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Process for the manufacture of metal complexes in a pure form

Assignee: Novartis Corp
•
Filing: 1973-11-08
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Granted: 1975-06-03
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Expires: 1993-11-08
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Abstract

Abstract A new process for preparing metal complexes of unsubstituted or 3,5-substituted salicylic acid and of 3- or 4-valent metals comprising reacting a corresponding salicylic acid with a soluble metal salt and an alkali alcoholate.

Inventors

  • 👤 Hans Eicke
  • 👤 Vladimir Arnold
  • 👤 Eplattenier Francois L

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 10:06
CPC Classifications
C; C10; C10L; C10L1/00; C10L1/10; C10L1/14; C10L1/30; C10L1/301; C07; C07C; C07C51/00; C07C51/41; C07C51/418; C07F; C07F5/00; C07F5/06; C07F5/069; C08; C08K; C08K5/00; C08K5/0091; C10M; C10M2207/00; C10M2207/10; C10M2207/14; C10M2207/144; C10M2207/146; C10M2211/00; C10M2211/04; C10M2211/044; C10M2219/00; C10M2219/04; C10M2219/044; C10N; C10N2010/00; C10N2010/06; C10N2010/08; C10N2010/10; C10N2010/14; C10N2010/16

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 18 words
PROCESS FOR THE MANUFACTURE OF METAL COMPLEXES OF TRIVALENT OR TETRAVALENT METALS WITH ACIDS OF THE FORMULA I
Claim 2
Dependent Claim 18 words
PROCESS FOR THE MANUFACTURE OF METAL COMPLEXES OF TRIVALENT OR TETRAVALENT METALS WITH ACIDS OF THE FORMULA I
Claim 3
Dependent Claim 18 words
Process for the manufacture of metal complexes of trivalent or tetravalent metals with acids of the formula I
Claim 4
Dependent Claim 18 words
Process for the manufacture of metal complexes of trivalent or tetravalent metals with acids of the formula I
Claim 5
Dependent Claim 192 words
Process according to claim 1, characterised in that a successive reaction is carried out, in a lower alcohol, a lower ether, a lower ether-alcohol, a lower ketone or dimethylformamide, of a. an acid of the formula I with b. a salt of the formula II MpX(n p)m (II) in which M denotes the trivalent cation of Cr, Co, Fe, Al, Ga, In or Bi or of a lanthanide or the tetravalent cation of Zr, X denotes the anion Cl , Br , F , NO3 , SO4 or ClO4 and p denotes 1 or 2 and m corresponds to the valency of the anion X and n to the valency of the cation M and c. an alcoholate of the formula III M''OR (III) in which M'' denotes the cation of an alkali metal and R denotes lower alkyl, the methoxyethyl group or the ethoxyethyl group, a, b and c are employed in the molar ratio of (n-i):l/p:n and i denotes 1 or 0 and, if i is 1, the reaction mixture is reacted with water, the molar ratio of water to the acid of the formula I being at least 1:(n-1).
Claim 6
Dependent Claim 52 words
Process according to claim 1, characterised in that an acid of the formula I is used, in which R1 and R2 independently of one another denote hydrogen, alkyl with a total of 1 to 10 carbon atoms, cycloalkyl with 6 to 9 carbon atoms or aralkyl with 7 to 9 carbon atoms.

References Cited (Backward Citations)

US1933520A Cited
US3627798A Cited
US3624116A Cited
US3751440A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-06-02 1978-12-02 1979-06-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-06-02 1982-12-02 1983-06-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-06-02 1986-12-02 1987-06-03 $7700.00 Window Closed / Lapsed

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