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US3890263A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of producing a thermoplastic composition comprising essentially bitumen and an elastomer, and product thus obtained

Assignee: Siplast SA
•
Filing: 1974-05-08
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Granted: 1975-06-17
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Expires: 1994-05-08
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Abstract

Abstract This invention provides a method of producing an improved thermoplastic composition comprising essentially a bitumen of petroleum origin and an elastomer. Possibly, a mineral filler is used, and a dissolving intermediary is used. The basic principle of the method is derived from the fact that high-ethylene EPR elastomers can easily be dispersed in a bitumen medium, provided that these elastomers are mixed up beforehand with a solid dissolving intermediary capable of reducing their cohesion, said dissolving intermediary consisting of one or a plurality of saturated or unsaturated polyolefins.

Inventors

  • 👤 Jean-Yves Meynard

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 20:55
CPC Classifications
C; C08; C08L; C08L23/00; C08L23/02; C08L23/16; C08J; C08J3/00; C08J3/005; C08L95/00

Claims Analysis

Total Claims: 32
Claim 1
Independent Claim 333 words
A METHOD OF PRODUCING A THERMOPLASTIC COMPOSITION COMPRISING BITUMEN, AN ELASTOMER AND POSSIBLY A MINERAL FILLER, BY USING A DISSOLVING INTERMEDIARY, WHEREN THERE IS USED AD AN ELASTOMER A RANDOM ETHYLENE-PROPYLENE COPOLYMER REFERRED TO AS EPR INCLUDING THE RANDOM ETHYLENE-PROPYLENEDIENE TERPOLYMER REFERRED TO AS EPDM OF WHICH THE DIENE COMPONENT IS SELECTED FROM THE GROUP CONSISTING OF HEXADIENE(1.4). DICYCLOPENTADIENE, 5-METHYLENE-NORBORNENE-(2), 5ETHYLENE-NORBORNENE-(2) AND 1-METHYL-CYCLOOTADIENE, SAID EPR COPOLYMER CONSISTING OF 54 TO 77% BY WEIGHT OF ETHYLENE, 0 TO 5& BY WEIGHT OF DIENE AND THE BALANCE TO 100% BY WEIGHT OF PROPYLENE, A SOLID DISSOLVING INTERMEDIARY IS USED WHICH CONSISTS OF AT LEAST ONE POLYOLEFIN, SATURATED OR UNSATURATED, LINEAR OR BRANCHED, HAVING A MEAN MOLECULAR WEIGHT WITHIN THE RANGE OF 2,0000 TO 500,000 AND SELECTED FROM THE GROUP CONSISTING OF POLYETHYLENE, ISOTACTIC POLYPROPYLENE AND ATACTI POLYPROPYLENE, SAID ELASTOMER IS MIXED UP WITH SAID DISSOLVING INTERMEDIARY IN THE PROPORTIONS OF 99 TO 50% BY WEIGHT OF SAID ELASTOMER AND 1 TO 50% BY WEIGHT OF SAID DISSOLVING INTERMEDIARY, AT A TEMPERATURE AT LEAST EQUAL TO THE SOFTENING TEMPERATURE OF SAID DISSOVING INTERMEDIARY, WHICH RANGES FROM 70* TO 150*C IN THE CASE OF POLYETHYLENES AND FROM 150* TO 160*C FOR POLYPROPYLENES, THE MIXTURE IS SUBSEQUENTLY GRANULATED TO A PARTICLES SIZE OF ABOUT 2 TO 3 MM., TO YIELD A GRANULATED ELASTOMER AND DISSOLVING INTERMEDIARY PRE-MIXTUR, WHEREAFTER SAID GRANULATED PRE-MIXTURE IS KNEADED WITH SAID BITUMEN AND SAID POSSIBLE MINERAL FILLER, IN THE PROPORTIONS OF 1 TO 15% BY WEIGHT OF SAID PRE-MIXTURE GRANULAR SUBSTANCE, 99 TO 35% BY WEIGHT OF SAID BITUMENE AND 0 TO 50% BY WEIGHT OF SAID MINERAL FILLER, PROVIDED THAT THE TOTAL OF THESE THREE COMPONENT ELEMENTS IS 100% BY WEIGHT, AT A TEMPERATURE WITHIN THE RANGE OF 180* TO 250*C, IN ORDER TO OBTAIN A FINE PARTICULATE DISPERSION OF SAID GRANULATED PRE-MIXTURE IN THE BITUME N MASS, SAID BITUMEN BEING OF PETROLEUM ORIGIN AND HAVING A PENETRATION AT 25*C OF 1 TO 500 ACCORDING TO THE FRENCH STANDARD NF T 66 004.
Claim 2
Independent Claim 333 words
A METHOD OF PRODUCING A THERMOPLASTIC COMPOSITION COMPRISING BITUMEN, AN ELASTOMER AND POSSIBLY A MINERAL FILLER, BY USING A DISSOLVING INTERMEDIARY, WHEREN THERE IS USED AD AN ELASTOMER A RANDOM ETHYLENE-PROPYLENE COPOLYMER REFERRED TO AS EPR INCLUDING THE RANDOM ETHYLENE-PROPYLENEDIENE TERPOLYMER REFERRED TO AS EPDM OF WHICH THE DIENE COMPONENT IS SELECTED FROM THE GROUP CONSISTING OF HEXADIENE(1.4). DICYCLOPENTADIENE, 5-METHYLENE-NORBORNENE-(2), 5ETHYLENE-NORBORNENE-(2) AND 1-METHYL-CYCLOOTADIENE, SAID EPR COPOLYMER CONSISTING OF 54 TO 77% BY WEIGHT OF ETHYLENE, 0 TO 5& BY WEIGHT OF DIENE AND THE BALANCE TO 100% BY WEIGHT OF PROPYLENE, A SOLID DISSOLVING INTERMEDIARY IS USED WHICH CONSISTS OF AT LEAST ONE POLYOLEFIN, SATURATED OR UNSATURATED, LINEAR OR BRANCHED, HAVING A MEAN MOLECULAR WEIGHT WITHIN THE RANGE OF 2,0000 TO 500,000 AND SELECTED FROM THE GROUP CONSISTING OF POLYETHYLENE, ISOTACTIC POLYPROPYLENE AND ATACTI POLYPROPYLENE, SAID ELASTOMER IS MIXED UP WITH SAID DISSOLVING INTERMEDIARY IN THE PROPORTIONS OF 99 TO 50% BY WEIGHT OF SAID ELASTOMER AND 1 TO 50% BY WEIGHT OF SAID DISSOLVING INTERMEDIARY, AT A TEMPERATURE AT LEAST EQUAL TO THE SOFTENING TEMPERATURE OF SAID DISSOVING INTERMEDIARY, WHICH RANGES FROM 70* TO 150*C IN THE CASE OF POLYETHYLENES AND FROM 150* TO 160*C FOR POLYPROPYLENES, THE MIXTURE IS SUBSEQUENTLY GRANULATED TO A PARTICLES SIZE OF ABOUT 2 TO 3 MM., TO YIELD A GRANULATED ELASTOMER AND DISSOLVING INTERMEDIARY PRE-MIXTUR, WHEREAFTER SAID GRANULATED PRE-MIXTURE IS KNEADED WITH SAID BITUMEN AND SAID POSSIBLE MINERAL FILLER, IN THE PROPORTIONS OF 1 TO 15% BY WEIGHT OF SAID PRE-MIXTURE GRANULAR SUBSTANCE, 99 TO 35% BY WEIGHT OF SAID BITUMENE AND 0 TO 50% BY WEIGHT OF SAID MINERAL FILLER, PROVIDED THAT THE TOTAL OF THESE THREE COMPONENT ELEMENTS IS 100% BY WEIGHT, AT A TEMPERATURE WITHIN THE RANGE OF 180* TO 250*C, IN ORDER TO OBTAIN A FINE PARTICULATE DISPERSION OF SAID GRANULATED PRE-MIXTURE IN THE BITUME N MASS, SAID BITUMEN BEING OF PETROLEUM ORIGIN AND HAVING A PENETRATION AT 25*C OF 1 TO 500 ACCORDING TO THE FRENCH STANDARD NF T 66 004.
Claim 3
Dependent Claim 25 words
A method as set forth in claim 1, wherein said used elastomer consists of an EPR copolymer containing 65 to 77% bY weight of ethylene.
Claim 4
Dependent Claim 74 words
A method as set forth in claim 2, wherein a mixture of 90% by weight of said bitumen and 10% by weight of said premixture granulated substance are kneaded at a temperature of 200*C, said elastomer being an EPDM terpolymer having a Mooney viscosity equal to 60 and consisting of 65 to 77% by weight of ethylene, not more than 5% by weight of diene and the balance to 100% by weight of propylene.
Claim 5
Dependent Claim 33 words
A method as set forth in claim 3, wherein said EPDM terpolymer consists of 73% by weight of ethylene, 3% by weight of diene, and the balance to 100% by weight of propylene.
Claim 6
Dependent Claim 29 words
A method as set forth in claim 4, wherein said pre-mixture granulated substance comprises 2 parts by weight of polyethylene for every 8 parts by weight of said EPDM.
Claim 7
Dependent Claim 30 words
A method as set forth in claim 4, wherein said pre-mixture granulated substance comprises 3 parts by weight of atactic polypropylene for every 7 parts by weight of said EPDM.
Claim 8
Dependent Claim 30 words
A method as set forth in claim 4, wherein said pre-mixture granulated substance comprises 4 parts by weight of isotactic polypropylene for every 6 parts by weight of said EPDM.
Claim 9
Dependent Claim 16 words
A method as set forth in claim 5, wherein the diene of said EPDM is hexadiene-(1.4).
Claim 10
Dependent Claim 16 words
A method as set forth in claim 6, wherein the diene of said EPDM is hexadiene-(1.4).
Claim 11
Dependent Claim 16 words
A method as set forth in claim 7, wherein the diene of said EPDM is hexadiene-(1.4).
Claim 12
Dependent Claim 26 words
A method as set forth in claim 5, wherein the diene of said EPDM is selected from the group consisting of dicyclopentadiene, 5-methylene-norbornene-(2), 5-ethylidene-norbornene-(2) and 1-methylcyclooctadiene.
Claim 13
Dependent Claim 26 words
A method as set forth in claim 6, wherein the diene of said EPDM is selected from the group consisting of dicyclopentadiene, 5-methylene-norbornene-(2), 5-ethylidene-norbornene-(2) and 1-methylcyclooctadiene.
Claim 14
Dependent Claim 26 words
A method as set forth in claim 7, wherein the diene of said EPDM is selected from the group consisting of dicyclopentadiene, 5-methylene-norbornene-(2), 5-ethylidene-norbornene-(2) and 1-methylcyclooctadiene.
Claim 15
Dependent Claim 224 words
A THERMOPOLASTIC COMPOSITION PRODUCED BY APPLYING THE METHOD SET FORTH IN CLAIM 1, CONSISTING OF 99 TO 35% BY WEIGHT OF BITUMEN OF PETROLEUM ORIGIN HAVING A PENETRATION OF 1 TO 500 AT 25*C ACCORDING TO THE FRENCH STANDARD NF T 66 004; OF 1 TO 15% BY WEIGHT OF FINE PARTICLES DISPERESED THROUGH THE MASS OF SAID BITUMEN AND CONSISTING OF A MIXTURE OF 99 TO 50% BY WEIGHT OF A RADOM ETHYLENE-PROPYLENE COPOLYMER REFERRED TO AS EPR, INCLUDING THE RADOM ETHYLENE-PROPYLENE-DIENE TERPOLYMER REFERRED TO AS EPDM, WHEREIN SAID DIENE COMPONENT ELEMENT IS SELECTED FROM THE GROUP CONSISTING OF HEXADIENE-(1.4), DICYCLOPENTADIENE, 5-METHYLEN-NORBORNENE-((2), 5-ETHYLIDENE-NORBORNENE-(2) AND 1-METHYL-CYCLOOCTADIENE, SAID EPR COPOLYMER HAVING AN ETHYLENE CONTENT OF 54 TO 77% BY WEIGHT, A DIENE CONTENT OF 0 TO 5% BY WEIGHT, AND A PROPYLENE CONTENT TO MAKE THE BALANCE TO 100% BY WEIGHT AND A MONEY VISCOSITY ML (1+4) AT 121*C OF 60 TO 70, AND 1 TO 50% BY WEIGHT OF AT LEAST ONE SATURATED OR UNSATURATED POLYOLEFIN CONTAINING OR NOT SIDE CHAINS AND HAVING A MEAN MOLECULAR WEIGHT WITHIN THE RANGE OF 2,000 TO 500,000, SAID POLYOLEFIN BEING SELECTED FROM THE GROUP CONSISTING OF POLYETHYLENE, ISOTACTIC POLYPROPYLENE AND ATACTIC POLYPROPYLENE; AND OF 0 TO 50% BY WEIGHT OF A MINERAL FILLER, PROVIDED THT THE TOTAL OF THE THREE COMPONENT ELEMENTS CORRESPONDS TO 100% BY WEIGHT.
Claim 16
Dependent Claim 23 words
A thermoplastic composition as set forth in claim 14, wherein said EPR copolymer has an ethylene content of 65 to 77% by weight.
Claim 17
Dependent Claim 67 words
A therMoplastic composition as set forth in claim 15, consisting of 90% by weight of said bitumen and 10% by weight of said fine particles, in which said EPR copolymer is an EPDM terpolymer having a Mooney viscosity of 60 and consisting of 65 to 77% by weight of ethylene, not more than 5% by weight of diene and the balance to 100% by weight of propylene.
Claim 18
Dependent Claim 33 words
A thermoplastic composition as set forth in claim 16, wherein said EPDM consists of 73% by weight of ethylene, 3% by weight of diene, and the balance to 100% by weight of propylene.
Claim 19
Dependent Claim 42 words
A thermoplastic composition as set forth in claim 17, wherein said particles consist of 2 parts by weight of polyethylene of coefficient of fluidity in the hot state 0.7 grams / 10 minutes for every 8 parts by weight of said EPDM.
Claim 20
Dependent Claim 30 words
A thermoplastic composition as set forth in claim 17, wherein said particles consist of 3 parts by weight of atactic polypropylene for every 7 parts by weight of said EPDM.
Claim 21
Dependent Claim 30 words
A thermoplastic composition as set forth in claim 17, wherein said particles consist of 4 parts by weight of isotactic polypropylene for every 6 parts by weight of said EPDM.
Claim 22
Dependent Claim 17 words
A thermoplastic composition as set forth in claim 18, wherein the diene of said EPDM is hexadiene-(1.4).
Claim 23
Dependent Claim 17 words
A thermoplastic composition as set forth in claim 19, wherein the diene of said EPDM is hexadiene-(1.4).
Claim 24
Dependent Claim 17 words
A thermoplastic composition as set forth in claim 20, wherein the diene of said EPDM is hexadiene-(1.4.).
Claim 25
Dependent Claim 27 words
A thermoplastic composition as set forth in claim 18, wherein the diene of said EPDM is selected from the group consisting of dicyclopentadiene, 5-methylene-norbornene-(2), 5-ethylidene-norbornene-(2) and 1-methyl-cyclooctadiene.
Claim 26
Dependent Claim 27 words
A thermoplastic composition as set forth in claim 19, wherein the diene of said EPDM is selected from the group consisting of dicyclopentadiene, 5-methylene-norbornene-(2), 5-ethylidene-norbornene-(2) and 1-methyl-cyclooctadiene.
Claim 27
Dependent Claim 27 words
A thermoplastic composition as set forth in claim 20, wherein the diene of said EPDM is selected from the group consisting of dicyclopentadiene, 5-methylene-norbornene-(2), 5-ethylidene-norbornene-(2) and 1-methyl-cyclooctadiene.
Claim 28
Dependent Claim 25 words
A method as set forth in claim 2, wherein said used EPR copolymer has a Mooney viscosity ML (1+4) at 121*C of 60 to 70.
Claim 29
Dependent Claim 31 words
A method as set forth in claim 1, wherein said used polyolefin is polyethylene having a coefficient of fluidity in the hot state of 0.7 grams/10 minutes to 2 grams/10 minutes.
Claim 30
Dependent Claim 31 words
A method as set forth in claim 27, wherein said used polyolefin is polyethylene having a coefficient of fluidity in the hot state of 0.7 grams/10 minutes to 2 grams/10 minutes.
Claim 31
Dependent Claim 31 words
A thermoplastic composition as set forth in claim 14, wherein said polyolefin is polyethylene having a coefficient of fluidity in the hot state of 0.7 grams/10 minutes to 2 grams/10 minutes.
Claim 32
Dependent Claim 31 words
A thermoplastic composition as set forth in claim 15, wherein said polyolefin is polyethylene having a coefficient of fluidity in the hot state of 0.7 grams/10 minutes to 2 grams/10 minutes.

References Cited (Backward Citations)

US3154508A Cited
US3790519A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-06-16 1978-12-16 1979-06-17 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-06-16 1982-12-16 1983-06-17 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-06-16 1986-12-16 1987-06-17 $7700.00 Window Closed / Lapsed

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