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US3904587A
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Process for the production of polymers capable of self-curing at room temperature and products thereof
Assignee: National Institute of Advanced Industrial Science and Technology
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Filing: 1972-10-26
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Granted: 1975-09-09
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Expires: 1992-10-26
Abstract
Abstract A polymer capable of self-curing or cross-linking at room temperature is produced by free radical polymerization in a nonprotonic solvent of: A. i. a combination of (a) at least one ethylenically unsaturated compound having an epoxy group and (b) at least one ethylenically unsaturated compound having a tertiary amino group selected from the group consisting of an N,Ndisubstituted amino group, a pyridyl group, a quinolyl group and an isoquinolyl group or II. AT LEAST ONE ETHYLENICALLY UNSATURATED COMPOUND HAVING ONE EPOXY GROUP AND ONE TERTIARY AMINO GROUP SELECTED FROM THE GROUP CONSISTING OF AN N,N-disubstituted amino group, a pyridyl group, a quinolyl group and an isoquinolyl group, and optionally B. at least one free radical-copolymerizable ethylenically unsaturated compound other than the ethylenically unsaturated compounds (i) and (ii) and which is free of active hydrogen atoms.
Inventors
- 👤 Yoshio Tanaka
- 👤 Masao Kato
- 👤 Akira Okada
- 👤 Yukio Shimura
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-31 19:46
CPC Classifications
C; C08; C08F; C08F220/00; C08F220/02; C08F220/10; C08F220/26; C08F220/32; C08F220/325
Claims Analysis
Total Claims: 8
Claim 1
Independent Claim
67 words
A PROCESS FOR THE PRODUCTION OF POLYMERS CAPABLE OF SELF-CURING A ROOM TEMPERATURE CHARACTERIZED BY SUBJECTING TO REE RADICAL PHOLYMERICATION IN A NON-PROTONIC SOLVENT A MONOMERIC MATERIAL CONSISTING ESSENTIALLY OF AT LEAST ONE ETHYLENICALLY UNSATURATED MONOMER HVING AT LEAST ONE EPOXY GROUP AND A TERTIARY AMINO GROUP SELECTED FROM THE GROUP CONSISTING OF A N-N-DITUTED AMINO GROUP A PYRIDYL GROUP A QUINOLYL GROUP AND AN ISOQUINOLYL GROUP.
Claim 2
Dependent Claim
67 words
A PROCESS FOR THE PRODUCTION OF POLYMERS CAPABLE OF SELF-CURING A ROOM TEMPERATURE CHARACTERIZED BY SUBJECTING TO REE RADICAL PHOLYMERICATION IN A NON-PROTONIC SOLVENT A MONOMERIC MATERIAL CONSISTING ESSENTIALLY OF AT LEAST ONE ETHYLENICALLY UNSATURATED MONOMER HVING AT LEAST ONE EPOXY GROUP AND A TERTIARY AMINO GROUP SELECTED FROM THE GROUP CONSISTING OF A N-N-DITUTED AMINO GROUP A PYRIDYL GROUP A QUINOLYL GROUP AND AN ISOQUINOLYL GROUP.
Claim 3
Dependent Claim
100 words
A process for the production of polymers capable of self-curing at room temperature, characterized by subjecting to free radical polymerization in a non-protonic solvent a monomeric material consisting essentially of: a. at least one ethylenically unsaturated monomer having at least one epoxy group connected to the ethylenically unsaturated group through a tertiary amino group, a pyridyl group, a quinolyl group, or an isoquinolyl group with b. at least one other ethylenically unsaturated monomer free of active hydrogen-containing groups, said other monomer being present in an amount of about 0.5-1,000 mole percent based on the epoxy substituted ethylenically unsaturated monomer (a).
Claim 4
Dependent Claim
100 words
A process for the production of polymers capable of self-curing at room temperature, characterized by subjecting to free radical polymerization in a non-protonic solvent a monomeric material consisting essentially of: a. at least one ethylenically unsaturated monomer having at least one epoxy group connected to the ethylenically unsaturated group through a tertiary amino group, a pyridyl group, a quinolyl group, or an isoquinolyl group with b. at least one other ethylenically unsaturated monomer free of active hydrogen-containing groups, said other monomer being present in an amount of about 0.5-1,000 mole percent based on the epoxy substituted ethylenically unsaturated monomer (a).
Claim 5
Dependent Claim
40 words
A polymer self-curing at room temperature of at least one ethylenically unsaturated monomer having at least one epoxy group connected to the ethylenically unsaturated group through a tertiary amino group, a pyridyl group, a quinolyl group, or an isoquinolyl group.
Claim 6
Dependent Claim
40 words
A polymer self-curing at room temperature of at least one ethylenically unsaturated monomer having at least one epoxy group connected to the ethylenically unsaturated group through a tertiary amino group, a pyridyl group, a quinolyl group, or an isoquinolyl group.
Claim 7
Dependent Claim
77 words
A copolymer self-curing at room temperature of (a) at least one ethylenically unsaturated monomer having at least one epoxy group connected to the ethylenically unsaturated group through a tertiary amino group, a pyridyl group, a quinolyl group, or an isoquinolyl group with (a) at least one other ethylenically unsaturated monomer free of active hydrogen-containing groups, said other monomer being present in an amount of about 0.5-1,000 mole percent based on the epoxy substituted ethylenically unsaturated monomer (a).
Claim 8
Dependent Claim
77 words
A copolymer self-curing at room temperature of (a) at least one ethylenically unsaturated monomer having at least one epoxy group connected to the ethylenically unsaturated group through a tertiary amino group, a pyridyl group, a quinolyl group, or an isoquinolyl group with (a) at least one other ethylenically unsaturated monomer free of active hydrogen-containing groups, said other monomer being present in an amount of about 0.5-1,000 mole percent based on the epoxy substituted ethylenically unsaturated monomer (a).
References Cited (Backward Citations)
US2687404A
Cited
US2910459A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1978-09-08 | 1979-03-10 | 1979-09-09 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1982-09-08 | 1983-03-10 | 1983-09-09 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1986-09-08 | 1987-03-10 | 1987-09-09 | $7700.00 | Window Closed / Lapsed |