Patent US2887716A successfully refreshed from Google Patents.
Patent US3895166A successfully refreshed from Google Patents.
US3895166A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Bonded reinforced structures using amine resins
Assignee: WR Grace and Co
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Filing: 1973-02-13
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Granted: 1975-07-15
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Expires: 1993-02-13
Abstract
Abstract The invention disclosed is for integral reinforced structures of elastomeric materials using curable amine resin compositions derived from particular polyamine epichlorohydrin adducts. The amine resin compositions are highly effective for bonding reinforcing assemblies with an elastomeric material into an integral product.
Inventors
- 👤 Louis L Wood
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 05:12
CPC Classifications
D; D21; D21H; D21H17/00; D21H17/20; D21H17/33; D21H17/46; D21H17/54; D21H17/57; C; C08; C08G; C08G18/00; C08G18/06; C08G18/08; C08G18/10; C08G18/28; C08G18/30; C08G18/32; C08G18/3225; C08G18/3253; C08G18/3256; C08G18/70; C08G18/72; C08G18/83; D06; D06M; D06M15/00; D06M15/19; D06M15/37; D06M15/564; Y; Y10; Y10S; Y10S156/00; Y10S156/91; Y10T; Y10T156/00; Y10T156/10; Y10T156/1089; Y10T156/109; Y10T428/00; Y10T428/249921; Y10T428/249924; Y10T428/24994; Y10T428/29; Y10T428/2913; Y10T428/2933; Y10T428/2938; Y10T428/294; Y10T428/2942; Y10T428/2947; Y10T428/296; Y10T428/2964; Y10T428/2965; Y10T428/2967; Y10T428/2969
Claims Analysis
Total Claims: 5
Claim 1
Independent Claim
232 words
IN AN INTERGAL ELASTOMERIC COMPOSITE REINFORCED STRUCTURE WHEREIN A FILAMENTARY REINFORCEMENT ASSEMBLY IS ADHESIVELY SECURED TO AND WITHIN AN ELASTOMERIC MATRIX STRUCTURE BY AN ADHESIVE, THE IMPROVEMENT WHICH CONSISTS ESSENTIALLY OF AN ADHESIVE CONSISTING ESSENTIALLY OF THE COMBINATION OF RESORCINOL - FORMALDEHYDE - LATEX ADHESIVE DIP AND AN AQUEOUS SOLUTION OF POLYMIDE - POLYAMINE - EPICHLORHYDRIN ADDUCT, SAID POLYAMIDE - POLYAMINE BEING FORMED BY REACTION OF A POLYAMINE HAVING AT LEAST THREE AMINO GROUPS PER MOLECULE AND A SATURATED ALIPHATIC DICARBOXYLIC ACID CONTAINING 3 TO 10 CARBON ATOMS AT A REACTION TEMPERATURE OF ABOUT 110*C TO ABOUT 250*C THE AMOUNT OF SAID SATURATED ALIPHATIC DICARBOXYLIC ACID BEING SUFFICIENT TO REACT WITH AT LEAST TWO AMINE GROUPS OF THE POLYAMINE, THE POLYAMIDE - POLYAMINE BEING FURTHER REACTED WITH EPICHLOROHYDRIN AT A TEMPERATURE FROM ABOUT 25*C, TO ABOUT 110*C IN AN AQUEOUS SOLUTION AND AT A PH OF 7.5 TO 9.5, THE AMOUNT OF EPICHLOROHYDRIN BEING ABOUT 0.5 MOLE TO ABOUT 1.8 MOLE OF EPICHLOROHYDRIN PER MOLE POLYAMIDE, THE SOLUTION OF POLYAMIDE - POLYAMINE - EPCHLOROHYDRIN BEING ADJUSTED TO A SOLID CONTENT OF LESS THAN ABOUT 60% TO ABOUT 10 % AND A PH OF ABOUT 3 TO ABOUT 8, SAID ADHESIVE BEING APPLIED TO THE FILAMENTARY REINFORCEMENT PRIOR TO BONDING WITHIN THE ELASTOMERIC MATRIX, AND WHEREIN THE FILAMENTARY REINFORCEMENT ASSEMBLY IS SELECTED FROM THE GROUP CONSISTING OF GLASS METAL, RAYON, POLYESTER AND POLYAMIDE.
Claim 2
Dependent Claim
232 words
IN AN INTERGAL ELASTOMERIC COMPOSITE REINFORCED STRUCTURE WHEREIN A FILAMENTARY REINFORCEMENT ASSEMBLY IS ADHESIVELY SECURED TO AND WITHIN AN ELASTOMERIC MATRIX STRUCTURE BY AN ADHESIVE, THE IMPROVEMENT WHICH CONSISTS ESSENTIALLY OF AN ADHESIVE CONSISTING ESSENTIALLY OF THE COMBINATION OF RESORCINOL - FORMALDEHYDE - LATEX ADHESIVE DIP AND AN AQUEOUS SOLUTION OF POLYMIDE - POLYAMINE - EPICHLORHYDRIN ADDUCT, SAID POLYAMIDE - POLYAMINE BEING FORMED BY REACTION OF A POLYAMINE HAVING AT LEAST THREE AMINO GROUPS PER MOLECULE AND A SATURATED ALIPHATIC DICARBOXYLIC ACID CONTAINING 3 TO 10 CARBON ATOMS AT A REACTION TEMPERATURE OF ABOUT 110*C TO ABOUT 250*C THE AMOUNT OF SAID SATURATED ALIPHATIC DICARBOXYLIC ACID BEING SUFFICIENT TO REACT WITH AT LEAST TWO AMINE GROUPS OF THE POLYAMINE, THE POLYAMIDE - POLYAMINE BEING FURTHER REACTED WITH EPICHLOROHYDRIN AT A TEMPERATURE FROM ABOUT 25*C, TO ABOUT 110*C IN AN AQUEOUS SOLUTION AND AT A PH OF 7.5 TO 9.5, THE AMOUNT OF EPICHLOROHYDRIN BEING ABOUT 0.5 MOLE TO ABOUT 1.8 MOLE OF EPICHLOROHYDRIN PER MOLE POLYAMIDE, THE SOLUTION OF POLYAMIDE - POLYAMINE - EPCHLOROHYDRIN BEING ADJUSTED TO A SOLID CONTENT OF LESS THAN ABOUT 60% TO ABOUT 10 % AND A PH OF ABOUT 3 TO ABOUT 8, SAID ADHESIVE BEING APPLIED TO THE FILAMENTARY REINFORCEMENT PRIOR TO BONDING WITHIN THE ELASTOMERIC MATRIX, AND WHEREIN THE FILAMENTARY REINFORCEMENT ASSEMBLY IS SELECTED FROM THE GROUP CONSISTING OF GLASS METAL, RAYON, POLYESTER AND POLYAMIDE.
Claim 3
Dependent Claim
25 words
The combination of claim 1 wherein the saturated aliphatic dicarboxylic acid is selected from the group consisting of adipic acid, suberic acid and azelaic acid.
Claim 4
Dependent Claim
56 words
The combination of claim 1 wherein the reaction temperature of dicarboxylic acid and polyamine is between about 160*C. and 210*C., the pH of the polyamide - polyamine - epichlorohydrin reaction is about 8.5 - 9.5, the adjusted pH is about 5.0 to 6.0, and the moles of epichlorohydrin to polyamide is about 0.9 to about 1.5.
Claim 5
Dependent Claim
33 words
The combination of claim 1 wherein the polyamine is selected from the group consisting of diethylene triamine, triethylene tetramine, tetraethylene pentamine, methyl bis(3-aminopropyl) amine, methyl bis(2-aminoethyl) amine, N-(2-aminoethyl) piperazine, 4,7-dimethyltriethylenetetramine and the like.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1978-07-14 | 1979-01-13 | 1979-07-15 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1982-07-14 | 1983-01-13 | 1983-07-15 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1986-07-14 | 1987-01-13 | 1987-07-15 | $7700.00 | Window Closed / Lapsed |