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US3890434A
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Hair and antiseptic formulations containing adducts of bis-(2-pyridyl-1-oxide) disulfide
Assignee: Olin Corp
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Filing: 1974-03-28
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Granted: 1975-06-17
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Expires: 1994-03-28
Abstract
Abstract This invention pertains to adducts of bis-(2-pyridyl-1-oxide) disulfide with alkaline earth metal salts in hair and antiseptic formulations.
Inventors
- 👤 Guenther K Weisse
- 👤 Jr Haywood Hooks
- 👤 Gene A Hyde
- 👤 Samuel I Trotz
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-08 02:09
CPC Classifications
A; A61; A61Q; A61Q5/00; A61Q5/02; A61K; A61K8/00; A61K8/18; A61K8/30; A61K8/49; A61K8/4906; A61K8/4933; Y; Y10; Y10S; Y10S424/00; Y10S424/02; Y10S424/04
Claims Analysis
Total Claims: 32
Claim 1
Independent Claim
110 words
A clear hair shampoo composition comprising from about 10 to about 85% by weight of a synthetic detergent, from 0 to about 10% by weight of a foam builder, from 0 to about 5% by weight of a viscosity control agent, from about 0.001 to about 10% by weight of an adduct having the empirical formula: (C5H4NOS)2MYt or hydrate thereof, wherein M is an alkaline earth metal selected from the group consisting of calcium, magnesium, barium and strontium; Y is an anion selected from the group consisting of halide, sulfate, nitrate, chlorate and acetate and t is 1 or 2 and from 0 to about 89% by weight of water.
Claim 2
Dependent Claim
110 words
A clear hair shampoo composition comprising from about 10 to about 85% by weight of a synthetic detergent, from 0 to about 10% by weight of a foam builder, from 0 to about 5% by weight of a viscosity control agent, from about 0.001 to about 10% by weight of an adduct having the empirical formula: (C5H4NOS)2MYt or hydrate thereof, wherein M is an alkaline earth metal selected from the group consisting of calcium, magnesium, barium and strontium; Y is an anion selected from the group consisting of halide, sulfate, nitrate, chlorate and acetate and t is 1 or 2 and from 0 to about 89% by weight of water.
Claim 3
Dependent Claim
16 words
The composition of claim 1 wherein M is calcium, Y is chloride and t is 2.
Claim 4
Dependent Claim
16 words
The composition of claim 1 wherein M is magnesium, Y is sulfate and t is 1.
Claim 5
Dependent Claim
12 words
The composition of claim 1 wherein said adduct has the formula: (C5H4NOS)2MgSO4.3H2O.
Claim 6
Dependent Claim
21 words
The composition of claim 1 wherein the amount of said adduct is from about 0.1 to about 3 percent by weight.
Claim 7
Dependent Claim
21 words
The composition of claim 1 wherein the amount of said adduct is from about 0.25 to about 2 percent by weight.
Claim 8
Dependent Claim
19 words
The composition of claim 6 wherein said adduct is selected from the group consisting of (C5H4NOS)2CaCl2, (C5H4NOS)2MgSO4 and (C5H4NOS)2MgSO4.3H2O.
Claim 9
Dependent Claim
44 words
A CLEAR HAIR DRESSING COMPOSITION COMPRISING FROM ABOUT 10 TO ABOUT 50% BY WEIGHT OF A GROOMING AGENT, FROM 0 TO ABOUT 40% BY WEIGHT OF A SOLUBILIZING AGENT, FROM ABOUT, 0.0001 TO ABOUT 10% BY WEIGHT OF AN ADDUCT HAVING THE EMPIRICAL FORMULA:
Claim 10
Dependent Claim
44 words
A CLEAR HAIR DRESSING COMPOSITION COMPRISING FROM ABOUT 10 TO ABOUT 50% BY WEIGHT OF A GROOMING AGENT, FROM 0 TO ABOUT 40% BY WEIGHT OF A SOLUBILIZING AGENT, FROM ABOUT, 0.0001 TO ABOUT 10% BY WEIGHT OF AN ADDUCT HAVING THE EMPIRICAL FORMULA:
Claim 11
Dependent Claim
16 words
The composition of claim 8 wherein M is calcium, Y is chloride and t is 2.
Claim 12
Dependent Claim
16 words
The composition of claim 8 wherein M is magnesium, Y is sulfate and t is 1.
Claim 13
Dependent Claim
12 words
The composition of claim 8 wherein said adduct has the formula: (C5H4NOS)2MgSO4.3H2O.
Claim 14
Dependent Claim
20 words
The composition of claim 8 wherein the amount of said adduct is from about 0.1 to about 3 percent weight.
Claim 15
Dependent Claim
21 words
The composition of claim 8 wherein the amount of said adduct is from about 0.25 to about 2 percent by weight.
Claim 16
Dependent Claim
19 words
The composition of claim 13 wherein said adDuct is selected from the group consisting of (C5H4NOS)2CaCl2, (C5H4NOS)2MgSO4 and (C5H4NOS)2MgSO4.3H2O.
Claim 17
Dependent Claim
66 words
A clear antiseptic and disinfectant composition comprising a mixture of water and an effective amount of an adduct having the empirical formula: (C5H4NOS)2MYt or hydrate thereof, wherein M is an alkaline earth metal selected from the group consisting of calcium, magnesium, barium and strontium; Y is an anion selected from the group consisting of halide, sulfate, nitrate, chlorate and acetate and t is 1 or 2.
Claim 18
Dependent Claim
66 words
A clear antiseptic and disinfectant composition comprising a mixture of water and an effective amount of an adduct having the empirical formula: (C5H4NOS)2MYt or hydrate thereof, wherein M is an alkaline earth metal selected from the group consisting of calcium, magnesium, barium and strontium; Y is an anion selected from the group consisting of halide, sulfate, nitrate, chlorate and acetate and t is 1 or 2.
Claim 19
Dependent Claim
16 words
The composition of claim 15 wherein M is calcium, Y is chloride and t is 2.
Claim 20
Dependent Claim
16 words
The composition of claim 15 wherein M is magnesium, Y is sulfate and t is 1.
Claim 21
Dependent Claim
21 words
The composition of claim 15 wherein the amount of said adduct is from about 0.1 to about 3 percent by weight.
Claim 22
Dependent Claim
21 words
The composition of claim 15 wherein the amount of said adduct is from about 0.25 to about 2 percent by weight.
Claim 23
Dependent Claim
19 words
The composition of claim 19 wherein said adduct is selected from the group consisting of (C5H4NOS)2CaCl2, (C5H4NOS)2MgSO4 and (C5H4NOS)2MgSO4.3H2O.
Claim 24
Dependent Claim
132 words
A clear hair shampoo composition comprising from about 10 to about 85% by weight of a synthetic detergent, from 0 to about 10% by weight of a foam builder, from 0 to about 5% of a viscosity control agent, from 0 to about 89 percent by weight water and from about 0.1 to about 15% by weight of a mixture of bis-(2-pyridyl-1-oxide) disulfide and an alkaline earth metal salt of the formula: MYt wherein M is an alkaline earth metal selected from the group consisting of calcium, magnesium, barium and strontium; Y is an anion selected from the group consisting of halide, sulfate, nitrate, chlorate and acetate and t is 1 or 2 wherein said mixture contains from about 0.4 to about 85 percent by weight of said alkaline earth metal salt.
Claim 25
Dependent Claim
132 words
A clear hair shampoo composition comprising from about 10 to about 85% by weight of a synthetic detergent, from 0 to about 10% by weight of a foam builder, from 0 to about 5% of a viscosity control agent, from 0 to about 89 percent by weight water and from about 0.1 to about 15% by weight of a mixture of bis-(2-pyridyl-1-oxide) disulfide and an alkaline earth metal salt of the formula: MYt wherein M is an alkaline earth metal selected from the group consisting of calcium, magnesium, barium and strontium; Y is an anion selected from the group consisting of halide, sulfate, nitrate, chlorate and acetate and t is 1 or 2 wherein said mixture contains from about 0.4 to about 85 percent by weight of said alkaline earth metal salt.
Claim 26
Dependent Claim
37 words
The composition of claim 21 wherein the amount of said mixture is from about 0.3 to about 2 percent by weight and said alkaline earth metal salt is selected from the group consisting of CaCl2 and MgSO4.
Claim 27
Dependent Claim
121 words
A clear hair dressing composition comprising from about 10 to about 50% by weight of a grooming agent, from 0 to about 40% by weight of a solubilizing agent, from 0 to about 89 percent by weight water and from about 0.1 to about 15% by weight of a mixture of bis-(2-pyridyl-1-oxide) disulfide and an alkaline earth metal salt of the formula: MYt wherein M is an alkaline earth metal selected from the group consisting of calcium, magnesium, barium and strontium; Y is an anion selected from the group consisting of halide, sulfate, nitrate, chlorate and acetate and t is 1 or 2 wherein said mixture contains from about 0.4 to about 85% by weight of said alkaline earth metal salt.
Claim 28
Dependent Claim
121 words
A clear hair dressing composition comprising from about 10 to about 50% by weight of a grooming agent, from 0 to about 40% by weight of a solubilizing agent, from 0 to about 89 percent by weight water and from about 0.1 to about 15% by weight of a mixture of bis-(2-pyridyl-1-oxide) disulfide and an alkaline earth metal salt of the formula: MYt wherein M is an alkaline earth metal selected from the group consisting of calcium, magnesium, barium and strontium; Y is an anion selected from the group consisting of halide, sulfate, nitrate, chlorate and acetate and t is 1 or 2 wherein said mixture contains from about 0.4 to about 85% by weight of said alkaline earth metal salt.
Claim 29
Dependent Claim
37 words
The composition of claim 23 wherein the amount of said mixture is from about 0.3 to about 2 percent by weight and said alkaline earth metal salt is selected from the group consisting of CaCl2 and MgSO4.
Claim 30
Dependent Claim
95 words
A clear antiseptic and disinfectant composition comprising a mixture of water and from about 0.1 to about 15 percent by weight of a mixture of bis-(2-pyridyl-1-oxide) disulfide and an alkaline earth metal salt of the formula: MYt wherein M is an alkaline earth metal selected from the group consisting of calcium, magnesium, barium and strontium; Y is an anion selected from the group consisting of halide, sulfate, nitrate, chlorate and acetate and t is 1 or 2 wherein said mixture contains from about 0.4 to about 85% by weight of said alkaline earth metal salt.
Claim 31
Dependent Claim
95 words
A clear antiseptic and disinfectant composition comprising a mixture of water and from about 0.1 to about 15 percent by weight of a mixture of bis-(2-pyridyl-1-oxide) disulfide and an alkaline earth metal salt of the formula: MYt wherein M is an alkaline earth metal selected from the group consisting of calcium, magnesium, barium and strontium; Y is an anion selected from the group consisting of halide, sulfate, nitrate, chlorate and acetate and t is 1 or 2 wherein said mixture contains from about 0.4 to about 85% by weight of said alkaline earth metal salt.
Claim 32
Dependent Claim
37 words
The composition of claim 25 wherein the amount of said mixture is from about 0.3 to about 2 percent by weight and said alkaline earth metal salt is selected from the group consisting of CaCl2 and MgSO4.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1978-06-16 | 1978-12-16 | 1979-06-17 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1982-06-16 | 1982-12-16 | 1983-06-17 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1986-06-16 | 1986-12-16 | 1987-06-17 | $7700.00 | Window Closed / Lapsed |