Patent US3894933A successfully refreshed from Google Patents.
US3894933A
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Method for producing light fuel oil
Assignee: Mobil Oil AS
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Filing: 1974-04-02
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Granted: 1975-07-15
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Expires: 1994-04-02
Abstract
Abstract A dual riser cracking operation of restricted hydrocarbon conversion is described wherein an intermediate fuel oil product of cracking higher boiling than the desired light fuel oil product is recovered and recracked in a first riser cracking zone in the presence of freshly regenerated catalyst and catalyst separated from the gasiform product of the first riser cracking zone is used in admixture with freshly regenerated catalyst in a second riser to crack higher boiling hydrocarbon charge in the presence of heavy recycle oil product under restricted conversion conditions to desired light fuel oil product. The riser may discharge into the lower portion of a dense fluid bed of catalyst.
Inventors
- 👤 Hartley Owen
- 👤 Paul B Venuto
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 02:27
CPC Classifications
C; C10; C10G; C10G51/00; C10G51/02; C10G51/026; C10G11/00; C10G11/14; C10G11/18
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
180 words
A METHOD FOR PRODUCING LIGHT CYCLE OIL FROM HIGHER BOILING HYDROCARBON FEED MATERIALS WHICH COMPRISES, PASSING A RELATIVELY HIGH BOILING HYDROCARBON FEED MATERIAL WITH A CRACKING CATALYST OF LIMITED ACTIVITY THROUGH A FIRST CONVERSION ZONE MAINTAINED UNDER CONDITIONS TO LIMIT CONVERSION OF THE HYDROCARBON FEED TO GASOLINE AND LOWER BOILING PRODUCTS, RECOVERING A HYDROCARBON PHASE FROM SAID FIRST CONVERSION ZONE AND SEPARATING IN A FRACTIONATION ZONE SAID HYDROCARBON PHASE INTO A DESIRED LIGHT FUEL OIL PRODUCT, AN INTERMEDIATE CYCLE OIL PRODUCT AND A HIGHER BOILING CYCLE OIL PRODUCT, PASSING SAID HIGHER BOILING CYCLE OIL PRODUCT TO SAID FIRST CONVERSION ZONE, PASSING SAID INTERMEDIATE CYCLE OIL PRODUCT TO A SECOND CONVERSION ZONE FOR CONTACT WITH A CRACKING CATALYST OF LIMITED ACTIVITY UNDER LIMITED CONVERSION CONDITIONS PARTICULARLY SELECTED TO PRODUCE LIGHT FUEL OIL PRODUCT, AND RECOVERING SAID LIGHT FUEL OIL PRODUCT IN SAID FRACTIONATION ZONE, PASSING CATALYST SEPARATED FROM SAID SECOND CONVERSION ZONE TO SAID FIRST CONVERSION ZONE, AND REDUCING THE POUR POINT OF SAID LIGHT OIL PRODUCT RECOVERED FROM SAID CONVERSION OPERATIONS BY CONTACT WITH A ZSM-5 TYPE OF CRYSTALLINE ZEOLITE.
Claim 2
Independent Claim
180 words
A METHOD FOR PRODUCING LIGHT CYCLE OIL FROM HIGHER BOILING HYDROCARBON FEED MATERIALS WHICH COMPRISES, PASSING A RELATIVELY HIGH BOILING HYDROCARBON FEED MATERIAL WITH A CRACKING CATALYST OF LIMITED ACTIVITY THROUGH A FIRST CONVERSION ZONE MAINTAINED UNDER CONDITIONS TO LIMIT CONVERSION OF THE HYDROCARBON FEED TO GASOLINE AND LOWER BOILING PRODUCTS, RECOVERING A HYDROCARBON PHASE FROM SAID FIRST CONVERSION ZONE AND SEPARATING IN A FRACTIONATION ZONE SAID HYDROCARBON PHASE INTO A DESIRED LIGHT FUEL OIL PRODUCT, AN INTERMEDIATE CYCLE OIL PRODUCT AND A HIGHER BOILING CYCLE OIL PRODUCT, PASSING SAID HIGHER BOILING CYCLE OIL PRODUCT TO SAID FIRST CONVERSION ZONE, PASSING SAID INTERMEDIATE CYCLE OIL PRODUCT TO A SECOND CONVERSION ZONE FOR CONTACT WITH A CRACKING CATALYST OF LIMITED ACTIVITY UNDER LIMITED CONVERSION CONDITIONS PARTICULARLY SELECTED TO PRODUCE LIGHT FUEL OIL PRODUCT, AND RECOVERING SAID LIGHT FUEL OIL PRODUCT IN SAID FRACTIONATION ZONE, PASSING CATALYST SEPARATED FROM SAID SECOND CONVERSION ZONE TO SAID FIRST CONVERSION ZONE, AND REDUCING THE POUR POINT OF SAID LIGHT OIL PRODUCT RECOVERED FROM SAID CONVERSION OPERATIONS BY CONTACT WITH A ZSM-5 TYPE OF CRYSTALLINE ZEOLITE.
Claim 3
Dependent Claim
22 words
The method of claim 1 wherein the hydrocarbon conversion steps are restricted not to exceed about 30 volume percent in each zone.
Claim 4
Dependent Claim
27 words
The method of claim 1 wherein the activity of the catalyst employed in the conversion steps is restricted to within the range of 15 to 50 FAI.
Claim 5
Dependent Claim
17 words
The method of claim 1 wherein hot regenerated catalyst is passed to each of said conversion zones.
Claim 6
Dependent Claim
39 words
The method of claim 1 wherein each of said conversion zones comprises at least a riser conversion zone and the hydrocarbon residence time within the first conversion zone is restricted to within the range of 2 to 60 seconds.
Claim 7
Dependent Claim
55 words
The method of claim 1 wherein the catalyst of selected and limited activity is made from catalyst components selected from the group comprising amorphous silica alumina, crystalline zeolites of the faujasite type and mixtures thereof in combination with one or more of a ZSM-5 type of crystalline aluminosilicate and a mordenite type of crystalline zeolite.
Claim 8
Dependent Claim
32 words
The method of claim 1 wherein the intermediate cycle oil product of cracking used as feed in the second conversion zone boils in the range of about 550*F. up to about 800*F.
Claim 9
Dependent Claim
46 words
The method of claim 1 wherein the light fuel oil product of the hydrocarbon conversion zones boils in the range of 320*F. to about 700*F. and contact thereof with the ZSM-5 type catalyst reduces its pour point to within the range of -30* to about 15*F.
Claim 10
Dependent Claim
35 words
The method of claim 1 wherein each of said conversion zones comprises a riser conversion zone discharging into a fluid bed of catalyst before separation of a hydrocarbon phase from a catalyst phase is effected.
Claim 11
Independent Claim
212 words
A method for producing light fuel oil product of desired pour point which comprises, separating an intermediate cycle oil product of cracking higher boiling than desired fuel oil product obtained as hereinafter defined, recracking said separated intermediate cycle oil product in a first riser cracking operation in the presence of freshly regenerated catalyst of restricted activity under conditions selected to restrict conversion thereof to less than 30 vol. percent, separating the product of said recracking operation to recover a hydrocarbon phase from a first catalyst phase and passing said hydrocarbon phase to a product fractionation zone, passing catalyst from said first catalyst phase to a second riser conversion zone, passing freshly regenerated catalyst along with fresh gas oil feed and heavy cycle oil product of cracking to said second riser cracking zone, effecting cracking of the hydrocarbon feed passed to said second riser cracking operation under conversion condition restricted to less than about 40 vol. percent, separating the product of said second riser cracking operation into a hydrocarbon phase and a second catalyst phase, passing the hydrocarbon phase to said product fractionation zone, and reducing the pour point of a light cycle oil separated from the product of cracking operation by contacting a ZSM-5 type of crystalline zeolite under selected conversion conditions.
Claim 12
Independent Claim
212 words
A method for producing light fuel oil product of desired pour point which comprises, separating an intermediate cycle oil product of cracking higher boiling than desired fuel oil product obtained as hereinafter defined, recracking said separated intermediate cycle oil product in a first riser cracking operation in the presence of freshly regenerated catalyst of restricted activity under conditions selected to restrict conversion thereof to less than 30 vol. percent, separating the product of said recracking operation to recover a hydrocarbon phase from a first catalyst phase and passing said hydrocarbon phase to a product fractionation zone, passing catalyst from said first catalyst phase to a second riser conversion zone, passing freshly regenerated catalyst along with fresh gas oil feed and heavy cycle oil product of cracking to said second riser cracking zone, effecting cracking of the hydrocarbon feed passed to said second riser cracking operation under conversion condition restricted to less than about 40 vol. percent, separating the product of said second riser cracking operation into a hydrocarbon phase and a second catalyst phase, passing the hydrocarbon phase to said product fractionation zone, and reducing the pour point of a light cycle oil separated from the product of cracking operation by contacting a ZSM-5 type of crystalline zeolite under selected conversion conditions.
References Cited (Backward Citations)
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US3700585A
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US3689402A
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US3849291A
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US3801493A
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US3847793A
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1978-07-14 | 1979-01-13 | 1979-07-15 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1982-07-14 | 1983-01-13 | 1983-07-15 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1986-07-14 | 1987-01-13 | 1987-07-15 | $7700.00 | Window Closed / Lapsed |