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US3893906A Expired / Lapsed US ⏱️ 0.0 years remaining

Production of low pour point gas oil and high octane number gasoline

Assignee: Mobil Oil AS
•
Filing: 1974-03-21
•
Granted: 1975-07-08
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Expires: 1994-03-21
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Abstract

Abstract A process for the simultaneous dewaxing of high pour point gas oil and upgrading of an aromatic containing naphtha by contact of a mixture of the gas oil and naphtha with a high silica to alumina ratio synthetic aluminosilicate zeolite catalyst, which is derived from a zeolite which was synthesized with an organic cation, incorporating a hydrogenation dehydrogenation component, and a hydrogen atmosphere at about 500* to 1,000*F followed by distillation of the product in order to recover a lower pour point gas oil fraction and a higher octane gasoline fraction.

Inventors

  • 👤 William Everett Garwood
  • 👤 John J Wise

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 14:22
CPC Classifications
C; C10; C10G; C10G35/00; C10G35/04; C10G35/06; C10G35/095; C10G2400/00; C10G2400/02; C10G2400/06

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 184 words
A PROCESS OF UPGRADING PETROLEUM FRACTIONS WHICH COMPRISES CONTACTING AN ADMIXTURE, CONTAINING AT LEAST 10% BENZENE, OF GASOLINE BOILING RANGE FRACTION HAVING A BOILING RANGE OF AT LEAST ABOUT C6 TO 239*C WHICH CONTAINS AT LEAST ABOUT 20 WEIGHT PERCENT AROMATICS AND A GAS OIL FRACTION HAVING AN END POINT UP TO ABOUT 850*F AND A POUR POINT OF AT LEAST ABOUT +20*F WITH A CATALYST COMPRISING A ZEOLITE CONSISTING ESSENTIALLY OF A SYNTHETIC CRYSTALLINE ALUMINOSILICATE ZEOLITE DERIVED IN AN ORGANIC CATION CONTAINING FORM, HAVING A SILICA TO ALUMINA RATIO OF AT LEAST ABOUT 12 TO 1 AND HAVING A HYDROGENATION/DEHYDROGENATION COMPONENT, CONVERTING SAID ADMIXTURE IN THE PRESENCE OF HYDROGEN AT A SPACE VELOCITY OF ABOUT 0.5 TO 20 WHSV, AT A TEMPERATURE OF ABOUT 500* TO 1,000*F AND AT A HYDROGEN TO HYDROCARBON RATIO OF ABOUT 1 TO 20 TO 1 TO A PRODUCT COMPRISING A GAS OIL FRACTION HAVING A LOWER POUR POINT, A GASOLINE FRACTION HAVING A HIGHER OCTANE AND A LIGHT GAS FRACTION, AND RESOLVING SAID PRODUCT INTO SAID GAS OIL FRACTION, SAID GASOLINE FRACTION AND SAID LIGHT GAS FRACTION.
Claim 2
Dependent Claim 184 words
A PROCESS OF UPGRADING PETROLEUM FRACTIONS WHICH COMPRISES CONTACTING AN ADMIXTURE, CONTAINING AT LEAST 10% BENZENE, OF GASOLINE BOILING RANGE FRACTION HAVING A BOILING RANGE OF AT LEAST ABOUT C6 TO 239*C WHICH CONTAINS AT LEAST ABOUT 20 WEIGHT PERCENT AROMATICS AND A GAS OIL FRACTION HAVING AN END POINT UP TO ABOUT 850*F AND A POUR POINT OF AT LEAST ABOUT +20*F WITH A CATALYST COMPRISING A ZEOLITE CONSISTING ESSENTIALLY OF A SYNTHETIC CRYSTALLINE ALUMINOSILICATE ZEOLITE DERIVED IN AN ORGANIC CATION CONTAINING FORM, HAVING A SILICA TO ALUMINA RATIO OF AT LEAST ABOUT 12 TO 1 AND HAVING A HYDROGENATION/DEHYDROGENATION COMPONENT, CONVERTING SAID ADMIXTURE IN THE PRESENCE OF HYDROGEN AT A SPACE VELOCITY OF ABOUT 0.5 TO 20 WHSV, AT A TEMPERATURE OF ABOUT 500* TO 1,000*F AND AT A HYDROGEN TO HYDROCARBON RATIO OF ABOUT 1 TO 20 TO 1 TO A PRODUCT COMPRISING A GAS OIL FRACTION HAVING A LOWER POUR POINT, A GASOLINE FRACTION HAVING A HIGHER OCTANE AND A LIGHT GAS FRACTION, AND RESOLVING SAID PRODUCT INTO SAID GAS OIL FRACTION, SAID GASOLINE FRACTION AND SAID LIGHT GAS FRACTION.
Claim 3
Dependent Claim 15 words
A process as claimed in claim 1 wherein said gasoline boiling range fraction is reformate.
Claim 4
Dependent Claim 19 words
A process as claimed in claim 1 wherein said gas oil fraction has an end point of about 850*F.
Claim 5
Dependent Claim 21 words
A process as claimed in claim 1 wherein said gas oil fraction has a pour point of about 80* to 100*F.
Claim 6
Dependent Claim 15 words
A process as claimed in claim 1 wherein said catalyst comprises a ZSM-5 type zeolite.
Claim 7
Dependent Claim 17 words
A process as claimed in claim 1 operated at a pressure of about 1 to 70 atmospheres.
Claim 8
Dependent Claim 28 words
A process as claimed in claim 1 wherein said admixture is a wide cut petroleum fraction having a boiling range in the range of about C5 to 850*F.
Claim 9
Dependent Claim 15 words
A process as claimed in claim 7 wherein said admixture is a virgin petroleum fraction.
Claim 10
Dependent Claim 24 words
A process as claimed in claim 2 wherein said gas oil is a virgin petroleum fraction having a boiling range up to about 850*F.
Claim 11
Dependent Claim 36 words
A process as claimed in claim 1 wherein said gas oil is a lubricant containing material and wherein said product is resolved to additionally contain a purified lube oil fraction boiling in the range of 650*F+.
Claim 12
Dependent Claim 25 words
A process as claimed in claim 10 wherein said lube oil containing fraction is Foot''s oil and wherein the gasoline boiling range fraction comprises benzene.

References Cited (Backward Citations)

US3597493A Cited
US3700585A Cited
US3804746A Cited
US3758402A Cited
US3729409A Cited
US3753891A Cited
US3767568A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-07-07 1979-01-06 1979-07-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-07-07 1983-01-06 1983-07-08 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-07-07 1987-01-06 1987-07-08 $7700.00 Window Closed / Lapsed

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