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US3893902A Expired / Lapsed US ⏱️ 0.0 years remaining

Electrolytic sea water process

Assignee: Diamond Shamrock Corp
•
Filing: 1973-04-12
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Granted: 1975-07-08
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Expires: 1993-04-12
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Abstract

Abstract A cell and a method of operation are disclosed whereby sea water may be electrolyzed to form an aqueous hypochlorite solution with reduced formation of interfering deposits on the electrodes. The cell design and method of operation ensure suspension of particulate matter in the electrolyte and also allow intermittent backwashing to remove any accumulations of contaminants.

Inventors

  • 👤 Richard E Loftfield
  • 👤 John E Bennett
  • 👤 John E Cinke

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 20:56
CPC Classifications
C; C02; C02F; C02F1/00; C02F1/46; C02F1/461; C02F1/467; C02F1/4672; C02F1/4674; C25; C25B; C25B1/00; C25B1/01; C25B1/24; C25B1/26; C25B9/00; C25B9/17; C02F1/46104; C02F1/46109; C02F2001/46133

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 117 words
IN THE METHOD OF OPERATING A CELL FOR THE ELECTROLYSIS OF SEA WATER TO PRODUCE HYPOCHLORITE, WHICH CELL COMPRISES AN ENCLOSED CONTAINING A PLURALITY OF VERTICALLY DISPOSED ELECTRODES IN AN ALTERNATE ARRAY OF ANODE AND CATHODES, THE IMPROVEMENT WHICH COMPRISES REDUCING THE FORMATION OF UNDESIRABLE DEPOSITS ON THE ELECTRODES BY: A. INTRODUCING SEA WATER TO THE CELL AT A POINT BELOW THE ELECTRODES THROUGH A SERIES OF ORIFICES, SUBSTANTUALLY CORRESPONDING IN NUMBER AND LOCATION TO AT LEAST THE CATHODES, THE DIRECTION OF THE ORIFICES BEING SUCH THAT THE SEA WATER FIRST IMPINGES PRIMARILY ON NONELECTRODE SURFACES IMMEDIATELY SUBJACENT THE ELECTRODES, AND THE SEA WATER VELOCITY THROUGH THE ORIFICES BEING BETWEEEN 5 AND 25 FEET PER SECOND, AND
Claim 2
Dependent Claim 117 words
IN THE METHOD OF OPERATING A CELL FOR THE ELECTROLYSIS OF SEA WATER TO PRODUCE HYPOCHLORITE, WHICH CELL COMPRISES AN ENCLOSED CONTAINING A PLURALITY OF VERTICALLY DISPOSED ELECTRODES IN AN ALTERNATE ARRAY OF ANODE AND CATHODES, THE IMPROVEMENT WHICH COMPRISES REDUCING THE FORMATION OF UNDESIRABLE DEPOSITS ON THE ELECTRODES BY: A. INTRODUCING SEA WATER TO THE CELL AT A POINT BELOW THE ELECTRODES THROUGH A SERIES OF ORIFICES, SUBSTANTUALLY CORRESPONDING IN NUMBER AND LOCATION TO AT LEAST THE CATHODES, THE DIRECTION OF THE ORIFICES BEING SUCH THAT THE SEA WATER FIRST IMPINGES PRIMARILY ON NONELECTRODE SURFACES IMMEDIATELY SUBJACENT THE ELECTRODES, AND THE SEA WATER VELOCITY THROUGH THE ORIFICES BEING BETWEEEN 5 AND 25 FEET PER SECOND, AND
Claim 3
Dependent Claim 28 words
A method as in claim 1 wherein the sea water velocity through the cell in Step (B) is within the range of 1.5 to 24 inches per second.
Claim 4
Dependent Claim 178 words
In the method of operating a cell for the electrolysis of sea water to produce hypochlorite, which cell comprises an enclosure containing a plurality of vertically disposed electrodes in an alternate array of anodes and cathodes, the improvement which comprises reducing the formation of undesirable deposits on the electrodes by: A. introducing sea water to the cell at a point below the electrodes through a series of orifices, substantially corresponding in number and location to at least the cathodes, the direction of the orifices being such that the sea water first impinges primarily on nonelectrode surfaces immediately subjacent the electrodes, and the sea water velocity through the orifices being between 5 and 25 feet per second; B. maintaining a sea water velocity through the cell during electrolysis sufficient to at least suspend substantially all particulate matter present; C. intermittently halting electrolysis and flushing the cell with sea water introduced through a like series of orifices at a point above the electrodes; D. removing a slurry of particulate material from the bottom of the cell; and E. resuming electrolysis.
Claim 5
Dependent Claim 178 words
In the method of operating a cell for the electrolysis of sea water to produce hypochlorite, which cell comprises an enclosure containing a plurality of vertically disposed electrodes in an alternate array of anodes and cathodes, the improvement which comprises reducing the formation of undesirable deposits on the electrodes by: A. introducing sea water to the cell at a point below the electrodes through a series of orifices, substantially corresponding in number and location to at least the cathodes, the direction of the orifices being such that the sea water first impinges primarily on nonelectrode surfaces immediately subjacent the electrodes, and the sea water velocity through the orifices being between 5 and 25 feet per second; B. maintaining a sea water velocity through the cell during electrolysis sufficient to at least suspend substantially all particulate matter present; C. intermittently halting electrolysis and flushing the cell with sea water introduced through a like series of orifices at a point above the electrodes; D. removing a slurry of particulate material from the bottom of the cell; and E. resuming electrolysis.
Claim 6
Dependent Claim 28 words
A method as in claim 3 wherein the direction of the orifices in Step (C) is such that the sea water is directed onto and between the electrodes.

References Cited (Backward Citations)

US2959532A Cited
US3282823A Cited
US3558466A Cited
US3682809A Cited
US3766045A Cited
US3718540A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-07-07 1979-01-06 1979-07-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-07-07 1983-01-06 1983-07-08 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-07-07 1987-01-06 1987-07-08 $7700.00 Window Closed / Lapsed

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