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US3914358A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of improving the finish of the bores of a reverse osmosis sand module

Assignee: Graftech Technology LLC
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Filing: 1973-12-10
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Granted: 1975-10-21
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Expires: 1993-12-10
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Abstract

Abstract A method of making a liquid purification module consists of (1) applying a finishing composition, comprising fine filler particles coated with a resinous material, to the interior circular cular bore walls of a membrane support module made of bonded, resin-coated coarse filler particles, to smooth irregularities in the bore walls, and then (2) drying the finishing composition to harden the finishing composition resinous material and bond it to the bore walls prior to applying semipermeable membranes inthe module bores.

Inventors

  • 👤 George D Dixon
  • 👤 Hugh A Nelson

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 01:47
CPC Classifications
B; B01; B01D; B01D61/00; B01D61/02; B01D61/10; B01D63/00; B01D63/06; B01D63/061; B01D63/062; B01D63/063; B01D69/00; B01D69/10; B01D69/105; B01D2313/00; B01D2313/14; B01D2313/146

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 172 words
A METHOD OF MAKING A LIQUID PURIFICATION MODULE COMPRISING A SUPPORTED SEMIPERMEABLE MEMBRANCE COMPRISING THE STEPS OF: A. PROVIDING AN OPEN SORE SUPPORT MODULE MADE OF BONDED, RESIN-COATED FILLER PARTICALES HAVING A GRANULAR STRUCTURE AND AN AVERAGE PARTICLE SIZE BETWEEN ABOUT 40 AND 500 MICRONS, THE RESIN COATED CONSTITUTING ABOUT 1 TO 18 PRECENT OF THE COATED FILLER PARTICLE WEIGHT, THE MODULE HAVING AT LEAST ONE FEED BORE EXTENDING FROM END TO END THERETHROUGH: B. APPLYING A THIN COATING OF A FINISHING COMPOSITION TO THE ENTIRE SURFACE OF THE INTERIOR FEED BORE WALLS, SAID FINISHING COMPOSITION COMPRISING FILLER PARTICALES COATED WITH A RESINOUS MATERIAL AND HAVING A GRANULAR STRUCTURE AND AN AVERAGE PARTICAL SIZE BETWEEN ABOUT 0.5 TO 30 MICRONS, THE RESINOUS MATERIAL CONSTITUTING ABOUT 0.5 TO 10 PERCENT OF THE COATED FILLER PARTICLE WEIGHT, C. DRYING THE FINISHING COMPOSITION COATING TO FROM A POROUS COATED BONDED TO THE BORE WALLS, AND FINALLY D. APPLYING A POLYMERIC SEMIPERMEABLE MEMBRANE TO THE INTERIOR FINISHED BORE WALLS TO PROVIDE A POROUS LIQUID PURIFICATION MODULE.
Claim 2
Independent Claim 172 words
A METHOD OF MAKING A LIQUID PURIFICATION MODULE COMPRISING A SUPPORTED SEMIPERMEABLE MEMBRANCE COMPRISING THE STEPS OF: A. PROVIDING AN OPEN SORE SUPPORT MODULE MADE OF BONDED, RESIN-COATED FILLER PARTICALES HAVING A GRANULAR STRUCTURE AND AN AVERAGE PARTICLE SIZE BETWEEN ABOUT 40 AND 500 MICRONS, THE RESIN COATED CONSTITUTING ABOUT 1 TO 18 PRECENT OF THE COATED FILLER PARTICLE WEIGHT, THE MODULE HAVING AT LEAST ONE FEED BORE EXTENDING FROM END TO END THERETHROUGH: B. APPLYING A THIN COATING OF A FINISHING COMPOSITION TO THE ENTIRE SURFACE OF THE INTERIOR FEED BORE WALLS, SAID FINISHING COMPOSITION COMPRISING FILLER PARTICALES COATED WITH A RESINOUS MATERIAL AND HAVING A GRANULAR STRUCTURE AND AN AVERAGE PARTICAL SIZE BETWEEN ABOUT 0.5 TO 30 MICRONS, THE RESINOUS MATERIAL CONSTITUTING ABOUT 0.5 TO 10 PERCENT OF THE COATED FILLER PARTICLE WEIGHT, C. DRYING THE FINISHING COMPOSITION COATING TO FROM A POROUS COATED BONDED TO THE BORE WALLS, AND FINALLY D. APPLYING A POLYMERIC SEMIPERMEABLE MEMBRANE TO THE INTERIOR FINISHED BORE WALLS TO PROVIDE A POROUS LIQUID PURIFICATION MODULE.
Claim 3
Independent Claim 256 words
A method of making a liquid purification module comprising a supported semipermeable membrane comprising the steps of: A. providng an open pore support module made of bonded, resin-coated filler particles having a granular structure and an average particle size between about 40 and 500 microns, the resin coating constituting about 1 to 18 percent of the coated filler particle weight, the module having a plurality of spaced-apart feed bores extending from end to end therethrough, said feed bores having walls with protrusions and cavities; B. applying a thin coating of a fluid finishing composition having a specific gravity between about 20* - 60* Baume to the entire surface of the interior feed bore walls, to fill the wall cavities and smooth the wall protrusions, said finishing composition comprising filler particles coated with a resinous material and having a granular structure and an average particle size between about 0.5 and 30 microns, the resinous material comprising about 0.5 to 10 percent of the coated filler particle weight, said coated filler particles being mixed with an evaporable liquid; and then C. drying the finishing composition coating to evaporate the liquid, form a liquid permeable coating, harden the finishing composition resinous material and bond the finishing composition resinous material to the resin-coated filler particles of the open pore support module bore walls; and then D. removing excess finishing composition to provide smooth open pore feed bore walls; and then E. applying a polymeric semipermeable membrane to the interior finished feed bore walls to provide a porous liquid purification module.
Claim 4
Independent Claim 256 words
A method of making a liquid purification module comprising a supported semipermeable membrane comprising the steps of: A. providng an open pore support module made of bonded, resin-coated filler particles having a granular structure and an average particle size between about 40 and 500 microns, the resin coating constituting about 1 to 18 percent of the coated filler particle weight, the module having a plurality of spaced-apart feed bores extending from end to end therethrough, said feed bores having walls with protrusions and cavities; B. applying a thin coating of a fluid finishing composition having a specific gravity between about 20* - 60* Baume to the entire surface of the interior feed bore walls, to fill the wall cavities and smooth the wall protrusions, said finishing composition comprising filler particles coated with a resinous material and having a granular structure and an average particle size between about 0.5 and 30 microns, the resinous material comprising about 0.5 to 10 percent of the coated filler particle weight, said coated filler particles being mixed with an evaporable liquid; and then C. drying the finishing composition coating to evaporate the liquid, form a liquid permeable coating, harden the finishing composition resinous material and bond the finishing composition resinous material to the resin-coated filler particles of the open pore support module bore walls; and then D. removing excess finishing composition to provide smooth open pore feed bore walls; and then E. applying a polymeric semipermeable membrane to the interior finished feed bore walls to provide a porous liquid purification module.
Claim 5
Dependent Claim 28 words
The method of claim 2 wherein the fluid finishing composition is placed into each of the bores within the module and forced through thE bores in step (B).
Claim 6
Dependent Claim 18 words
The method of claim 2 wherein the fluid finishing composition is poured down the bore in step (B).
Claim 7
Dependent Claim 17 words
The method of claim 2 wherein the finishing composition is heated between about 140*-275*C in step (C).
Claim 8
Dependent Claim 32 words
The method of claim 5, wherein after step (B) and before heating in step (C), the evaporable liquid is partly removed by contacting the finishing composition surface with a stream of gas.
Claim 9
Dependent Claim 67 words
The method of claim 5 wherein the resinous material used in the finishing composition is selected from the group consisting of phenolic resins, epoxy resins, polyester resins, polystyrene resins, poly-imide resins, polyamide-imide resins, polysulphone resins, polyacrylic resins and natural drying oils and the evaporable liquid used in the finishing composition is selected from the group consisting of water, alcohol, ketone, aromatic hydrocarbons and liquid N, N-dialkylcarboxylamide compounds.
Claim 10
Dependent Claim 36 words
The method of claim 7 wherein the finishing composition resinous material is a resin and also contains a small effective amount of polymerization catalyst and is heated in step (C) for about 5 to 90 minutes.
Claim 11
Dependent Claim 47 words
The method of claim 7 wherein the applied membrane is about 0.08-6 mils thick, the finishing composition has a specific gravity of between about 20*-50* Baume and the resin coating the filler particles of the finishing composition comprises about 0.5-5 weight of the coated filler particle weight.
Claim 12
Dependent Claim 85 words
The method of claim 7 wherein the open pore support module and finishing composition is made of sand particles coated with a resin selected from the group consisting of epoxy and phenolic resin, the membrane is applied to the feed bore walls by casting a resin solution in - place to form a membrane of about 0.08-15 mils thick, and the resin of the membrane casting solution is selected from the group consisting of cellulose esters, cellulose ethers, polyamides, polyamide-imides, polyphenylesters, polypyrrones, polyacrylics, and polysulfonamides.
Claim 13
Dependent Claim 27 words
The method of claim 10 wherein the membrane is cellulose acetate and as a last step the membrane is leached by contacting it with a leaching solution.

References Cited (Backward Citations)

US3022187A Cited
US3341024A Cited
US3457170A Cited
US3544358A Cited
US3505785A Cited
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US3598241A Cited
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US3773181A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-10-20 1979-04-21 1979-10-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-10-20 1983-04-21 1983-10-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-10-20 1987-04-21 1987-10-21 $7700.00 Window Closed / Lapsed

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