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US3899447A Expired / Lapsed US ⏱️ 0.0 years remaining

Detergent compositions containing silica colloids

Assignee: Individual
•
Filing: 1972-12-27
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Granted: 1975-08-12
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Expires: 1992-12-27
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Abstract

Abstract This invention is concerned with detergent compositions containing colloidal silica to enhance their cleaning and soil removal ability. The colloidal silica is formed in situ as a sol by the reaction of water-soluble or dispersible alkali silicates with a variety of anionic, detergent-forming organic acids, exemplified by fatty acids of from 8 to 12 carbon atoms or alkyl aryl sulfonic acids. The colloidal silica is characterized by an alkaline oxide to SiO2 ratio of from 1:4 to 1:2000 or more.

Inventors

  • 👤 Louis Mcdonald

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 09:36
CPC Classifications
C; C11; C11D; C11D9/00; C11D9/04; C11D9/06; C11D9/18; C11D3/00; C11D3/02; C11D3/12; C11D3/124; C11D3/16; C11D3/37; C11D3/3746; C11D3/378; C11D9/08; C11D9/10

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 75 words
AN AQUEOUS DETERGENT COMPOSITION COMPRISING (A) AN ALKALI SALT OF AN ANIONIC DETERGENT FORMING ACID AND (B) A COLLODIAL SILICA SOL, (A) AND (B) BEING FORMED IN SITU BY REACTION OF A CORRESPONDING WATER SOLUBLE ALKALI SILICATE AND ANIONIC DETERGENT FORMING ACID IN SUCH PROPORTION AS TO YIELD A COMPOSITION NOT GREATER THAN 0.2 N IN ALKALI ION, THE SILICA SOL OF SAID DETERGENT COMPOSITION BEING ALKALI-STABILIZED WITHIN A PH RANGE OF 7.2 TO 11.0.
Claim 2
Dependent Claim 75 words
AN AQUEOUS DETERGENT COMPOSITION COMPRISING (A) AN ALKALI SALT OF AN ANIONIC DETERGENT FORMING ACID AND (B) A COLLODIAL SILICA SOL, (A) AND (B) BEING FORMED IN SITU BY REACTION OF A CORRESPONDING WATER SOLUBLE ALKALI SILICATE AND ANIONIC DETERGENT FORMING ACID IN SUCH PROPORTION AS TO YIELD A COMPOSITION NOT GREATER THAN 0.2 N IN ALKALI ION, THE SILICA SOL OF SAID DETERGENT COMPOSITION BEING ALKALI-STABILIZED WITHIN A PH RANGE OF 7.2 TO 11.0.
Claim 3
Dependent Claim 34 words
The composition of claim 1 wherein the silica sol particles of said detergent composition are less than 5 microns in diameter and are characterized by an alkali oxide to SiO2 ratio greater than 1:4.
Claim 4
Dependent Claim 26 words
The composition of claim 2 wherein the silica sol particles of said composition are characterized by an alkali oxide to SiO2 ratio of 1:4 to 1:2000.
Claim 5
Dependent Claim 35 words
The composition of claim 3 wherein said anionic detergent-forming acid is selected from the group consisting of fatty acids having from 8 to 22 carbon atoms in the carbon chain and alkyl aryl sulfonic acids.
Claim 6
Dependent Claim 30 words
The composition of claim 4 wherein said alkali silicate is selected from the group consisting of sodium and potassium silicates having an alkali oxide to SiO2 ratio greater than 1:4.
Claim 7
Dependent Claim 13 words
The composition of claim 5 wherein said acid is dodecyl benzene sulfonic acid.
Claim 8
Dependent Claim 12 words
The composition of claim 5 wherein said alkali silicate is sodium silicate.
Claim 9
Dependent Claim 15 words
The composition of claim 1 which additionally comprises a minor amount of polystyrene alkali sulfonate.
Claim 10
Dependent Claim 14 words
A composition according to claim 8 which has been dried to a solid state.

References Cited (Backward Citations)

US2443512A Cited
US3674700A Cited
US3708428A Cited
US3654168A Cited
US3709823A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-08-11 1979-02-10 1979-08-12 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-08-11 1983-02-10 1983-08-12 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-08-11 1987-02-10 1987-08-12 $7700.00 Window Closed / Lapsed

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