Patent US3887755A successfully refreshed from Google Patents.
← Back to Patent Explorer
US3887755A Expired / Lapsed US ⏱️ 0.0 years remaining

Laminating adhesives

Assignee: BASF Corp
•
Filing: 1973-09-11
•
Granted: 1975-06-03
•
Expires: 1993-09-11
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract Adhesives for laminating saran film or saran coated surfaces to polypropylene or polyethylene films or surfaces are disclosed. The adhesives comprise solutions of a mixture of a terpene urethane resin with certain thermoplastic polyether polyurethanes.

Inventors

  • 👤 Joseph Zamer

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 13:57
CPC Classifications
B; B32; B32B; B32B27/00; B32B27/06; B32B27/08; C; C08; C08G; C08G18/00; C08G18/06; C08G18/08; C08G18/0804; C08G18/0809; C08G18/0814; C09; C09J; C09J175/00; C09J175/04; C09J175/12; B32B2323/00; B32B2323/04; B32B2323/10; B32B2375/00; C08G2170/00; C08G2170/80; C08L; C08L2666/00; C08L2666/02; C08L2666/14; Y; Y10; Y10S; Y10S528/00; Y10S528/905; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31551; Y10T428/31573; Y10T428/3158; Y10T428/31587; Y10T428/31855; Y10T428/31909; Y10T428/31913

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 251 words
A LAMINATE OF THE GROUP CONSISTING OF SARAN ADHESIVELY BONDED TO SARAN, SARAN ADHERED TO TREATED POLYETHYLENE OR TREATED POLYPROPYLENE, AND TREATED POLYETHYLENE ADHERED TO TREATED POLYETHYLENE WHEREIN THE ADHESIVE IS A MIXTURE OF A MINOR AMOUNT OF A TERPENE URETHANE RESIN WHICH IS THE REACTION PRODUCT OF A TERPENE ALCOHOL WITH A POLYISOCYANATE, AND A MAJOR AMOUNT OF A WATER SOLUBLE SALT OF A SUBSTANTIALLY LINEAR THERMOPLASTIC POLYURETHANE CONTAINING 0.5 TO 2.5% BY WEIGHT OF NITROGEN DERIVED FROM TERITARY AMINE GROUPS, AND FROM 2 TO 8% OF NITROGEN DERIVED FROM ISOCYANATE GROUPS, SAID POLYURETHANE BEING PREPARED BY (A) REACTING AN EXCESS OF AN ISOCYANATE WITH A MIXTURE OF DIOLS CONSISTING OF POLYETHER DIOLS HAVING A MOLECULAR WEIGHT OF FROM 425 TO 4.000 AND TERTIARY AMINE DIOLS SELECTED FORM THE GROUP CONSISTING OF N-PHENYL DIALKANOL AMINE AND N-LOWER ALKYL DIALKANOL AMINES TO OBTAIN A REACTION PRODUCT HAVING FREE ISOCYANATED GROUPS GREATER THAN 0.1 MILLIEQUIVALENTS OF NCO PER GRAM OF SOLUTION AT 50% SOLIDS, (B) CHAIN EXTENDING THE REACTION PRODUCT WITH A CHAIN EXTENDER SELECTED FROM THE GROUP CONSISTING OF ALKANOL AMINES AND ALKYLENE DIAMINES TO OBTAIIN A CHAIN EXTENDED POLYURETHANE POLYMER CONTAINING FROM 0.07 TO 0.1 MILLIEQUIVALENTS OF NCO PER GRAM OF 50% SOLUTION, (C) REACTING THE FREE ISOCYANATE GROUPS WITH A MATERIAL SELECTED FROM THE GROUP CONSISTING OF WATER MMISCIBLE ALCOHOLS, WATER MISCIBLE ACIDS AND WATER, AN AMOUNT OF A WATER MISCIBLE ACID BEING ADDED SUFFICIENT TO FORM THE ACIDS SALTS OF THE TETIARY AMINE GROUPS PRESENT ON THE POLYURETHANE.
Claim 2
Dependent Claim 251 words
A LAMINATE OF THE GROUP CONSISTING OF SARAN ADHESIVELY BONDED TO SARAN, SARAN ADHERED TO TREATED POLYETHYLENE OR TREATED POLYPROPYLENE, AND TREATED POLYETHYLENE ADHERED TO TREATED POLYETHYLENE WHEREIN THE ADHESIVE IS A MIXTURE OF A MINOR AMOUNT OF A TERPENE URETHANE RESIN WHICH IS THE REACTION PRODUCT OF A TERPENE ALCOHOL WITH A POLYISOCYANATE, AND A MAJOR AMOUNT OF A WATER SOLUBLE SALT OF A SUBSTANTIALLY LINEAR THERMOPLASTIC POLYURETHANE CONTAINING 0.5 TO 2.5% BY WEIGHT OF NITROGEN DERIVED FROM TERITARY AMINE GROUPS, AND FROM 2 TO 8% OF NITROGEN DERIVED FROM ISOCYANATE GROUPS, SAID POLYURETHANE BEING PREPARED BY (A) REACTING AN EXCESS OF AN ISOCYANATE WITH A MIXTURE OF DIOLS CONSISTING OF POLYETHER DIOLS HAVING A MOLECULAR WEIGHT OF FROM 425 TO 4.000 AND TERTIARY AMINE DIOLS SELECTED FORM THE GROUP CONSISTING OF N-PHENYL DIALKANOL AMINE AND N-LOWER ALKYL DIALKANOL AMINES TO OBTAIN A REACTION PRODUCT HAVING FREE ISOCYANATED GROUPS GREATER THAN 0.1 MILLIEQUIVALENTS OF NCO PER GRAM OF SOLUTION AT 50% SOLIDS, (B) CHAIN EXTENDING THE REACTION PRODUCT WITH A CHAIN EXTENDER SELECTED FROM THE GROUP CONSISTING OF ALKANOL AMINES AND ALKYLENE DIAMINES TO OBTAIIN A CHAIN EXTENDED POLYURETHANE POLYMER CONTAINING FROM 0.07 TO 0.1 MILLIEQUIVALENTS OF NCO PER GRAM OF 50% SOLUTION, (C) REACTING THE FREE ISOCYANATE GROUPS WITH A MATERIAL SELECTED FROM THE GROUP CONSISTING OF WATER MMISCIBLE ALCOHOLS, WATER MISCIBLE ACIDS AND WATER, AN AMOUNT OF A WATER MISCIBLE ACID BEING ADDED SUFFICIENT TO FORM THE ACIDS SALTS OF THE TETIARY AMINE GROUPS PRESENT ON THE POLYURETHANE.
Claim 3
Dependent Claim 251 words
A laminate of the group consisting of saran adhesively bonded to saran, saran adhered to treated polyethylene or treated polypropylene, and treated polyethylene adhered to treated polyethylene wherein the adhesive is a mixture of a minor amount of a terpene urethane resin which is the reaction product of a terpene alcohol with a polyisocyanate, and a major amount of a water soluble salt of a substantially linear thermoplastic polyurethane containing 0.5 to 2.5% by weight of nitrogen derived from tertiary amine groups and from 2 to 8% of nitrogen derived from isocyanate groups, said polyurethane being prepared by (a) reacting an excess of an isocyanate with a mixture of diols consisting of polyether diols having a molecular weight of from 425 to 4,000 and tertiary amine diols selected from the group consisting of N-phenyl dialkanol amine and N-lower alkyl dialkanol amines to obtain a reaction product having free isocyanate groups greater than 0.1 milliequivalents of NCO per gram of solution at 50% solids, (b) chain extending the reaction product with a chain extender selected from the group consisting of alkanol amines and alkylene diamines to obtain a chain extended polyurethane polymer containing from 0.07 to 0.1 milliequivalents of NCO per gram of 50% solution, (c) reacting the free isocyanate groups with a material selected from the group consisting of water miscible alcohols, water miscible acids and water, an amount of a water miscible acid being added sufficient to form the acid salts of the tertiary amine groups present on the polyurethane.
Claim 4
Dependent Claim 251 words
A laminate of the group consisting of saran adhesively bonded to saran, saran adhered to treated polyethylene or treated polypropylene, and treated polyethylene adhered to treated polyethylene wherein the adhesive is a mixture of a minor amount of a terpene urethane resin which is the reaction product of a terpene alcohol with a polyisocyanate, and a major amount of a water soluble salt of a substantially linear thermoplastic polyurethane containing 0.5 to 2.5% by weight of nitrogen derived from tertiary amine groups and from 2 to 8% of nitrogen derived from isocyanate groups, said polyurethane being prepared by (a) reacting an excess of an isocyanate with a mixture of diols consisting of polyether diols having a molecular weight of from 425 to 4,000 and tertiary amine diols selected from the group consisting of N-phenyl dialkanol amine and N-lower alkyl dialkanol amines to obtain a reaction product having free isocyanate groups greater than 0.1 milliequivalents of NCO per gram of solution at 50% solids, (b) chain extending the reaction product with a chain extender selected from the group consisting of alkanol amines and alkylene diamines to obtain a chain extended polyurethane polymer containing from 0.07 to 0.1 milliequivalents of NCO per gram of 50% solution, (c) reacting the free isocyanate groups with a material selected from the group consisting of water miscible alcohols, water miscible acids and water, an amount of a water miscible acid being added sufficient to form the acid salts of the tertiary amine groups present on the polyurethane.
Claim 5
Dependent Claim 31 words
A laminate as in claim 1 wherein the polyether diol is polypropylene glycol, the N-lower alkyl dialkanol amine is N-methyl diethanol amine and the acid is a non-toxic organic carboxylic acid.
Claim 6
Dependent Claim 28 words
A laminate as in claim 1 wherein the polyurethane is reacted with an excess of a water soluble alcohol and the acid is a non-toxic organic carboxylic acid.
Claim 7
Dependent Claim 13 words
A laminate as in claim 3 wherein the isocyanate reactant is a isopropanol.
Claim 8
Dependent Claim 33 words
A laminate as in claim 1 wherein the percentage of isocyanate derived nitrogen of the polyether polyurethane is 3 to 5% by weight and the tertiary nitrogen is 0.75 to 1.5% by weight.

References Cited (Backward Citations)

US3479310A Cited
US3442843A Cited
US3463753A Cited
US3656998A Cited
US3718712A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-06-02 1978-12-02 1979-06-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-06-02 1982-12-02 1983-06-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-06-02 1986-12-02 1987-06-03 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag