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US3899333A Expired / Lapsed US ⏱️ 0.0 years remaining

Photosensitive composition containing TiO{HD 2 {B having a particle size of about 25 millimicrons and the use thereof in physical development

Assignee: Northrop Grumman Guidance and Electronics Co Inc
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Filing: 1973-02-27
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Granted: 1975-08-12
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Expires: 1993-02-27
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Abstract

Abstract An improvement is disclosed in a data storage medium comprising a substrate having a radiation sensitive coating thereon consisting essentially of particulate titanium dioxide dispersed in a binder and developable after exposure by a physical developer. The specific improvement comprises the use of a particulate titanium dioxide having an average particle size of about 25 millimicrons.

Inventors

  • 👤 Elliot Berman
  • 👤 Carl F W Ekman

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 19:54
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/705; Y; Y10; Y10S; Y10S430/00; Y10S430/148

Claims Analysis

Total Claims: 17
Claim 1
Independent Claim 85 words
IN A DATA STORAGE MEDIUM COMPRISING A SUBSTRATE AND A RADIATION SENSITIVE COATING THEREON, SAID COATING CONSISTING ESSENTIALLY OF PARTICULATE TITANIUM DIOXIDE DISPERSED IN A BINDER, SAID MEDIUM BEING SUITABLE FOR USE IN A PROCESS WHEREIN SAID MEDIUM IS EXPOSED IMAGEWISE AND CONTACTED WITH A PHYSICAL DEVELOPER COMPRISING A SOLUTION OF METAL IONS AND A REDUCING AGENT FOR SAID METAL IONS TO PRODUCE A VISIBLE IMAGE IN SAID MEDIUM, THE IMPROVEMENT WHEREIN SAID PARTICULATE TITANIUM DIOXIDE HAS AN AVERAGE PARTICLE SIZE OF ABOUT 25 MILLIMICRONS.
Claim 2
Dependent Claim 85 words
IN A DATA STORAGE MEDIUM COMPRISING A SUBSTRATE AND A RADIATION SENSITIVE COATING THEREON, SAID COATING CONSISTING ESSENTIALLY OF PARTICULATE TITANIUM DIOXIDE DISPERSED IN A BINDER, SAID MEDIUM BEING SUITABLE FOR USE IN A PROCESS WHEREIN SAID MEDIUM IS EXPOSED IMAGEWISE AND CONTACTED WITH A PHYSICAL DEVELOPER COMPRISING A SOLUTION OF METAL IONS AND A REDUCING AGENT FOR SAID METAL IONS TO PRODUCE A VISIBLE IMAGE IN SAID MEDIUM, THE IMPROVEMENT WHEREIN SAID PARTICULATE TITANIUM DIOXIDE HAS AN AVERAGE PARTICLE SIZE OF ABOUT 25 MILLIMICRONS.
Claim 3
Dependent Claim 13 words
Improvement as in claim 1 wherein said substrate is transmissive of visible light.
Claim 4
Dependent Claim 12 words
Improvement as in claim 1 wherein said medium includes a dye sensitizer.
Claim 5
Dependent Claim 12 words
Improvement as in claim 1 wherein said metal ions are silver ions.
Claim 6
Dependent Claim 40 words
Improvement as in claim 1 wherein said coating was formed by applying an aqueous dispersion of titanium dioxide to said substrate, said aqueous dispersion comprising an aqueous suspending liquid, said particulate titanium dioxide, a dispersing agent and an organic binder.
Claim 7
Dependent Claim 153 words
A pellucid data storage medium suitable for projection viewing after development of an image therein by means of contacting the imagewise exposed medium with a redox developer composition comprising a solution of metals ions, said medium comprising A light transmissive substrate and a radiation sensitive coating thereon said coating being no more than about 10 mils thick and consisting essentially of a binder and dispersed therein, a particles of titanium dioxide having an average particle size less than 100 millimicrons, the ratio of said solid binder being from about 8 parts by weight of titanium dioxide to 1 part by weight binder solids to about 1 part by weight titanium dioxide to about 4 parts by weight binder solids and the coating weight being less than about 20 pounds of coating per 3,000 square feet of substrate, the improvement wherein said titanium dioxide has an average particle size of of about 25 millimicrons.
Claim 8
Dependent Claim 153 words
A pellucid data storage medium suitable for projection viewing after development of an image therein by means of contacting the imagewise exposed medium with a redox developer composition comprising a solution of metals ions, said medium comprising A light transmissive substrate and a radiation sensitive coating thereon said coating being no more than about 10 mils thick and consisting essentially of a binder and dispersed therein, a particles of titanium dioxide having an average particle size less than 100 millimicrons, the ratio of said solid binder being from about 8 parts by weight of titanium dioxide to 1 part by weight binder solids to about 1 part by weight titanium dioxide to about 4 parts by weight binder solids and the coating weight being less than about 20 pounds of coating per 3,000 square feet of substrate, the improvement wherein said titanium dioxide has an average particle size of of about 25 millimicrons.
Claim 9
Dependent Claim 16 words
Medium as in claim 6 wherein the titanium dioxide is produced by pyrolosis of titanium tetrachloride.
Claim 10
Dependent Claim 56 words
In a process of recording an image pattern of activating radiation by imagewise exposing and contacting with a physical developer comprising a solution of metal ions and a reducing agent for said metal ions a data storage medium comprising titanium dioxide, the improvement wherein the titanium dioxide has an average particle size of about 25 millimicrons.
Claim 11
Dependent Claim 56 words
In a process of recording an image pattern of activating radiation by imagewise exposing and contacting with a physical developer comprising a solution of metal ions and a reducing agent for said metal ions a data storage medium comprising titanium dioxide, the improvement wherein the titanium dioxide has an average particle size of about 25 millimicrons.
Claim 12
Dependent Claim 12 words
Improvement as in claim 8 wherein said metal ions are silver ions.
Claim 13
Dependent Claim 15 words
Improvement as in claim 8 wherein said titanium dioxide is dispersed in an organic binder.
Claim 14
Dependent Claim 35 words
Improvement as in claim 8 wherein said data storage medium is formed by coating a substrate with an aqueous dispersion comprising an aqueous suspending liquid, said titanium dioxide, a dispersing agent, and an organic binder.
Claim 15
Dependent Claim 123 words
IN A PROCESS OF RECORDING AN IMAGE PATTERN OF ACTINIC LIGHT BY EXPOSING TO AN IMAGE PATTERN OF ACTINIC LIGHT A DATA STORAGE MEDIUM COMPRISING A PARTICULATE TITANIUM DIOXIDE IN AN ORGANIC BINDER WHICH TITANIUM DIOXIDE BECOMES REVERSIBLY ACTIVATED BY SUCH EXPOSURE AND THEREBY CAPABLE OF CAUSING CHEMICAL REACTIONS AT PORTIONS OF SAID MEDIUM CORRESPONDING TO SAID IMAGE PATTERN OF ACTINIC LIGHT AND THEN APPLYING TO AT LEAST REVERSIBLY ACTIVATED PORTIONS OF SAID MEDIUM A PHYSICAL DEVELOPER COMPRISING A SOLUTION OF METAL IONS AND A REDUCING AGENT FOR SAID METAL IONS WHICH FORMS METAL IMAGES SOLELY ON CONTACT WITH AT LEAST ACTIVATED PORTIONS OF SAID DATA STORAGE MEDIUM, THE IMPROVEMENT WHEREIN THE TITANIUM DIOXIDE HAS AN AVERAGE PARTICLE SIZE OF ABOUT 25 MILLIMICRONS.
Claim 16
Dependent Claim 123 words
IN A PROCESS OF RECORDING AN IMAGE PATTERN OF ACTINIC LIGHT BY EXPOSING TO AN IMAGE PATTERN OF ACTINIC LIGHT A DATA STORAGE MEDIUM COMPRISING A PARTICULATE TITANIUM DIOXIDE IN AN ORGANIC BINDER WHICH TITANIUM DIOXIDE BECOMES REVERSIBLY ACTIVATED BY SUCH EXPOSURE AND THEREBY CAPABLE OF CAUSING CHEMICAL REACTIONS AT PORTIONS OF SAID MEDIUM CORRESPONDING TO SAID IMAGE PATTERN OF ACTINIC LIGHT AND THEN APPLYING TO AT LEAST REVERSIBLY ACTIVATED PORTIONS OF SAID MEDIUM A PHYSICAL DEVELOPER COMPRISING A SOLUTION OF METAL IONS AND A REDUCING AGENT FOR SAID METAL IONS WHICH FORMS METAL IMAGES SOLELY ON CONTACT WITH AT LEAST ACTIVATED PORTIONS OF SAID DATA STORAGE MEDIUM, THE IMPROVEMENT WHEREIN THE TITANIUM DIOXIDE HAS AN AVERAGE PARTICLE SIZE OF ABOUT 25 MILLIMICRONS.
Claim 17
Dependent Claim 12 words
Improvement as in claim 12 wherein said metal ions are silver ions.

References Cited (Backward Citations)

US2886434A Cited
US3198632A Cited
US3214284A Cited
US3360341A Cited
US3197307A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-08-11 1979-02-10 1979-08-12 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-08-11 1983-02-10 1983-08-12 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-08-11 1987-02-10 1987-08-12 $7700.00 Window Closed / Lapsed

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