Patent US3904384A successfully refreshed from Google Patents.
← Back to Patent Explorer
US3904384A Expired / Lapsed US ⏱️ 0.0 years remaining

Gasoline production

Assignee: Chevron USA Inc
•
Filing: 1972-11-13
•
Granted: 1975-09-09
•
Expires: 1992-11-13
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract A process for producing a high-octane gasoline having reduced smog-forming tendencies, which comprises: A. THERMALLY DEHYDROGENATING-CRACKING ISOBUTANE TO OBTAIN PROPYLENE AND ISOBUTENE; B. HYDRATING PROPYLENE TO OBTAIN ISOPROPANOL; C. ETHERATING THE ISOPROPANOL WITH THE ISOBUTENE TO OBTAIN TBUTYL ISOPROPYL ETHER; AND D. BLENDING THE T-BUTYL ISOPROPYL ETHER WITH GASOLINE-BOILINGRANGE HYDROCARBONS. Preferably the thermal dehydrogenation is carried out under conditions, specifically including a temperature between about 1125* and 1275*F., to produce a molar ratio of isobutene to propylene between 1.0 to 1.25.

Inventors

  • 👤 Jacob D Kemp
  • 👤 Robert P Sieg

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 17:14
CPC Classifications
C; C10; C10L; C10L1/00; C10L1/02; C10L1/023

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 176 words
IN A PROCESS FOR PRODUCING A HIGH-OCTANE GASOLINE BY BLENDING A HYDROCARBON MIXTURE OF THE GASOLINE RANGE WITH AN ETHER, THE IMPROVEMENT WHICH COMPRISES: A. PRODUCING A MIXTURE COMPRISING PROPYLENE AND ISOBUTENE IN WHICH THE MOL RATIO OF THE ISOBUTENEE IS TO PROPYLENE IS IN THE RANGE FROM ABOUT 1-1.25 TO 1, RESPECTIVELY, BY MAINTAINING A REFINERY PROCESS STREAM COMPRISING A SUBSTANTIALLY ISOBUTANCE FEED IN A REACTION ZONE AT A TEMPERATURE IN THE RANGE FROM ABOUT 1125*F. TO 1275*F., B. SEPARATING BY DISTILLATION SAID MIXTURE INTO A PROPYLENERICH STREAM AND AN ISOBUTENE-RICH STREAM, C. PRODUCING ISOPROPANOL BY CONTACTING A MIXTURE OF THE PROPYLENE-RICH STREAM AND WATER WITH A SOLID ACIDIC HYDRATION CATALYST AT A TEMPERATURE IN THE RANGE FROM ABOUT 100* TO ABOUT 400*F, D. PRODUCING-BUTYL ISOPROPYL ETHER BY REACTING SAID ISOPROPANOL WITH SAID ISOBUTENE-RICH STREAM BY CONTACTING A MIXTURE OF SAID REACTANTS WITH A SOLIDS ACIDIC ETHERATION CATALYST IN A REACTION ZONE AT A TEMPERATURE BETWEEN ABOUT 50* TO 200*F AND E. PRODUCING A HIGH-OCTANE GASOLINE BY BLENDING SAID ETHER WITH SAID GASOLINE-RANGE HYDROCARBON MIXTURE.
Claim 2
Dependent Claim 176 words
IN A PROCESS FOR PRODUCING A HIGH-OCTANE GASOLINE BY BLENDING A HYDROCARBON MIXTURE OF THE GASOLINE RANGE WITH AN ETHER, THE IMPROVEMENT WHICH COMPRISES: A. PRODUCING A MIXTURE COMPRISING PROPYLENE AND ISOBUTENE IN WHICH THE MOL RATIO OF THE ISOBUTENEE IS TO PROPYLENE IS IN THE RANGE FROM ABOUT 1-1.25 TO 1, RESPECTIVELY, BY MAINTAINING A REFINERY PROCESS STREAM COMPRISING A SUBSTANTIALLY ISOBUTANCE FEED IN A REACTION ZONE AT A TEMPERATURE IN THE RANGE FROM ABOUT 1125*F. TO 1275*F., B. SEPARATING BY DISTILLATION SAID MIXTURE INTO A PROPYLENERICH STREAM AND AN ISOBUTENE-RICH STREAM, C. PRODUCING ISOPROPANOL BY CONTACTING A MIXTURE OF THE PROPYLENE-RICH STREAM AND WATER WITH A SOLID ACIDIC HYDRATION CATALYST AT A TEMPERATURE IN THE RANGE FROM ABOUT 100* TO ABOUT 400*F, D. PRODUCING-BUTYL ISOPROPYL ETHER BY REACTING SAID ISOPROPANOL WITH SAID ISOBUTENE-RICH STREAM BY CONTACTING A MIXTURE OF SAID REACTANTS WITH A SOLIDS ACIDIC ETHERATION CATALYST IN A REACTION ZONE AT A TEMPERATURE BETWEEN ABOUT 50* TO 200*F AND E. PRODUCING A HIGH-OCTANE GASOLINE BY BLENDING SAID ETHER WITH SAID GASOLINE-RANGE HYDROCARBON MIXTURE.
Claim 3
Dependent Claim 19 words
The process as in claim 1 wherein the propylene-isobutene mixture is produced in the absence of a dehydrogenation catalyst.
Claim 4
Dependent Claim 23 words
The process as in claim 2 wherein the propylene-isobutene mixture is produced at a temperature in the range from about 1175* to 1235*F.
Claim 5
Dependent Claim 23 words
The process as in claim 2 wherein the propyleneisobutene mixture is produced at a temperature in the range from about 1185* to 1215*F.
Claim 6
Dependent Claim 22 words
The process as in claim 1 wherein the hydration and etheration catalysts are selected from the group consisting of acidic sulfonate resins.
Claim 7
Dependent Claim 27 words
The process as in claim 5 wherein the production of the isopropanol is carried out at a pressure in the range from about 10 to 1500 psig.
Claim 8
Dependent Claim 24 words
The process as in claim 5 wherein the resin catalyst has a hydrogen ion concentration of about 4.9 milliequivalents per gram of the catalyst.
Claim 9
Dependent Claim 24 words
The process as in claim 5 wherein the etheration reaction is carried out at a temperature in the range from about 75* to 125*F.
Claim 10
Dependent Claim 13 words
The process as in claim 1 wherein said feed comprises an n-butane isomerizate.
Claim 11
Dependent Claim 19 words
The process as in claim 1 wherein the propyleneisobutene mixture is produced in the presence of a dehydrogenation catalyst.
Claim 12
Dependent Claim 23 words
The process as in claim 10 wherein the propyleneisobutene mixture is produced at a temperature in the range from about 1175* to 1235*F.
Claim 13
Dependent Claim 23 words
The process as in claim 10 wherein the propyleneisobutene mixture is produced at a temperature in the range from about 1185* to 1215*F.

References Cited (Backward Citations)

US2816150A Cited
US2848522A Cited
US2813908A Cited
US2861045A Cited
US2891999A Cited
US2803667A Cited
US3224848A Cited
US3285977A Cited
US3482952A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-09-08 1979-03-10 1979-09-09 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-09-08 1983-03-10 1983-09-09 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-09-08 1987-03-10 1987-09-09 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag