Patent US3907979A successfully refreshed from Google Patents.
US3907979A
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Low SO{HD 2 {B emission sulfuric acid process form sulfur and oxygen
Assignee: Chemiebau Dr A Zieren GmbH and KG
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Filing: 1973-05-14
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Granted: 1975-09-23
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Expires: 1993-05-14
Abstract
Abstract This invention relates to a process for the production of sulfuric acid from sulfur and technical oxygen or oxygen-enriched air by sulfur combustion and contact oxidation of the sulfur combustion gas.
Inventors
- 👤 Ernst Jenniges
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 20:48
CPC Classifications
C; C01; C01B; C01B17/00; C01B17/69; C01B17/74; C01B17/76; C01B17/765; C01B17/7655; Y; Y02; Y02P; Y02P20/00; Y02P20/10; Y02P20/129
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
189 words
A PROCESS FOR THE PRODUCTION OF SULFURIC ACID FROM SULFUR AND AN OXYGEN-CONTAINING GAS CONTAINING AT LEAST 40% BY VOLUME MOLECULAR OXYGEN COMPRISING REACTING THE SULFUR WITH SAID GAS AT ABOUT 900-3*C., TO FROM AN SO2-CONTAINING COMBUSTION GAS, OXIDIZING SAID COMBUSTION GAS WITH OXYGEN IN A MAIN CONTACT OXIDATION STAGE TO FORM AN SO3-CONTAINING CONTACT GAS, ABSORBING SAID SULFUR TRIOXIDE IN A MAIN ABSORPTIONN STEP TO FORM A RESIDUAL SO3-LEAN GAS, BRANCHING SAID SO3-LEAN GAS INTO PORTIONS THEREOF, HEATING AND PASSING A FIRST PORTION THEREOF INTO SAID MAIN CONTACT STAGE IN ADMIXTURE WITH SAID SO2-CONTAINING, COMBUSTION GAS AN OXYGEN, HEATING A SECOND PORTION OF SAID SO3-LEAN GAS TO A TEMPERATURE LESS THAN THAT OF SAID FIRST PORTION AND PASSING ONLY HEATED SECOND PORTION OF SO3- LEAN GAS TO A POST-CONTACT OXIDATION STAGE TO CONVERT RESIDUAL SO2 TO SO3, AND SUBJECTING RESULTANT SO2 DEPLETED GAS TO A SUPPLEMENTAL POST-CONTACT ABSORPTION STEP, SAID POST-CONTACT OXIDATION STAGE AND SUPPLEMENTAL POST-CONTACT ABSORPTION STEPS BEING CONDUCTED IN EQUIPMENT SIMILAR TO, BUT SEPARATE AND DISTINCT FROM, AND PHYSICALLY SMALLER THAN COMPARABLE EQUIPMENT PROVIDED FOR THE MAIN CONTACT OXIDATION STAGE AND THE MAIN ABSORPTION STEP RESPECTIVELY.
Claim 2
Dependent Claim
189 words
A PROCESS FOR THE PRODUCTION OF SULFURIC ACID FROM SULFUR AND AN OXYGEN-CONTAINING GAS CONTAINING AT LEAST 40% BY VOLUME MOLECULAR OXYGEN COMPRISING REACTING THE SULFUR WITH SAID GAS AT ABOUT 900-3*C., TO FROM AN SO2-CONTAINING COMBUSTION GAS, OXIDIZING SAID COMBUSTION GAS WITH OXYGEN IN A MAIN CONTACT OXIDATION STAGE TO FORM AN SO3-CONTAINING CONTACT GAS, ABSORBING SAID SULFUR TRIOXIDE IN A MAIN ABSORPTIONN STEP TO FORM A RESIDUAL SO3-LEAN GAS, BRANCHING SAID SO3-LEAN GAS INTO PORTIONS THEREOF, HEATING AND PASSING A FIRST PORTION THEREOF INTO SAID MAIN CONTACT STAGE IN ADMIXTURE WITH SAID SO2-CONTAINING, COMBUSTION GAS AN OXYGEN, HEATING A SECOND PORTION OF SAID SO3-LEAN GAS TO A TEMPERATURE LESS THAN THAT OF SAID FIRST PORTION AND PASSING ONLY HEATED SECOND PORTION OF SO3- LEAN GAS TO A POST-CONTACT OXIDATION STAGE TO CONVERT RESIDUAL SO2 TO SO3, AND SUBJECTING RESULTANT SO2 DEPLETED GAS TO A SUPPLEMENTAL POST-CONTACT ABSORPTION STEP, SAID POST-CONTACT OXIDATION STAGE AND SUPPLEMENTAL POST-CONTACT ABSORPTION STEPS BEING CONDUCTED IN EQUIPMENT SIMILAR TO, BUT SEPARATE AND DISTINCT FROM, AND PHYSICALLY SMALLER THAN COMPARABLE EQUIPMENT PROVIDED FOR THE MAIN CONTACT OXIDATION STAGE AND THE MAIN ABSORPTION STEP RESPECTIVELY.
Claim 3
Dependent Claim
40 words
A process according to claim 1 wherein 50-99.9% by volume of the SO3-lean gas from the main absorption step is recycled into the main contact stage, and 0.1-1.50% by volume of the SO3-lean gas is fed to the post-contact stage.
Claim 4
Dependent Claim
40 words
A process according to claim 1 wherein 95-99.9% by volume of the SO3-lean gas from the main absorption step is recycled into the main contact stage and 0.5-5% by volume of the SO3-lean gas is fed to the post-contact stage.
Claim 5
Dependent Claim
26 words
A process as defined by claim 1 wherein the SO3-containing contact gas is cooled to 80*-220* C., prior to being passed to the main absorption stage.
Claim 6
Dependent Claim
24 words
A process as defined by claim 1 wherein said sulfur is burned with technical oxygen and the contact oxidation is conducted with technical oxygen.
Claim 7
Dependent Claim
48 words
A process as defined by claim 1, a portion of SO2-containing combustion gas being cooled and recycled to the sulfur combustion stage, and said SO2-containing combustion gas prior to being mixed with said first portion of SO3-lean gas and entering the main contact stage being cooled to 110*-350*C.
Claim 8
Dependent Claim
24 words
A process as defined by claim 6 wherein the sulfur is burned in a waste heat boiler under a gauge pressure of 1-20 atmospheres.
Claim 9
Dependent Claim
26 words
A process according to claim 1 further comprising heating the SO3-lean gas from the main absorption stage indirectly with hot gases from the main contact stage.
Claim 10
Dependent Claim
24 words
A process as defined by claim 8 wherein said SO3-lean gas is heated to 400*-450* C., prior to being subjected to the post-contact stage.
Claim 11
Dependent Claim
23 words
A process as defined by claim 9, said SO3-lean gas being heated to 400*-420* C. prior to being subjected to the post-contact stage.
Claim 12
Dependent Claim
30 words
A process as defined by claim 10, wherein the 400*-420* C. temperature of the SO3-lean gas is obtained by mixing two streams of SO3-lean gas having two different temperature levels.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1978-09-22 | 1979-03-24 | 1979-09-23 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1982-09-22 | 1983-03-24 | 1983-09-23 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1986-09-22 | 1987-03-24 | 1987-09-23 | $7700.00 | Window Closed / Lapsed |