Patent US3887451A successfully refreshed from Google Patents.
US3887451A
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US
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Method for sputtering garnet compound layer
Assignee: International Business Machines Corp
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Filing: 1972-12-29
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Granted: 1975-06-03
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Expires: 1992-12-29
Abstract
Abstract A method is disclosed for sputtering epitaxially a layer of stoichiometric garnet composition from a single target wherein the target is composed of a mixture of the separate components of the sputtered layer.
Inventors
- 👤 Jerome J Cuomo
- 👤 Ashok F Mayadas
- 👤 Robert Rosenberg
- 👤 Varadachari Sadagopan
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 15:11
CPC Classifications
C; C23; C23C; C23C14/00; C23C14/22; C23C14/34; C23C14/35
Claims Analysis
Total Claims: 24
Claim 1
Independent Claim
19 words
said temperature of said substrate is established approximately in the range of greater than 500*C to 650 *C, and
Claim 2
Dependent Claim
19 words
said temperature of said substrate is established approximately in the range of greater than 500*C to 650 *C, and
Claim 3
Dependent Claim
97 words
Method of producing film with garnet stoichiometric composition AxB3 xCyD5 yO12, where O < x < 3 and O < y < 3, wherein A is a rare earth element of the lanthanide series including Gd, Eu, Tb and Er; B is Y, La or Sc; C is Al or Ga; and D is Fe, Ni or Co; comprising the steps of: a. establishing a target with substantially non-garnet structure and with said stoichiometric composition and establishing a substrate with garnet composition; b. sputtering said film onto said substrate from said target including establishing operational parameters by:
Claim 4
Dependent Claim
97 words
Method of producing film with garnet stoichiometric composition AxB3 xCyD5 yO12, where O < x < 3 and O < y < 3, wherein A is a rare earth element of the lanthanide series including Gd, Eu, Tb and Er; B is Y, La or Sc; C is Al or Ga; and D is Fe, Ni or Co; comprising the steps of: a. establishing a target with substantially non-garnet structure and with said stoichiometric composition and establishing a substrate with garnet composition; b. sputtering said film onto said substrate from said target including establishing operational parameters by:
Claim 5
Dependent Claim
16 words
establishing said substrate at a temperature approximately in the range of greater than 500*C to 1,000*C,
Claim 6
Dependent Claim
16 words
establishing said substrate at a temperature approximately in the range of greater than 500*C to 1,000*C,
Claim 7
Dependent Claim
18 words
establishing radio-frequency power to said target approximately in the range of 2 watts/sq. in. to 100 watt/sq. in;
Claim 8
Dependent Claim
18 words
establishing radio-frequency power to said target approximately in the range of 2 watts/sq. in. to 100 watt/sq. in;
Claim 9
Dependent Claim
8 words
Method as set forth in claim 1 wherein
Claim 10
Dependent Claim
19 words
said radio-frequency power to said target is established in the range of 2 watts/sq. in. to 23 watts/sq. in.
Claim 11
Dependent Claim
19 words
said radio-frequency power to said target is established in the range of 2 watts/sq. in. to 23 watts/sq. in.
Claim 12
Dependent Claim
26 words
Method as set forth in claim 2 including the step of establishing said radio-frequency bias on said substrate less than approximately 200 volts d.c. level peak-to-peak.
Claim 13
Dependent Claim
46 words
establishing radio-frequency bias on said substrate at a given d.c. level; and c. varying interdependently said operational parameters to deposit onto said substrate a film having substantially said garnet stoichiometic composition and to establish a given accumulation rate of thickness of said film on said substrate.
Claim 14
Dependent Claim
46 words
establishing radio-frequency bias on said substrate at a given d.c. level; and c. varying interdependently said operational parameters to deposit onto said substrate a film having substantially said garnet stoichiometic composition and to establish a given accumulation rate of thickness of said film on said substrate.
Claim 15
Dependent Claim
29 words
Method as set forth in claim 1 and wherein said radio-frequency power to said substrate is established approximately in the range of 35 watts/sq. in. to 60 watts/sq. in.
Claim 16
Dependent Claim
35 words
Method as set forth in claim 4 wherein said radio-frequency bias on said substrate is varied during production of said film thereon while said temperature of said substrate is maintained at an approximately fixed value.
Claim 17
Dependent Claim
25 words
Method as set forth in claim 1 wherein power density on said target is approximately in the range 20 watts/sq. in. to 100 watts/sq. in.
Claim 18
Dependent Claim
30 words
Method as set forth in claim 1 wherein said temperature of said substrate is greater than approximately 650*C, said radio-frequency bias on said substrate is approximately 75 volts d.c. level.
Claim 19
Dependent Claim
18 words
Method as set forth in claim 1 wherein said temperature of said substrate is less than approximately 650*C.
Claim 20
Dependent Claim
159 words
Method for producing a layer with garnet stoichiometry comprising the steps of establishing a target which has substantially a garnet stoichiometric composition which is substantially nongarnet structure and establishing a substrate with garnet composition, radio-frequency sputtering said film onto said substrate from said target including, establishing operational parameters such that said substrate is at a given temperature approximately in the range of 650*C to 1,000*C, radio-frequency power to said target is at a given power density thereat approximately in the range of 35 watts/sq. in. to 60 wAtts/sq. in., and radio-frequency bias on said substrate is at a given d.c. level approximately in the range of 200 volts d.c. level to 25 volts d.c. level, and varying interdependently said operational parameters to deposit onto said substrate a layer having substantially said garnet stoichiometric composition and to establish a given accumulation rate of thickness of said layer on said substrate approximately in the range of 1 Angstrom/sec. to 3 Angstroms/sec.
Claim 21
Dependent Claim
159 words
Method for producing a layer with garnet stoichiometry comprising the steps of establishing a target which has substantially a garnet stoichiometric composition which is substantially nongarnet structure and establishing a substrate with garnet composition, radio-frequency sputtering said film onto said substrate from said target including, establishing operational parameters such that said substrate is at a given temperature approximately in the range of 650*C to 1,000*C, radio-frequency power to said target is at a given power density thereat approximately in the range of 35 watts/sq. in. to 60 wAtts/sq. in., and radio-frequency bias on said substrate is at a given d.c. level approximately in the range of 200 volts d.c. level to 25 volts d.c. level, and varying interdependently said operational parameters to deposit onto said substrate a layer having substantially said garnet stoichiometric composition and to establish a given accumulation rate of thickness of said layer on said substrate approximately in the range of 1 Angstrom/sec. to 3 Angstroms/sec.
Claim 22
Dependent Claim
144 words
METHOD FOR PRODUCING A LAYER WITH GARNET STOICHIOMETRY COMPRISING THE STEPS OF ESTABLISHING A TARGET WHICH HAS SUBSTANTIALLY A GARNET STOICHIOMETRIC COMPOSITION WHICH IS SUBSTANTIALLY NONGARNET STRUCTURE AND ESTABLISHING A SUBSTRATE WITH GARNET COMPOSITION, RADIO-FREQUENCY SPUTTERING SAID FILM ONTO SAID SUBSTRATE FROM SAID TARGET INCLUDING, ESTABLISHING OPERATIONAL PARAMETERS SUCH THAT SAID SUBSTRATE IS AT A GIVEN TEMPERATURE APPROXIMATELY IN THE RANGE OF 650*C TO 1,000*C, RADIO-FREQUENCY POWER TO SAID TARGET IS AT A GIVEN POWER DENSITY THEREAT APPROXIMATELY IN THE RANGE OF 35 WATTS/SQ. IN. TO 60 WATTS/SQ. IN., AND RADIOFREQUENCY BIAS ON SAID SUBSTRATE IS AT A GIVEN D.C. LEVEL TO 2 APPROXIMATELY IN THE RANGE OF 200 VOLTS D.C. LEVEL TO 25 VOLTS D.C. LEVEL VARYING INTERDEPENDENTLY SAID OPERATIONAL PARAMETERS TO DEPOSIT ONTO SAID SUBSTRATE A LAYER HAVING SUBSTANTIALLY SAID GARNET STOICHIOMETRIC COMPOSITION AND TO ESTABLISH A GIVEN ACCUMULATION RATE OF THICK-
Claim 23
Dependent Claim
144 words
METHOD FOR PRODUCING A LAYER WITH GARNET STOICHIOMETRY COMPRISING THE STEPS OF ESTABLISHING A TARGET WHICH HAS SUBSTANTIALLY A GARNET STOICHIOMETRIC COMPOSITION WHICH IS SUBSTANTIALLY NONGARNET STRUCTURE AND ESTABLISHING A SUBSTRATE WITH GARNET COMPOSITION, RADIO-FREQUENCY SPUTTERING SAID FILM ONTO SAID SUBSTRATE FROM SAID TARGET INCLUDING, ESTABLISHING OPERATIONAL PARAMETERS SUCH THAT SAID SUBSTRATE IS AT A GIVEN TEMPERATURE APPROXIMATELY IN THE RANGE OF 650*C TO 1,000*C, RADIO-FREQUENCY POWER TO SAID TARGET IS AT A GIVEN POWER DENSITY THEREAT APPROXIMATELY IN THE RANGE OF 35 WATTS/SQ. IN. TO 60 WATTS/SQ. IN., AND RADIOFREQUENCY BIAS ON SAID SUBSTRATE IS AT A GIVEN D.C. LEVEL TO 2 APPROXIMATELY IN THE RANGE OF 200 VOLTS D.C. LEVEL TO 25 VOLTS D.C. LEVEL VARYING INTERDEPENDENTLY SAID OPERATIONAL PARAMETERS TO DEPOSIT ONTO SAID SUBSTRATE A LAYER HAVING SUBSTANTIALLY SAID GARNET STOICHIOMETRIC COMPOSITION AND TO ESTABLISH A GIVEN ACCUMULATION RATE OF THICK-
Claim 24
Dependent Claim
38 words
Method as set forth in claim 9 wherein said target is comprised of a mixture of oxides Y2O3, Ga2O3 and Fe2O3, and said film is produced with stoichiometric composition of Y3Fe5 yGayO12, where 0 < y < 3.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1978-06-02 | 1978-12-02 | 1979-06-03 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1982-06-02 | 1982-12-02 | 1983-06-03 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1986-06-02 | 1986-12-02 | 1987-06-03 | $7700.00 | Window Closed / Lapsed |