Patent US3957253A successfully refreshed from Google Patents.
Patent US3909456A successfully refreshed from Google Patents.
← Back to Patent Explorer
US3909456A Expired / Lapsed US ⏱️ 0.0 years remaining

Catalyst for promoting reduction of nitrogen oxides contained in exhaust gases

Assignee: Nissan Motor Co Ltd
•
Filing: 1973-04-12
•
Granted: 1975-09-30
•
Expires: 1993-04-12
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract A catalyst for reducing nitrogen oxides contained in exhaust gases, comprising a major portion of a carrier, and 0.02 to 0.85 wt% of ruthenium. The catalyst may also contain platinum, rhodium and/or palladium. The catalyst is obtained by immersing the carrier in an aqueous solution containing a catalytic component or components, and calcining the same in a flow of hydrogen gas at 300* to 1,000*C.

Inventors

  • 👤 Kiyoshi Numagami
  • 👤 Toshiki Okuyama
  • 👤 Tadanari Kato

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 20:14
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/34; B01D53/92; B01D53/94; B01D53/9404; B01D53/9409; B01D53/9413; B01J; B01J23/00; B01J23/38; B01J23/40; B01J23/46; B01J23/464; B01D2255/00; B01D2255/10; B01D2255/102; B01D2255/1021; B01D2255/1023; B01D2255/1025; B01D2255/1026

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 123 words
A METHOD FOR PREPARING A CATALYST FOR REDUCING NITROGEN OXIDES CONTAINED IN EXHAUST GASES, SAID METHOD COMPRISING THE STEPS FORMING A MONOLITHIC CARRIER IN A DESIRED FORM, IMMERSING SAID CARRIER IN AN AQUEOUS SOLUTION CONTAINING A RUTHENIUM SALT SO AS TO SUPPORT RUTHENIUM IN AN AMOUNT OF 0.020.85% BY WEIGHT, AND A SALT OF AT LEAST ONE METAL SELECTED FROM THE GROUP CONSISTING OF PALLADIUM, PLATIUM AND RHODIUM SO AS TO SUPPORT THE AT LEAST ONE METAL IN AN AMOUNT OF 0.001 TO 0.7% BY WEIGHT REMOVING THE IMMERSED CARRIER FROM THE SOLUTION, EXPOSING THE CARRIER TO A FLOW OF AMMONIA GAS, DRYING THE CARRIER, AND CALCINING THE RESULTANT CARRIER IN A FLOW OF HYDROGEN GAS AT A TEMPERATURE OF 300*C TO 1,000*C.
Claim 2
Independent Claim 123 words
A METHOD FOR PREPARING A CATALYST FOR REDUCING NITROGEN OXIDES CONTAINED IN EXHAUST GASES, SAID METHOD COMPRISING THE STEPS FORMING A MONOLITHIC CARRIER IN A DESIRED FORM, IMMERSING SAID CARRIER IN AN AQUEOUS SOLUTION CONTAINING A RUTHENIUM SALT SO AS TO SUPPORT RUTHENIUM IN AN AMOUNT OF 0.020.85% BY WEIGHT, AND A SALT OF AT LEAST ONE METAL SELECTED FROM THE GROUP CONSISTING OF PALLADIUM, PLATIUM AND RHODIUM SO AS TO SUPPORT THE AT LEAST ONE METAL IN AN AMOUNT OF 0.001 TO 0.7% BY WEIGHT REMOVING THE IMMERSED CARRIER FROM THE SOLUTION, EXPOSING THE CARRIER TO A FLOW OF AMMONIA GAS, DRYING THE CARRIER, AND CALCINING THE RESULTANT CARRIER IN A FLOW OF HYDROGEN GAS AT A TEMPERATURE OF 300*C TO 1,000*C.
Claim 3
Dependent Claim 15 words
A method as claimed in claim 1, wherein said ruthenium salt is ruthenium (III) chloride.
Claim 4
Dependent Claim 25 words
A method as claimed in claim 1, wherein said palladium saLt is selected from the group consisting of palladium (II) nitrate and palladium (II) chloride.
Claim 5
Dependent Claim 15 words
A method as claimed in claim 1, wherein said rhodium salt is rhodium (III) nitrate.
Claim 6
Independent Claim 110 words
A method for preparing a catalyst for reducing nitrogen oxides contained in exhaust gases, said method comprising the steps of: forming a monolithic carrier in a desired form; immersing said carrier in an aqueous solution containing a ruthenium salt so as to support ruthenium in an amount of 0.02 -0.85% by weight, and chloroplatinic acid so as to support the metal in said acid in an amount of 0.001 to 0.7% by weight; removing the immersed carrier from the solution; exposing the carrier to a flow of ammonia gas; drying the carrier; and calcining the resultant carrier in a flow of hydrogen gas at a temperature of 300*C to 1,000*C.
Claim 7
Independent Claim 110 words
A method for preparing a catalyst for reducing nitrogen oxides contained in exhaust gases, said method comprising the steps of: forming a monolithic carrier in a desired form; immersing said carrier in an aqueous solution containing a ruthenium salt so as to support ruthenium in an amount of 0.02 -0.85% by weight, and chloroplatinic acid so as to support the metal in said acid in an amount of 0.001 to 0.7% by weight; removing the immersed carrier from the solution; exposing the carrier to a flow of ammonia gas; drying the carrier; and calcining the resultant carrier in a flow of hydrogen gas at a temperature of 300*C to 1,000*C.

References Cited (Backward Citations)

US3118727A Cited
US3257163A Cited
US3637344A Cited
US3615166A Cited
US3784675A Cited
US3741725A Cited
US3767764A Cited
US3809743A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-09-29 1979-03-31 1979-09-30 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-09-29 1983-03-31 1983-09-30 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-09-29 1987-03-31 1987-09-30 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag