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US3894868A Expired / Lapsed US ⏱️ 0.0 years remaining

Electron transport binder structure

Assignee: Xerox Corp
•
Filing: 1973-03-16
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Granted: 1975-07-15
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Expires: 1993-03-16
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Abstract

Abstract A photosensitive member having a photoreceptor binder layer comprising photoconductive particles dispersed in an electronically active matrix material. The photoconductor comprises a material which is capable of photogenerating and injecting electrons into the surrounding active binder which comprises a material capable of supporting electron injection and transport. The active matrix material has the additional property of being substantially transparent to radiation in the particular wavelength region of xerographic use thereby enabling use of a relatively small amount of photoconductor material in the binder layer. The structure may be imaged in the conventional xerographic mode which usually includes charging, exposure to light and development.

Inventors

  • 👤 Paul J Regensburger

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 20:30
CPC Classifications
G; G03; G03G; G03G5/00; G03G5/02; G03G5/04; G03G5/09

Claims Analysis

Total Claims: 20
Claim 1
Independent Claim 136 words
AN ELECTROPHOTOGRAPHIC PLATE HAVING A PHOTORECEPTOR BINDER LAYER COMPRISING PHOTOSENSITIVE PARTICLES DISPERSED IN AN UNORIENTED FASHION IN AN ELECTRONICALLY ACTIVE ORGANIC MATRIX BINDER IN AN AMOUNT OF FROM ABOUT 0.1 TO 5 PERCENT BY VOLUME OF SAID BINER, SAID PHOTOSENTIVITE PARTICLES EXHIBITING THE CAPABILITY OF PHOTO-EXCITED ELECTRON GENERATION AND INJECTION INTO THE SORROUNDING ACTIVE MATRIX BINDER, SAID ACTIVE ORGANIC MATRIX BINDER BING CAPABLE OF SUPPORTING THE INJECTION OF PHOTO-EXCITED ELECTRONS FROM SAID PHOTOCONDUCTIVE PARTICLES AND TRANSPORTING SAID ELECTRONS THROUGH SAID ACTIVE MATRIX MATERIAL, WHEREIN SAID MATRIX COMPRISES AT LEAST ONE MATERIAL SELECTED FROM THE GROUP CONSISTING OF PHTHALIC ANHYDRIDE, TETRACHLOROPHTHALIC ANHYDRIDE, BENZUL. MELLITIC ANHYDRIDE, S-TRICYANOBENZENE, PRICYL CHLORIDE, 2,4-DINITROCHLOROBENEZENE, 2,4-DINITROBROMOBENZENE, 4-NITROBEPHENYL 4,4-DINITROPHENYL, 2,4,5 TRINITTOANISOLE, TRICHLOROTRINITROBENZENE, TRINITRO-O-TOULENE, 4,6 DICHLORO - 1,2 DINITROBENZENE 4,6-DIBROMO, -1,3 DINITROBENZENE, P-DINITROBENZEN, ANIL, BROMOANIL, 2,4,7 TRINITRO-9-FLUORENONE, 2,4,5,7 TETRANITROFLUORENONE, TRINITROANTHRACENE, DINITROACRIDENE, TETRANITOR PYRENE AND DINITROANTHRAQUINONE.
Claim 2
Dependent Claim 136 words
AN ELECTROPHOTOGRAPHIC PLATE HAVING A PHOTORECEPTOR BINDER LAYER COMPRISING PHOTOSENSITIVE PARTICLES DISPERSED IN AN UNORIENTED FASHION IN AN ELECTRONICALLY ACTIVE ORGANIC MATRIX BINDER IN AN AMOUNT OF FROM ABOUT 0.1 TO 5 PERCENT BY VOLUME OF SAID BINER, SAID PHOTOSENTIVITE PARTICLES EXHIBITING THE CAPABILITY OF PHOTO-EXCITED ELECTRON GENERATION AND INJECTION INTO THE SORROUNDING ACTIVE MATRIX BINDER, SAID ACTIVE ORGANIC MATRIX BINDER BING CAPABLE OF SUPPORTING THE INJECTION OF PHOTO-EXCITED ELECTRONS FROM SAID PHOTOCONDUCTIVE PARTICLES AND TRANSPORTING SAID ELECTRONS THROUGH SAID ACTIVE MATRIX MATERIAL, WHEREIN SAID MATRIX COMPRISES AT LEAST ONE MATERIAL SELECTED FROM THE GROUP CONSISTING OF PHTHALIC ANHYDRIDE, TETRACHLOROPHTHALIC ANHYDRIDE, BENZUL. MELLITIC ANHYDRIDE, S-TRICYANOBENZENE, PRICYL CHLORIDE, 2,4-DINITROCHLOROBENEZENE, 2,4-DINITROBROMOBENZENE, 4-NITROBEPHENYL 4,4-DINITROPHENYL, 2,4,5 TRINITTOANISOLE, TRICHLOROTRINITROBENZENE, TRINITRO-O-TOULENE, 4,6 DICHLORO - 1,2 DINITROBENZENE 4,6-DIBROMO, -1,3 DINITROBENZENE, P-DINITROBENZEN, ANIL, BROMOANIL, 2,4,7 TRINITRO-9-FLUORENONE, 2,4,5,7 TETRANITROFLUORENONE, TRINITROANTHRACENE, DINITROACRIDENE, TETRANITOR PYRENE AND DINITROANTHRAQUINONE.
Claim 3
Dependent Claim 16 words
The electrophotographic plate of claim 1 in which the photosensitive particles comprise an inorganic crystalline material.
Claim 4
Dependent Claim 14 words
The electrophotographic plate of claim 1 in which the photosensitive particles comprise phthalocyanine pigments.
Claim 5
Dependent Claim 29 words
The electrophotographic plate of claim 3 in which the phthalocyanine pigment is selected from the group consisting of the X and Beta forms of metal-free phthalocyanine and metal phthalocyanines.
Claim 6
Dependent Claim 124 words
An electrophotographic plate having a photoreceptor binder layer comprising photosensitive particles dispersed in an electronically active organic matrix binder in an unoriented fashion in an amount of from about 0.1 to 5 percent by volume of said binder, said photosensitive particles exhibiting the capability of photo-excited electron generation and injection in the surrounding active matrix binder, said active organic matrix binder being capable of supporting the injection of photo-excited electrons from said photoconductive particles and transporting said electrons through said active matrix binder wherein said active matrix comprises at least one material selected from the group consisting of 2,4,7 trinitro-9-fluorenone, 2,4,5,7 tetranitrofluorenone, trinitroanthracene, dinitroacridene, tetracyanopyrene, and dinitroanthraquinone, said material being substantially transparent in the wavelength region of from about 4,200 to 8,000 Angstrom Units.
Claim 7
Dependent Claim 124 words
An electrophotographic plate having a photoreceptor binder layer comprising photosensitive particles dispersed in an electronically active organic matrix binder in an unoriented fashion in an amount of from about 0.1 to 5 percent by volume of said binder, said photosensitive particles exhibiting the capability of photo-excited electron generation and injection in the surrounding active matrix binder, said active organic matrix binder being capable of supporting the injection of photo-excited electrons from said photoconductive particles and transporting said electrons through said active matrix binder wherein said active matrix comprises at least one material selected from the group consisting of 2,4,7 trinitro-9-fluorenone, 2,4,5,7 tetranitrofluorenone, trinitroanthracene, dinitroacridene, tetracyanopyrene, and dinitroanthraquinone, said material being substantially transparent in the wavelength region of from about 4,200 to 8,000 Angstrom Units.
Claim 8
Dependent Claim 16 words
The electrophotographic plate of claim 5 in which the photosensitive particles comprises an inorganic crstalline material.
Claim 9
Dependent Claim 14 words
The electrophotographic plate of claim 5 in which the photosensitive particles comprise phthalocyanine pigments.
Claim 10
Dependent Claim 29 words
The electrophotographic plate of claim 7 in which the phthalocyanine pigment is selected from the group consisting of the X and Beta forms of metal-free phthalocyanine and metal phthalocyanines.
Claim 11
Dependent Claim 18 words
The electrophotographic plate in claim 5 in which the photoreceptor layer is supported on an electrically conductive substrate.
Claim 12
Independent Claim 190 words
A method of imaging which comprises: a. providing an electrophotographic plate having a photoreceptor binder layer photoconductive particles dispersed in an electronically active organic matrix binder in an unoriented fashion and in an amount of between about 0.1 and 5 percent by volume of said binder, said photoconductive particles being capable of photogenerating electrons and injecting them into the surrounding active matrix material, said active matrix material being capable of supporting the injection of photo-excited electrons and transporting said electrons through said active material, wherein said active matrix comprises at least one material selected from the group consisting of phthalic anhydride, tetrachlorophthalic anhydride, benzil, mellitic anhydride, s-tricyanobenzene, picryl chloride, 2,4-dinitrochlorobenzene, 2,4-dinitrobromobenzene, 4-nitrobiphenyl, 4,4-dinitrobiphenyl, 2,4,6-trinitroanisole, trichlorotrinitrobenzene, trinitro-0-toulene, 4,6 dichloro, 1,3 dinitrobenzene, 4,6 dibromo, 1,3 dinitrobenzene, p-dinitrobenzene, chloranil, bromoanil, 2,4,7 trinitro-9-fluorenone, 2,4,5,7 tetranitrofluorenone, trinitroanthracene, dinitroanidene, tetracyanopyrene, and dinitroanthraquinone, b. uniforming charging said plate, and c. exposing said plate to a source of radiation to which the active layer is substantially transparent and non-absorbing whereby injection and transport of photogenerated electrons from said photosensitive particles occurs through said active transport binder to form a latent electrostatic image on the surface of said plate.
Claim 13
Independent Claim 190 words
A method of imaging which comprises: a. providing an electrophotographic plate having a photoreceptor binder layer photoconductive particles dispersed in an electronically active organic matrix binder in an unoriented fashion and in an amount of between about 0.1 and 5 percent by volume of said binder, said photoconductive particles being capable of photogenerating electrons and injecting them into the surrounding active matrix material, said active matrix material being capable of supporting the injection of photo-excited electrons and transporting said electrons through said active material, wherein said active matrix comprises at least one material selected from the group consisting of phthalic anhydride, tetrachlorophthalic anhydride, benzil, mellitic anhydride, s-tricyanobenzene, picryl chloride, 2,4-dinitrochlorobenzene, 2,4-dinitrobromobenzene, 4-nitrobiphenyl, 4,4-dinitrobiphenyl, 2,4,6-trinitroanisole, trichlorotrinitrobenzene, trinitro-0-toulene, 4,6 dichloro, 1,3 dinitrobenzene, 4,6 dibromo, 1,3 dinitrobenzene, p-dinitrobenzene, chloranil, bromoanil, 2,4,7 trinitro-9-fluorenone, 2,4,5,7 tetranitrofluorenone, trinitroanthracene, dinitroanidene, tetracyanopyrene, and dinitroanthraquinone, b. uniforming charging said plate, and c. exposing said plate to a source of radiation to which the active layer is substantially transparent and non-absorbing whereby injection and transport of photogenerated electrons from said photosensitive particles occurs through said active transport binder to form a latent electrostatic image on the surface of said plate.
Claim 14
Dependent Claim 16 words
The method of claim 10 which further includes developing said latent image to make it visible.
Claim 15
Dependent Claim 20 words
The method of claim 10 in which The substrate is substantially transparent and exposure is carried out through said substrate.
Claim 16
Dependent Claim 19 words
The electrophotographic plate of claim 1 in which the photosensitive particles comprise a phthalocyanine pigment in a 2,4,7-trinitro-9-fluorenone binder.
Claim 17
Dependent Claim 12 words
The plate of claim 13 wherein the phthalocyanine pigment is copper phthalocyanine.
Claim 18
Dependent Claim 18 words
The electrophotographic plate of claim 1 in which the photosensitive particles comprise trigonal selenium in a 2,4,7-trinitro-9-fluorenone binder.
Claim 19
Dependent Claim 21 words
The electrophotographic plate of claim 1 in which the photosensitive particles comprise dinitroacridine and beta-form metal-free phthalocyanine in a 2,4,7-trinitro-9-fluorenone binder.
Claim 20
Dependent Claim 19 words
The electrophotographic plate of claim 1 in which the photosensitive particles comprise X-form metal-free phthalocyanine in a 2,4,7-trinitro-9-fluorenone binder.

References Cited (Backward Citations)

US3113022A Cited
US3162532A Cited
US3159483A Cited
US3594163A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-07-14 1979-01-13 1979-07-15 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-07-14 1983-01-13 1983-07-15 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-07-14 1987-01-13 1987-07-15 $7700.00 Window Closed / Lapsed

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