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US3912701A Expired / Lapsed US ⏱️ 0.0 years remaining

Olefin polymerization process

Assignee: Dart Industries Inc
•
Filing: 1974-03-25
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Granted: 1975-10-14
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Expires: 1994-03-25
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Abstract

Abstract An improved process for the polymerization of alpha-olefin employing liquid diluent and a titanium chloride catalyst activated with an organoaluminum compound, wherein by means of separately introducing the catalyst and the organoaluminum activator at specific locations in the process cycle, the use of olefin feed containing catalyst contaminants is possible without sacrifice in catalyst efficiency.

Inventors

  • 👤 Jr George Harvey Dunn

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 09:35
CPC Classifications
C; C08; C08F; C08F10/00

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 183 words
IN A CONTINUOUS PROCESS FOR THE POLYMERIZATION OF AN AOLEFIN FEED SUBSTANTIALLY FREE OF CATALYST CONTEMINANTS IN THE PRESENCE OF A TITANIUM TRICHLORIDE CATALYST ACTIVATED BY AN ORGANOALUMINIM COMPOUND IN A MOLAR RATIO OF ORGANOALUMINUM COMPOUND TO TITANIUM CHLORIDE BETWEEN ABOUT 1.5:1 AND ABOUT 150:1 IN A REACTION ZONE MAINTAINED AT ELEVATED PRESSURE, WHEREIN A SLURRY COMPRISED OF POLYMER AND UNREACTED MONOMER IS WIHDRAWN FROM THE REACTION ZONE, AND THE SLURRY IS FLASHED IN A LOW PRESSURE SEPARATION ZONE FROM WHICH ARE SEPARATELY WITDRAWN A VAPOR COMPRISED OF UNREACTED MONOMER AND A POLYMER, THE IMPROVEMENT WHICH COMPRISES: INITMATELY CONTACTING AN A-OLEFIN STREAM CONTAINING CATALYST CONTAMINANTS WITH AT LEAST A SUFFICIENT AMOUNT OF ORGANOALUMINUM COMPOUND TO DEACTIVATE SAID CATALYST CONTAMINANTS AND TO PROVIDE SAID A-OLEFIN FEED SUBSTANTIALLY FREE OF CATALYST CONTAMINANTS AND PASSING SAID FEED IN THE ABSENCE OF CATALYST DIRECTLY TO THE REACTION ZONE, COMPRESSING AT LEAST A PORTION OF THE VAPOR FROM THE LOW PRESSURE SEPARATION ZONE AND INTRODUCING THE TITANIUM TRICHLORIDE CATALYST IN THE ABSENCE OF ORGANOALUMINUM COMPOUND WITH AT LEAST PART OF THE COMPRESSED STREAM DIRECTLY INTO THE REACTION ZONE.
Claim 2
Dependent Claim 183 words
IN A CONTINUOUS PROCESS FOR THE POLYMERIZATION OF AN AOLEFIN FEED SUBSTANTIALLY FREE OF CATALYST CONTEMINANTS IN THE PRESENCE OF A TITANIUM TRICHLORIDE CATALYST ACTIVATED BY AN ORGANOALUMINIM COMPOUND IN A MOLAR RATIO OF ORGANOALUMINUM COMPOUND TO TITANIUM CHLORIDE BETWEEN ABOUT 1.5:1 AND ABOUT 150:1 IN A REACTION ZONE MAINTAINED AT ELEVATED PRESSURE, WHEREIN A SLURRY COMPRISED OF POLYMER AND UNREACTED MONOMER IS WIHDRAWN FROM THE REACTION ZONE, AND THE SLURRY IS FLASHED IN A LOW PRESSURE SEPARATION ZONE FROM WHICH ARE SEPARATELY WITDRAWN A VAPOR COMPRISED OF UNREACTED MONOMER AND A POLYMER, THE IMPROVEMENT WHICH COMPRISES: INITMATELY CONTACTING AN A-OLEFIN STREAM CONTAINING CATALYST CONTAMINANTS WITH AT LEAST A SUFFICIENT AMOUNT OF ORGANOALUMINUM COMPOUND TO DEACTIVATE SAID CATALYST CONTAMINANTS AND TO PROVIDE SAID A-OLEFIN FEED SUBSTANTIALLY FREE OF CATALYST CONTAMINANTS AND PASSING SAID FEED IN THE ABSENCE OF CATALYST DIRECTLY TO THE REACTION ZONE, COMPRESSING AT LEAST A PORTION OF THE VAPOR FROM THE LOW PRESSURE SEPARATION ZONE AND INTRODUCING THE TITANIUM TRICHLORIDE CATALYST IN THE ABSENCE OF ORGANOALUMINUM COMPOUND WITH AT LEAST PART OF THE COMPRESSED STREAM DIRECTLY INTO THE REACTION ZONE.
Claim 3
Dependent Claim 27 words
A process according to claim 1 wherein at least a portion of the organoaluminum compound used for catalyst activation purposes is introduced directly into the reaction zone.
Claim 4
Dependent Claim 63 words
A according to claim 1 wherein the total amount of organoaluminum compound used in the process is contacted with the Alpha -olefin stream containing catalyst contaminants to provide the Alpha -olefin feed substantially free of catalyst contaminants and containing sufficient unreacted organoaluminum compound to provide the molar ratio thereof to titanium trichloride catalyst between about 1.5:1 and about 150:1 in the reaction zone.
Claim 5
Dependent Claim 13 words
A process according to claim 1 wherein the Alpha -olefin feed is propylene.
Claim 6
Dependent Claim 35 words
A process according to claim 1 wherein the titanium trichloride catalyst is a co-crystallization product of titanium trichloride and aluminum trichloride represented by the formula nTiC13.AlCl3 wherein n is a digit from 1 to 5.
Claim 7
Dependent Claim 14 words
A process according to claim 1 wherein the organoaluminum compound is diethyl aluminum chloride.

References Cited (Backward Citations)

US3257332A Cited
US2993036A Cited
US3220998A Cited
US3652527A Cited
US3729455A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-10-13 1979-04-14 1979-10-14 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-10-13 1983-04-14 1983-10-14 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-10-13 1987-04-14 1987-10-14 $7700.00 Window Closed / Lapsed

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