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US3901929A Expired / Lapsed US ⏱️ 0.0 years remaining

Wet processing of leather

Assignee: Thermanil Chemical Co Inc
•
Filing: 1972-09-27
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Granted: 1975-08-26
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Expires: 1992-09-27
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Abstract

Abstract A new tanning agent is provided comprising an organic salt of a phosphorated and ethoxylated saturated fatty acid. The tanning agent is prepared by reacting a saturated fatty acid having 12 to 20 carbon atoms with ethylene oxide, phosphorating the resulting ethoxylated fatty acid ester with phosphoric anhydride, and neutralizing the phosphorated ester with a strong organic base, such as triethanolamine. The tanning agent is preferably dissolved in a water soluble solvent such as dimethyl formamide and may be diluted with water for addition in the wet processing of leather. The new tanning agent may be added to the leather in the tanning wheel either during the initial tanning or during retanning, and is particularly useful in connection with chrome tanned leathers. Such tanning agents increase dye values and improve softness and other properties of the leather. They also permit the reduction or elimination of chrome tanning agents and fat liquors in the retanning stage as well as improving take up of chrome in the tanning and/or retanning.

Inventors

  • 👤 Gerald M Cote

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 20:19
CPC Classifications
C; C14; C14C; C14C3/00; C14C3/02; C14C3/08

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 42 words
A TANNING AGENT FOR LEATHER COMPRISING AN ORGANIC SALT OF A PHOSPHORATED ETHOXYLATED SATURED FATTY ACID ESTER, THE SATURATED FATTY ACID HAVING FROM 12 TO 20 CARBON ATOMS AND SAID SALT BEING THE NEUTRALIZATION PRODUCT OF SAID ESTER WITH AN ORGANIC BASE.
Claim 2
Dependent Claim 42 words
A TANNING AGENT FOR LEATHER COMPRISING AN ORGANIC SALT OF A PHOSPHORATED ETHOXYLATED SATURED FATTY ACID ESTER, THE SATURATED FATTY ACID HAVING FROM 12 TO 20 CARBON ATOMS AND SAID SALT BEING THE NEUTRALIZATION PRODUCT OF SAID ESTER WITH AN ORGANIC BASE.
Claim 3
Dependent Claim 26 words
A tanning agent according to claim 1 wherein said ester is approximately 50 percent monoethoxy ester and 50 percent diethoxy and is phosphorated with phosphoric anhydride.
Claim 4
Dependent Claim 24 words
A tanning agent according to claim 1 wherein said organic base is triethanolamine, and said salt has a pH of about 6 to 7.5.
Claim 5
Dependent Claim 17 words
A tanning agent according to claim 3 wherein said salt is dissolved in a water soluble solvent.
Claim 6
Dependent Claim 13 words
A tanning agent according to claim 4 wherein said solvent is dimethyl formamide.
Claim 7
Independent Claim 50 words
A method of making a tanning agent for leather comprising the steps of reacting a saturated fatty acid having from 12 to 20 carbon atoms with ethylene oxide, phosphorating the resulting ethoxylated saturated fatty acid ester by reacting with phosphoric anhydride, and neutralizing the phosphorated compound with an organic base.
Claim 8
Independent Claim 50 words
A method of making a tanning agent for leather comprising the steps of reacting a saturated fatty acid having from 12 to 20 carbon atoms with ethylene oxide, phosphorating the resulting ethoxylated saturated fatty acid ester by reacting with phosphoric anhydride, and neutralizing the phosphorated compound with an organic base.
Claim 9
Dependent Claim 17 words
A method according to claim 6 wherein the neutralized compound is dissolved in a water soluble solvent.
Claim 10
Dependent Claim 21 words
A method according to claim 6 wherein about one mole of phosphoric anhydride is reacted with every three moles of ester.
Claim 11
Dependent Claim 18 words
A method according to claim 6 wherein said ester is approximately 50 percent mono-ester and 50 percent di-ester.

References Cited (Backward Citations)

US3629377A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-08-25 1979-02-24 1979-08-26 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-08-25 1983-02-24 1983-08-26 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-08-25 1987-02-24 1987-08-26 $7700.00 Window Closed / Lapsed

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