phenol, and, additionally, between 0.9 and 2.0 moles formaldehyde per mole of dicyandiamide, B. a methoxymethylmelamine wherein the degree of methylolation is at least 1.5 and the degree of methylation is at least 0.5, and C. a proteinaceous compound selected from the group consisting of casein and soya protein; wherein the weight ratio of the modified resole to the methoxymethylmelamine is in the range of 10:1 to 1:2 and wherein the weight ratio of the proteinaceous compound to the modified resole and the methoxymethylmelamine is in the range of 1:1000 to 1:20.
Claim 18
Dependent Claim
148 words
A thermal insulation comprising mineral fibers bonded with a phenolic resin system which comprises: A. a modified resole comprising a phenol-formaldehyde condensate and a dicyandiamide-formaldehyde condensate wherein the mole ratio of phenol to dicyandiamide is in the range of 1:0.2 to 1: 1.2, wherein there are between 1.5 and 2.5 moles of formaldehyde per mole of phenol, and, additionally, between 0.9 and 2.0 moles formaldehyde per mole of dicyandiamide, B. a methoxymethylmelamine wherein the degree of methylolation is at least 1.5 and the degree of methylation is at least 0.5, and C. a proteinaceous compound selected from the group consisting of casein and soya protein; wherein the weight ratio of the modified resole to the methoxymethylmelamine is in the range of 10:1 to 1:2 and wherein the weight ratio of the proteinaceous compound to the modified resole and the methoxymethylmelamine is in the range of 1:1000 to 1:20.
Claim 19
Dependent Claim
22 words
A process for preparing thermal insulation which comprises: A. applying to a matrix of mineral fiber an aqueous phenolic resin system comprising:
Claim 20
Dependent Claim
22 words
A process for preparing thermal insulation which comprises: A. applying to a matrix of mineral fiber an aqueous phenolic resin system comprising:
Claim 21
Dependent Claim
19 words
The process of claim 9 wherein the methylolaminotriazine is selected from the group consisting of methylolmelamines, methylolguanamines and methylolbenzoguanamines.
Claim 22
Dependent Claim
16 words
The process of claim 9 wherein methylolaminotriazine is a methylolmelamine and the alcohol is methyl alcohol.
Claim 23
Dependent Claim
11 words
The process of claim 9 wherein the proteinaceous compound is casein.
Claim 24
Dependent Claim
12 words
The process of claim 9 wherein the proteinaceous compound is soya protein.
Claim 25
Dependent Claim
22 words
The process of claim 9 wherein the aqueous phenolic resin system additionally comprises up to 0.7 mole urea per mole of phenol.
Claim 26
Dependent Claim
11 words
The process of claim 9 wherein the mineral fiber is glass.
Claim 27
Dependent Claim
21 words
A process for preparing thermal insulation which comprises: A. applying to a matrix of mineral fiber an aqueous phenolic resin comprising:
Claim 28
Dependent Claim
21 words
A process for preparing thermal insulation which comprises: A. applying to a matrix of mineral fiber an aqueous phenolic resin comprising:
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1978-11-10 | 1979-05-12 | 1979-11-11 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1982-11-10 | 1983-05-12 | 1983-11-11 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1986-11-10 | 1987-05-12 | 1987-11-11 | $7700.00 | Window Closed / Lapsed |