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US3914399A Expired / Lapsed US ⏱️ 0.0 years remaining

Elemental sulfur produced by wet oxidation of hydrogen sulfide

Assignee: Marathon Oil Co
•
Filing: 1973-12-26
•
Granted: 1975-10-21
•
Expires: 1993-12-26
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Abstract

Abstract H2S and air are bubbled through a mixture of alcohol, e.g., methanol/amine e.g., isopropylamine/oxygen-carrier catechol to produce elemental sulfur which can settle to the bottom of the liquid phase.

Inventors

  • 👤 Phillip M Beazley

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 03:10
CPC Classifications
C; C01; C01B; C01B17/00; C01B17/02; C01B17/04; C01B17/05; B; B01; B01D; B01D53/00; B01D53/34; B01D53/46; B01D53/48; B01D53/52

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 55 words
A PROCESS FOR CONVERTING HYDROGEN SULFIDE TO ELEMENTAL SULFUR COMPRISING FORMING A MIXTURE OF CONSISTING ESSENTIALLY OF ALCOHOL, ALIPHATIC AMINE, AND CATECHOL CONTACTING SAID MIXTURE WITH H2S AND WITH OXYGEN-CONTAINING GAS AND RECOVERING THE MONOCLINIC ELEMENTAL SULFUR THUS FORMED WHEREIN FROM ABOUT 1 TO ABOUT 100 MOLES OF AMINE ARE PRESENT PER MOLE OF CATECHOL.
Claim 2
Dependent Claim 55 words
A PROCESS FOR CONVERTING HYDROGEN SULFIDE TO ELEMENTAL SULFUR COMPRISING FORMING A MIXTURE OF CONSISTING ESSENTIALLY OF ALCOHOL, ALIPHATIC AMINE, AND CATECHOL CONTACTING SAID MIXTURE WITH H2S AND WITH OXYGEN-CONTAINING GAS AND RECOVERING THE MONOCLINIC ELEMENTAL SULFUR THUS FORMED WHEREIN FROM ABOUT 1 TO ABOUT 100 MOLES OF AMINE ARE PRESENT PER MOLE OF CATECHOL.
Claim 3
Dependent Claim 21 words
A process according to claim 1 wherein said alcohol is an alkanol having from about 1 to about 3 carbon atoms.
Claim 4
Dependent Claim 28 words
A process according to claim 1 wherein said aliphatic amine is selected from the group consisting of aliphatic amines having from about 1 to about 30 carbon atoms.
Claim 5
Dependent Claim 27 words
A process according to claim 1 wherein there are present either more or the same number of moles of said aliphatic amine than moles of said oxygen-carrier.
Claim 6
Dependent Claim 26 words
A process according to claim 1 wherein the moles of oxygen in the oxygen-containing gas per mole of hydrogen sulfide is preferably from 0.8 to 1.2.
Claim 7
Dependent Claim 36 words
A process according to claim 1 wherein the hydrogen sulfide is added at a rate of preferably from 0.1 to about 1 liter of hydrogen sulfide per liter of oxygen carrier and alcohol solution per minute.

References Cited (Backward Citations)

US2472473A Cited
US2445468A Cited
US2772146A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-10-20 1979-04-21 1979-10-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-10-20 1983-04-21 1983-10-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-10-20 1987-04-21 1987-10-21 $7700.00 Window Closed / Lapsed

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