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US3907925A Expired / Lapsed US ⏱️ 0.0 years remaining

Metal deactivators as adhesion promotors for vulcanizable elastomers to metals

Assignee: Novartis Corp
•
Filing: 1973-10-10
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Granted: 1975-09-23
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Expires: 1993-10-10
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Abstract

Abstract Adhesion of metals to vulcanizable elastomers is promoted by a process of incorporating into the elastomer a metal deactivator and then vulcanizing the elastomeric composition while it is in contact with the metal surface.

Inventors

  • 👤 George K Cowell
  • 👤 David J Cherry

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 15:05
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/36; C08K5/37; C08K5/372; C08K5/3725; C08K5/16; C08K5/22; C08K5/24; C08K5/29; C08K5/30; C08K5/34; C08K5/3467; C08K5/3477; C08K5/3492; C08K5/38; Y; Y10; Y10S; Y10S156/00; Y10S156/91

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 68 words
A METHOD OF IMPROVING ADHESION BETWEEN A VULCANIZABLE ELASTOMERIC COMPOSITION AND A METAL SURFACE TO PROVIDE A STRONG AND DURABLE BOND, WHICH METHOD COMPRISES A. ADDING TO A VULCANIZABLE ELASTOMERIC COMPOSITION FROM 0.05 PHR TO 10 BY WEIGHT BASED ON THE WEIGHT OF THE ELASTOMER OF AN ORGANIC HYDROZINE DERIVATIVE WITH METAL DEACTING EFFICIENCY, AND B. VULCANIZING THE COMPOSITION WHILE IT IS IN CONDUCT WITH THE METAL SURFACE.
Claim 2
Independent Claim 68 words
A METHOD OF IMPROVING ADHESION BETWEEN A VULCANIZABLE ELASTOMERIC COMPOSITION AND A METAL SURFACE TO PROVIDE A STRONG AND DURABLE BOND, WHICH METHOD COMPRISES A. ADDING TO A VULCANIZABLE ELASTOMERIC COMPOSITION FROM 0.05 PHR TO 10 BY WEIGHT BASED ON THE WEIGHT OF THE ELASTOMER OF AN ORGANIC HYDROZINE DERIVATIVE WITH METAL DEACTING EFFICIENCY, AND B. VULCANIZING THE COMPOSITION WHILE IT IS IN CONDUCT WITH THE METAL SURFACE.
Claim 3
Dependent Claim 26 words
The method of claim 1 wherein the vulcanizable elastomer is selected from natural rubber, styrene-butadiene copolymer, ethylene-propylene terpolymer or butyl rubber containing at least 0.8% unsaturation.
Claim 4
Dependent Claim 30 words
The method of claim 1 wherein the organic hydrazine derivative is present in an amount of from 0.1 to 5.0 phr by weight, based on the weight of the elastomer.
Claim 5
Dependent Claim 12 words
The method of claim 1 wherein the elastomeric composition contains carbon black.
Claim 6
Dependent Claim 11 words
The method of claim 1 wherein the vulcanizing agent is sulfur.
Claim 7
Dependent Claim 20 words
The method of claim 1 wherein the vulcanizable elastomer is natural rubber and the organic hydrazine derivative has the formula
Claim 8
Dependent Claim 12 words
The method of claim 6 wherein the organic hydrazine derivative is oxalo-bis-(2-hydroxy-benzylidene-hydrazide).

References Cited (Backward Citations)

US2018645A Cited
US2912355A Cited
US3110696A Cited
US3357944A Cited
US3660438A Cited
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US3734885A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-09-22 1979-03-24 1979-09-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-09-22 1983-03-24 1983-09-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-09-22 1987-03-24 1987-09-23 $7700.00 Window Closed / Lapsed

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