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US3917551A Expired / Lapsed US ⏱️ 0.0 years remaining

Hot melt adhesive

Assignee: Phillips Petroleum Co
•
Filing: 1974-06-07
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Granted: 1975-11-04
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Expires: 1994-06-07
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Abstract

Abstract A hot melt adhesive is disclosed consisting essentially of rubber, tackifier and liquid polybutadiene as the extenderplasticizer.

Inventors

  • 👤 Lawrence D Jurrens
  • 👤 Leo L Gingerich

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 18:36
CPC Classifications
C; C09; C09J; C09J115/00; C08; C08L; C08L2666/00; C08L2666/02; C08L2666/04; C08L2666/08

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 111 words
A HOT MELT ADHESIVE COMPOSITION CONSISTING ESSENTIALLY OF A HYDROGENATED COPOLYMER OF A SUBSTITUTED OR UNSUBSTITUTED ALKADIENE HAVING 4-12 CARBON ATOMS AND A SUBSTITUTED OR UNSUBSTITUTED VINYLSUBSTITUTED AROMATIC MONOMER HAVING 8-16 CARBON ATOMS PER MOLECULE WHEREIN SUBSTANTIALLY ALL OF THE OLEFIN UNSATURATION IS HYDROGENATED, LEAVING THE AROMATIC UNSATURATION, A TACKIFIER AND ABOUT 10 TO ABOUT 30 PARTS BY WEIGHT PER ABOUT 40 TO ABOUT 70 PARTS BY WEIGHT OF THE COPOLYMER OF A LIQUID POLYALKADIENE HAVING ALKADINE UNITS OF 4-12 CARBON ATOMS PER MOLECULE, HAVING A WEIGHT AVERAGE MOLECULAR WEIGHT IN THE RANGE OF ABOUT 500 TO ABOUT 10,000 AND BEING SUBSTANTIALLY FREE OF OTHER FUCTIONAL GROUPS THAN C=C DOUBLE BONDS.
Claim 2
Dependent Claim 111 words
A HOT MELT ADHESIVE COMPOSITION CONSISTING ESSENTIALLY OF A HYDROGENATED COPOLYMER OF A SUBSTITUTED OR UNSUBSTITUTED ALKADIENE HAVING 4-12 CARBON ATOMS AND A SUBSTITUTED OR UNSUBSTITUTED VINYLSUBSTITUTED AROMATIC MONOMER HAVING 8-16 CARBON ATOMS PER MOLECULE WHEREIN SUBSTANTIALLY ALL OF THE OLEFIN UNSATURATION IS HYDROGENATED, LEAVING THE AROMATIC UNSATURATION, A TACKIFIER AND ABOUT 10 TO ABOUT 30 PARTS BY WEIGHT PER ABOUT 40 TO ABOUT 70 PARTS BY WEIGHT OF THE COPOLYMER OF A LIQUID POLYALKADIENE HAVING ALKADINE UNITS OF 4-12 CARBON ATOMS PER MOLECULE, HAVING A WEIGHT AVERAGE MOLECULAR WEIGHT IN THE RANGE OF ABOUT 500 TO ABOUT 10,000 AND BEING SUBSTANTIALLY FREE OF OTHER FUCTIONAL GROUPS THAN C=C DOUBLE BONDS.
Claim 3
Dependent Claim 23 words
A composition in accordance with claim 1 wherein the polyalkadiene has a weight average molecular weight of about 2, 000 to about 8,000.
Claim 4
Dependent Claim 34 words
A composition in accordance with claim 1 wherein the alkadiene monomer of the copolymer is selected from the group consisting of butadiene and isoprene and the monovinyl-substituted aromatic monomer of the copolymer is styrene.
Claim 5
Dependent Claim 39 words
A composition in accordance with claim 3 wherein the polymer is a hydrogenated butadiene-styrene copolymer having a butadiene content of about 30 to about 44 weight percent and a styrene content of about 70 to about 56 weight percent.
Claim 6
Dependent Claim 12 words
A composition in accordance with claim 1 wherein the polyalkadiene is polybutadiene.
Claim 7
Dependent Claim 29 words
A composition in accordance with claim 5 wherein the polybutadiene has a weight average molecular weight of about 5, 000 and a viscosity of about 75-125 poise at 77*F.
Claim 8
Dependent Claim 50 words
A hot melt adhesive composition according to claim 1 wherein said tackifier is selected from the group consisting of pentaerythritol ester of hydrogenated rosin, thermpolastic olefin resin tackifiers, thermoplastic hydrocarbon resin tackifiers, glycerol ester of hydrogenated rosin, wood resin tackfiers, resin ester tackifiers, polyterpene tackifiers and thermoplastic olefin resin tackifiers.
Claim 9
Dependent Claim 43 words
A composition in accordance with claim 7 comprising about 40 to about 70 parts by weight of said copolymer, about 50 to about 90 parts by weight of said tackifier, and about 10 to about 30 parts by weight of said liquid polyalkadiene.
Claim 10
Dependent Claim 31 words
A composition in accordance with claim 8 comprising about 1 to about 10 parts by weight of at least one additive selected from the group consisting of stabilizers, pigments, and antioxidants.

References Cited (Backward Citations)

US3035953A Cited
US3239478A Cited
US3554911A Cited
US3630980A Cited
US3741931A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-11-03 1979-05-05 1979-11-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-11-03 1983-05-05 1983-11-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-11-03 1987-05-05 1987-11-04 $7700.00 Window Closed / Lapsed

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