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US3917885A Expired / Lapsed US ⏱️ 0.0 years remaining

Electroless gold plating process

Assignee: Engelhard Minerals and Chemicals Corp
•
Filing: 1974-04-26
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Granted: 1975-11-04
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Expires: 1994-04-26
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Abstract

Abstract An Electroless plating bath, and processes for the autocatalytic deposition of Group IB metals upon various substrates using such a bath, are disclosed. The electroless plating bath disclosed includes an aqueous solution of an imide complex of the Group IB metal to be plated, an alkali metal cyanide, and a reducing agent, and is maintained at a pH of from about 11 to 14 by the addition of alkali metal hydroxides. In a preferred embodiment, an electroless gold plating bath is disclosed, including an aqueous solution of an alkali metal gold imide complex. Methods for plating various substrates from such electroless plating baths are also disclosed. Where non-metallic substrates are to be plated, the surfaces are rendered catalytically active prior to immersion in the electroless plating baths, and where metallic substrates are plated, they are preferably pre-coated with a thin plate by immersion in an aqueous plating bath including a soluble gold salt, an ammonium buffering agent, and an organic chelating agent, prior to immersion in the electroless plating baths of the present invention.

Inventors

  • 👤 Kenneth D Baker

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 20:39
CPC Classifications
C; C23; C23C; C23C18/00; C23C18/16; C23C18/31; C23C18/38; C23C18/40; C23C18/42; C23C18/44

Claims Analysis

Total Claims: 23
Claim 1
Independent Claim 132 words
AN ELECTROLESS PLATING BATH FOR AUTOCATALYTIC DEPOSITION OF GROUP 1B METALS UPON A SUBSTRATE COMPRISING AN AQUEOUS SOLUTION OF AN IMIDE COMPLEX OF THE GROUP 1B METAL TO BE PLATED, SAID IMIDE COMPLEX OF THE GROUP 1B META TO BE PLATED INCLUDING AN IMIDE SELECTED FROM THE GROUP CONSISTING OF IMIDES HAVING THE FORMULA RNHCO, AND CYCLIC IMIDES HAVING THE FORMULA RCONHCO, WHEREIN R IS SELECTED FROM THE GROUP CONSISTING OF ALKYLENE, SUBSTITUTED ALKYLENE, ARYLENE, AND SUBSTITUTED ARYLENE, AN ALKALI METAL CYANIDE IN AN AMOUNT RAGING FROM ABOUT 2 TO 20 GRAMS PER LITER, SUFFICIENT TO STABILIZE SAID BATH, AND A REDUCING AGENT SELECTED FROM THE GROUP CONSISTING OF WATER SOLUBLE ALKALI METAL BOROHYDRIDES, WATER SOLUBLE AMINE BORANES AND FORMALDEHYDE, SAID BATH MAINTANED AT A PH OF FROM ABOUT 11 TO 14.
Claim 2
Dependent Claim 132 words
AN ELECTROLESS PLATING BATH FOR AUTOCATALYTIC DEPOSITION OF GROUP 1B METALS UPON A SUBSTRATE COMPRISING AN AQUEOUS SOLUTION OF AN IMIDE COMPLEX OF THE GROUP 1B METAL TO BE PLATED, SAID IMIDE COMPLEX OF THE GROUP 1B META TO BE PLATED INCLUDING AN IMIDE SELECTED FROM THE GROUP CONSISTING OF IMIDES HAVING THE FORMULA RNHCO, AND CYCLIC IMIDES HAVING THE FORMULA RCONHCO, WHEREIN R IS SELECTED FROM THE GROUP CONSISTING OF ALKYLENE, SUBSTITUTED ALKYLENE, ARYLENE, AND SUBSTITUTED ARYLENE, AN ALKALI METAL CYANIDE IN AN AMOUNT RAGING FROM ABOUT 2 TO 20 GRAMS PER LITER, SUFFICIENT TO STABILIZE SAID BATH, AND A REDUCING AGENT SELECTED FROM THE GROUP CONSISTING OF WATER SOLUBLE ALKALI METAL BOROHYDRIDES, WATER SOLUBLE AMINE BORANES AND FORMALDEHYDE, SAID BATH MAINTANED AT A PH OF FROM ABOUT 11 TO 14.
Claim 3
Dependent Claim 26 words
The electroless plating bath of claim 1, wherein said Group IB metal to be plated is selected from the group consisting of gold, silver and copper.
Claim 4
Dependent Claim 29 words
The electroless plating bath of claim 1, wherein said bath is maintained at a pH of from about 11 to 14 by the addition of alkali metal hydroxide thereto.
Claim 5
Dependent Claim 29 words
The electroless plating bath of claim 3, including an alkali metal buffering salt selected from the group consisting of alkali metal phosphates, citrates, tartrates, borates, metaborates, and mixtures thereof.
Claim 6
Dependent Claim 20 words
The electroless plating bath of claim 1, wherein said imide is selected from the group consisting of succinimide and phthalimide.
Claim 7
Dependent Claim 112 words
An electroless gold plating bath for the autocatalytic deposition of gold upon a substrate, comprising an aqueous solution of an alkali metal gold imide complex, said alkali metal gold imide complex including an imide selected from the group consisting of imides having the formula RNHCO, and cyclic imides having the formula RCONHCO, wherein R is selected from the group consisting of alkylene, substituted alkylene, arylene, and substituted arylene, an alkali metal cyanide in an amount sufficient to stabilize said bath, a reducing agent selected from the group consisting of water soluble alkali metal borohydrides, water soluble amine boranes, and formaldehyde, said bath maintained at a pH of from about 11 to 14.
Claim 8
Dependent Claim 112 words
An electroless gold plating bath for the autocatalytic deposition of gold upon a substrate, comprising an aqueous solution of an alkali metal gold imide complex, said alkali metal gold imide complex including an imide selected from the group consisting of imides having the formula RNHCO, and cyclic imides having the formula RCONHCO, wherein R is selected from the group consisting of alkylene, substituted alkylene, arylene, and substituted arylene, an alkali metal cyanide in an amount sufficient to stabilize said bath, a reducing agent selected from the group consisting of water soluble alkali metal borohydrides, water soluble amine boranes, and formaldehyde, said bath maintained at a pH of from about 11 to 14.
Claim 9
Dependent Claim 12 words
The electroless plating bath of claim 6, wherein said imide comprises sulfobenzoicimide.
Claim 10
Dependent Claim 22 words
The electroless gold plating bath of claim 6, wherein said cyclic imide is selected from the group consisting of succinimide and phthalimide.
Claim 11
Dependent Claim 24 words
The electroless gold plating bath of claim 6 including an organic chelating agent capable of forming a chelate with the metal of said substrate.
Claim 12
Dependent Claim 31 words
The electroless gold plating bath of claim 6, wherein said bath is maintained at a pH of from about 11 to 14 by the addition of an alkali metal hydroxide thereto.
Claim 13
Dependent Claim 31 words
The electroless gold platng bath of claim 10, including an alkali metal buffering salt selected from the group consisting of an alkali metal phosphates, citrates, tartrates, borates, metaborates, and mixtures thereof.
Claim 14
Dependent Claim 25 words
The electroless gold plating bath of claim 6, wherein said reducing agent is selected from the group consisting of dimethylamine borane, potassium borohydride, and formaldehyde.
Claim 15
Independent Claim 13 words
A method of plating a metallic substrate with a Group IB metal comprising:
Claim 16
Independent Claim 13 words
A method of plating a metallic substrate with a Group IB metal comprising:
Claim 17
Dependent Claim 21 words
The method of claim 13, wherein said layer of gold plated in step (a) is from about 2 to 10 microinches.
Claim 18
Dependent Claim 29 words
The method of claim 13, wherein said electroless plating bath is maintained at a pH of from about 11 to 14 by the addition of alkali metal hydroxide thereto.
Claim 19
Dependent Claim 16 words
The method of claim 15, wherein said electroless plating bath includes an alkali metal buffering salt.
Claim 20
Dependent Claim 26 words
The method of claim 13, wherein said electroless plating bath includes an organic chelating agent capable of forming a chelate with the metal of said substrate.
Claim 21
Dependent Claim 10 words
The method of claim 1, wherein said imide comprises sulfobenzoicimide.
Claim 22
Dependent Claim 20 words
The method of claim 13, wherein said imide comprises an imide selected from the group consisting of succinimide and phthalimide.
Claim 23
Dependent Claim 12 words
The metal of claim 13, wherein said Group IB metal comprises gold.

References Cited (Backward Citations)

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US3515571A Cited
US3294578A Cited
US3589916A Cited
US3506462A Cited
US3482974A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-11-03 1979-05-05 1979-11-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-11-03 1983-05-05 1983-11-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-11-03 1987-05-05 1987-11-04 $7700.00 Window Closed / Lapsed

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