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US3887758A Expired / Lapsed US ⏱️ 0.0 years remaining

Oil resistant leather

Assignee: Dow Silicones Corp
•
Filing: 1974-04-19
•
Granted: 1975-06-03
•
Expires: 1994-04-19
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Abstract

Abstract Oil resistant leather articles are prepared by impregnating the leather with a room temperature curing organosilicon resin made by mixing (1) 1 to 65 percent by weight of a hydroxyl endblocked dimethylpolysiloxane, (2) from 15 to 70 percent by weight of a hydroxyl containing phenylsiloxane resin and (3) 5 to 65 percent by weight of a silane of the formula RSiX3 and thereafter allowing the mixture to cure. The leather is particularly useful for work shoes around areas where the shoes are exposed to solvents, oils or hydraulic fluids.

Inventors

  • 👤 Anthony J Butler
  • 👤 Daniel R Pail

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 18:23
CPC Classifications
C; C14; C14C; C14C9/00; Y; Y10; Y10T; Y10T428/00; Y10T428/4935

Claims Analysis

Total Claims: 19
Claim 1
Independent Claim 28 words
A METHOD OF PREPARING AN OIL RESISTANT LEATHER WHICH COMPRISES IMPREGNATING THE LEATHER WITH AN ORGANOSILICON RESIN CURABLE AT ROOM TEMPERATURE, SAID RESIN HAVING BEEN PREPARED BY MIXING
Claim 2
Independent Claim 28 words
A METHOD OF PREPARING AN OIL RESISTANT LEATHER WHICH COMPRISES IMPREGNATING THE LEATHER WITH AN ORGANOSILICON RESIN CURABLE AT ROOM TEMPERATURE, SAID RESIN HAVING BEEN PREPARED BY MIXING
Claim 3
Dependent Claim 36 words
FROM 1 TO 65 PERCENT BY WEIGHT OF A DIMETHYLPOLYSILOXANE CONTAINING SILICON-BONDED HYDROXYL GROUPS HAVING ON THE AVERAGE FROM 5 TO 50 SILOXANE UNITS PER MOLECULE WHICH CAN CONTAIN UP TO 10 MOL PERCENT MONOMETHYLSILOXANE UNITS.
Claim 4
Dependent Claim 36 words
FROM 1 TO 65 PERCENT BY WEIGHT OF A DIMETHYLPOLYSILOXANE CONTAINING SILICON-BONDED HYDROXYL GROUPS HAVING ON THE AVERAGE FROM 5 TO 50 SILOXANE UNITS PER MOLECULE WHICH CAN CONTAIN UP TO 10 MOL PERCENT MONOMETHYLSILOXANE UNITS.
Claim 5
Independent Claim 28 words
A method of preparing an oil resistant leather which comprises impregnating the leather with an organosilicon resin curable at room temperature, said resin having been prepared by mixing
Claim 6
Independent Claim 28 words
A method of preparing an oil resistant leather which comprises impregnating the leather with an organosilicon resin curable at room temperature, said resin having been prepared by mixing
Claim 7
Dependent Claim 36 words
from 1 to 65 percent by weight of a dimethylpolysiloxane containing silicon-bonded hydroxyl groups having on the average from 5 to 50 siloxane units per molecule which can contain up to 10 mol percent monomethylsiloxane units,
Claim 8
Dependent Claim 36 words
from 1 to 65 percent by weight of a dimethylpolysiloxane containing silicon-bonded hydroxyl groups having on the average from 5 to 50 siloxane units per molecule which can contain up to 10 mol percent monomethylsiloxane units,
Claim 9
Dependent Claim 48 words
from 15 to 70 percent by weight of a siloxane resin containing silicon-bonded hydroxyl groups having a phenyl-to-silicon ratio of at least 0.3, a hydrocarbon radical to silicon ratio of 1 to 1.5 in which the hydrocarbon radicals are of the group consisting of phenyl and methyl, and
Claim 10
Dependent Claim 48 words
from 15 to 70 percent by weight of a siloxane resin containing silicon-bonded hydroxyl groups having a phenyl-to-silicon ratio of at least 0.3, a hydrocarbon radical to silicon ratio of 1 to 1.5 in which the hydrocarbon radicals are of the group consisting of phenyl and methyl, and
Claim 11
Dependent Claim 46 words
FROM 15 TO 70 PERCENT OF A SILOXANE RESIN CONTAINING SILICON-BONDED HYDROXYL GROUPS HAVING A PHENYLTO-SILICON RATIO OF AT LEAST 0.3, A HYDROCARBON RADICAL TO SILICON RATIO OF 1 TO 1.5 IN WHICH THE HYDROCARBON RADICALS ARE OF THE GROUP CONSISTING OF PHENYL AND METHYL, AND
Claim 12
Dependent Claim 46 words
FROM 15 TO 70 PERCENT OF A SILOXANE RESIN CONTAINING SILICON-BONDED HYDROXYL GROUPS HAVING A PHENYLTO-SILICON RATIO OF AT LEAST 0.3, A HYDROCARBON RADICAL TO SILICON RATIO OF 1 TO 1.5 IN WHICH THE HYDROCARBON RADICALS ARE OF THE GROUP CONSISTING OF PHENYL AND METHYL, AND
Claim 13
Dependent Claim 10 words
A leather article prepared by the method of claim 1.
Claim 14
Dependent Claim 15 words
A leather article prepared by the method of claim 1 in which X is acetoxy.
Claim 15
Dependent Claim 54 words
FROM 5 TO 65 PERCENT BY WEIGHT OF A SILANE OF THE FORMULA RSIX3 IN WHICH X IS ACETOXY, LOWER ALKOXY, -ON=CR''2, -NR''2, -ONR''2 OR -NR''(O=CR'') IN WHICH R IS AN ALIPHATIC HYDROCARBON RADICAL OF 1 TO 2 CARBON ATOMS AND R'' IS A LOWER ALKYL RADICAL AND THEREAFTER ALLOWING THE RESIN TO CURE.
Claim 16
Dependent Claim 54 words
FROM 5 TO 65 PERCENT BY WEIGHT OF A SILANE OF THE FORMULA RSIX3 IN WHICH X IS ACETOXY, LOWER ALKOXY, -ON=CR''2, -NR''2, -ONR''2 OR -NR''(O=CR'') IN WHICH R IS AN ALIPHATIC HYDROCARBON RADICAL OF 1 TO 2 CARBON ATOMS AND R'' IS A LOWER ALKYL RADICAL AND THEREAFTER ALLOWING THE RESIN TO CURE.
Claim 17
Dependent Claim 56 words
from 5 to 65 percent by weight of a silane of the formula RSiX3 in wHich X is acetoxy, lower alkoxy, -ON CR''2, -NR''2, -ONR''2 or -NR''(O CR'') in which R is an aliphatic hydrocarbon radical of 1 to 2 carbon atoms and R'' is a lower alkyl radical and thereafter allowing the resin to cure.
Claim 18
Dependent Claim 56 words
from 5 to 65 percent by weight of a silane of the formula RSiX3 in wHich X is acetoxy, lower alkoxy, -ON CR''2, -NR''2, -ONR''2 or -NR''(O CR'') in which R is an aliphatic hydrocarbon radical of 1 to 2 carbon atoms and R'' is a lower alkyl radical and thereafter allowing the resin to cure.
Claim 19
Dependent Claim 16 words
A leather article prepared by the method of claim 1 in which X is -ON CCH3(C2H5).

References Cited (Backward Citations)

US2678893A Cited
US2924587A Cited
US3364160A Cited
US3419514A Cited
US3576905A Cited
US3636134A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-06-02 1978-12-02 1979-06-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-06-02 1982-12-02 1983-06-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-06-02 1986-12-02 1987-06-03 $7700.00 Window Closed / Lapsed

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