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US3900613A Expired / Lapsed US ⏱️ 0.0 years remaining

Production of surface diffusion alloys

Assignee: Office National d'Études et de Recherches Aérospatiales
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Filing: 1973-06-25
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Granted: 1975-08-19
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Expires: 1993-06-25
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Abstract

Abstract A metal called ''''application metal'''' is applied to the inner wall of a metallic hollow part, especially a metallic hollow part whose inner cavity has oblong or curved zones difficult to reach by a powder or pastry material. A heat treatment utilises a cement placed in the inner cavity of the treated part and in immediate proximity to the walls of said cavity, this cement comprising, among other constituents, a powder of the one or more application metals, an inert diluent with a high heat of formation, and a halogen or halogenated compound. The cement also contains a solution of a surface active agent adapted to confer thixotropic properties on the mixture formed by the initial constituents of the cement and by the solution. It is subjected to vibration during its introduction into the cavity and is then left undisturbed until it resumes its initial viscosity. The hollow part thus lined with cement is subjected to the heat diffusion treatment proper and, once this heat diffusion treatment is terminated, the cement is removed.

Inventors

  • 👤 Philippe Marie Galmiche
  • 👤 Andre Hivert

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 21:40
CPC Classifications
C; C23; C23C; C23C10/00; C23C10/04

Claims Analysis

Total Claims: 19
Claim 1
Independent Claim 260 words
IN A METHOD OF FORMING A SURFACE DIFFUSION ALLOY BY APPLYING AT LEAST ONE APPLICATION METAL TO THE INNER WALL OF A HOLLOW METALLIC PART IN WHICH A CEMENT COMPRISING A POWDER OF AT LEAST ONE APPLICATION METAL, AN INERT DILUENT HAVING A HIGH HEAT OF FORMATION TO PREVENT COALESCENCE OR SINTERING OF THE PARTICLES OF THE APPLICATION METAL POWDER DURING FORMATION OF SAID SURFACE DIFFUSION ALLOY, AND A HALOGEN OR HALOGENATED COMPOUND FOR GENERATING VAPORS OF SAID APPLICATION METAL TO THE INNER WALL OF THE PART TO BE TREATED, IS INTRODUCED INTO THE CAVITY OF SAID HOLLOW PART IN IMMEDIATED PROXIMITY TO SAID WALL, AND IN WHICH THE CEMENT IS THEN HEATED TO GENERATE VAPORS OF THE APPLICATION METAL TO FORM A SURFACE DIFFUSION ALLOY OF THE APPLICATION METAL AND THE METALLIC PART AT THE INNER WALL OF SAID PART, THE IMPROVEMENT WHICH COMPRISES: PROVIDING IN SAID CEMENT A SURFACE ACTIVE AGENT SELECTED FROM THE GROUP CONSISTING OF OLEIC ACID, LINOLEIC ACID AND RICINOLEIC ACID IN AN AMOUNT SUFFICIENT TO CONFER THIXOTROPIC PPROPERTIES ON THE CEMENT SUCH THAT THE CEMENT IS TEMPORARILY LIQUEFIED WHEN SUBJECTED TO VIBRATION. SUBJECTING THE CEMENT WITHIN SAID CAVITY, PRIOR TO HEATING THE CEMENT TO VIBRATION TO TEMPORARILY LIQUEFY SAID CEMENT TO FACILITATE PENETRATION OF SAID CEMENT INTO REMOTE ZONES OF SAID CAVITY TO BRING SAID CEMENT INTO IMMEDIATE PROXIMITY TO SAID WALL, LEAVING THE CEMENT UNDISTURBED WITHIN THE CAVITY UNTIL IT RESUMES ITS INITIAL VISCOSITY, AND AFTER HEATING THE CEMENT TO FORM SAID SURFACE DIFFUSION ALLOY, REMOVING THE CEMENT FROM WITHIN THE HOLLOW PART.
Claim 2
Dependent Claim 260 words
IN A METHOD OF FORMING A SURFACE DIFFUSION ALLOY BY APPLYING AT LEAST ONE APPLICATION METAL TO THE INNER WALL OF A HOLLOW METALLIC PART IN WHICH A CEMENT COMPRISING A POWDER OF AT LEAST ONE APPLICATION METAL, AN INERT DILUENT HAVING A HIGH HEAT OF FORMATION TO PREVENT COALESCENCE OR SINTERING OF THE PARTICLES OF THE APPLICATION METAL POWDER DURING FORMATION OF SAID SURFACE DIFFUSION ALLOY, AND A HALOGEN OR HALOGENATED COMPOUND FOR GENERATING VAPORS OF SAID APPLICATION METAL TO THE INNER WALL OF THE PART TO BE TREATED, IS INTRODUCED INTO THE CAVITY OF SAID HOLLOW PART IN IMMEDIATED PROXIMITY TO SAID WALL, AND IN WHICH THE CEMENT IS THEN HEATED TO GENERATE VAPORS OF THE APPLICATION METAL TO FORM A SURFACE DIFFUSION ALLOY OF THE APPLICATION METAL AND THE METALLIC PART AT THE INNER WALL OF SAID PART, THE IMPROVEMENT WHICH COMPRISES: PROVIDING IN SAID CEMENT A SURFACE ACTIVE AGENT SELECTED FROM THE GROUP CONSISTING OF OLEIC ACID, LINOLEIC ACID AND RICINOLEIC ACID IN AN AMOUNT SUFFICIENT TO CONFER THIXOTROPIC PPROPERTIES ON THE CEMENT SUCH THAT THE CEMENT IS TEMPORARILY LIQUEFIED WHEN SUBJECTED TO VIBRATION. SUBJECTING THE CEMENT WITHIN SAID CAVITY, PRIOR TO HEATING THE CEMENT TO VIBRATION TO TEMPORARILY LIQUEFY SAID CEMENT TO FACILITATE PENETRATION OF SAID CEMENT INTO REMOTE ZONES OF SAID CAVITY TO BRING SAID CEMENT INTO IMMEDIATE PROXIMITY TO SAID WALL, LEAVING THE CEMENT UNDISTURBED WITHIN THE CAVITY UNTIL IT RESUMES ITS INITIAL VISCOSITY, AND AFTER HEATING THE CEMENT TO FORM SAID SURFACE DIFFUSION ALLOY, REMOVING THE CEMENT FROM WITHIN THE HOLLOW PART.
Claim 3
Dependent Claim 39 words
A method according to claim 1, wherein the treated hollow part, at least at the inner wall of its cavity, is constituted by at least one metal selected from the group consisting of iron, nickel, cobalt, tungsten and molybdenum.
Claim 4
Dependent Claim 33 words
A method according to claim 1, wherein at least the inner wall of the cavity of said part includes an additional metal selected from the group consisting of chromium, titanium, aluminum or zirconium.
Claim 5
Dependent Claim 29 words
A method according to claim 1, wherein the application metal is selected from the group consisting of chromium, aluminum, tantalum, tinanium, zirconium, vanadium, boron and alloys of these metals.
Claim 6
Dependent Claim 27 words
A method according to claim 1, wherein the surface active agent is present in a solution, the solvent thereof having a boiling point between 80* and 120*C.
Claim 7
Dependent Claim 18 words
A method according to claim 5, wherein the solvent is an aliphatic or aromatic hydrocarbon, or absolute alcohol.
Claim 8
Dependent Claim 29 words
A method according to claim 1, wherein the surface active agent is introduced into a mixing apparatus at the same operational stage as the other constituents of the cement.
Claim 9
Dependent Claim 20 words
A method according to claim 1, wherein introduction of the cement into the cavity is effected by simple gravity flow.
Claim 10
Dependent Claim 26 words
A method according to claim 1, wherein the introduction of the cement into the cavity of the treated part subjected to vibration is effected by injection.
Claim 11
Dependent Claim 29 words
A method according to claim 1, wherein the surface active agent is present in a solution and wherein the solvent is removed prior to forming said surface diffusion alloy.
Claim 12
Dependent Claim 16 words
A method according to claim 10, wherein the elimination of the solvent is effected by heating.
Claim 13
Dependent Claim 39 words
A method according to claim 11, wherein the heating is carried out in a first phase conducted at a temperature below the boiling point of the solution and a second phase conducted at a temperature above this boiling point.
Claim 14
Dependent Claim 25 words
A method according to claim 1, wherein the removal of the cement residue from the hollow part comprises introducing an aqueous or alcohol acid solution.
Claim 15
Dependent Claim 25 words
A method according to claim 1, wherein the application metal is one which forms a protective surface diffusion alloy on the wall of said part.
Claim 16
Dependent Claim 38 words
A method according to claim 1, wherein the outer wall of the part is provided with a surface diffusion alloy by heat treatment with a cement comprising said powder, said inert diluent, and said halogen or halogenated compound.
Claim 17
Dependent Claim 27 words
A method according to claim 15, wherein the cement used for the treatment of the outer wall is different from the cement used for the inner wall.
Claim 18
Dependent Claim 30 words
A method according to claim 15, wherein the cement used for the treatment of the outer wall is the same as that used for the treatment of the inner wall.
Claim 19
Dependent Claim 16 words
Hollow metallic part having a surface diffusion alloy formed by the method according to claim 1.

References Cited (Backward Citations)

US1867837A Cited
US2657668A Cited
US2987416A Cited
US3038823A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-08-18 1979-02-17 1979-08-19 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-08-18 1983-02-17 1983-08-19 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-08-18 1987-02-17 1987-08-19 $7700.00 Window Closed / Lapsed

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