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US3886094A Expired / Lapsed US ⏱️ 0.0 years remaining

Preparation of hydrocarbon conversion catalysts

Assignee: WR Grace and Co
•
Filing: 1972-12-22
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Granted: 1975-05-27
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Expires: 1992-12-22
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Abstract

Abstract Zeolite containing catalyst compositions are prepared by partially crystallizing a zeolite precursor reaction mixture which contains zeolite seed particles capable of initiating the rapid crystallization of zeolite to form a zeolite suspended in an excess of aqueous alkali metal silicate solution. The crystallization reaction is terminated after the desired quantity of zeolite has been formed, and the excess silicate is gelled to form an amorphous hydrogel matrix therefor. Preferably the process is conducted on a continuous basis.

Inventors

  • 👤 Joseph Michael Pilato
  • 👤 Jr John Storey Magee
  • 👤 Edwin Wolf Albers

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 15:12
CPC Classifications
C; C10; C10G; C10G11/00; C10G11/02; C10G11/04; C10G11/05; B; B01; B01J; B01J29/00; B01J29/04; B01J29/06; B01J29/08; B01J29/085; B01J29/088; C01; C01B; C01B33/00; C01B33/20; C01B33/26; C01B33/28; C01B33/2807; C01B33/2838; B01J2229/00; B01J2229/30; B01J2229/42

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 179 words
A PROCESS FOR PREPARING CRYSTALLINE ALUMINO SILICATE CONTAINING CATALYSTS WHICH COMPRISES: T A. FORMING A ZEOLITE PRECURSOR REACTION MIXTURE CONTAINING SILICA, ALUMINA, SODIUM HYDROXIDE AND WATER AND CRYSTALLIZATION INITIATING AMORPHOUS SILICA-ALUMINA NUCLEATION CENTERS HAVING A PARTICLE SIZE BELOW ABOUT 0.1 MICRON; B. HEATING SAID REACTION MIXTURE TO A TEMPERATURE OF FROM ABOUT 90* TO 110*C. FOR ABOUT 15 TO 120 MINUTES TO PRODUCE ABOUT 15 TO 100% OF THE CRYSTALLINE ZEOLITE THEORETICALLY AVAILABLE TO SAID REACTION MIXTURE; C. DILUTING SAID REACTION MIXTURE WITH SUFFICIENT WATER TO YIELD A SODIUM SILICATE SOLUTION CONCENTRATION OF FROM ABOUT 3 TO 7% BY WEIGHT SIO2 IN SAID REACTION MIXTURE; D. GELLING SAID REACTION MIXTURE WITH A GELLING MIXTURE SELECTED FROM THE GROUP CONSISTING OF MINERAL ACIDS, CO2, ALUMINIUM SALTS AND MIXTURES THEREOF TO PRODUCE AN AMORPHOUS HYDROGEL COMPOSITE HAVING CRYSTALLINE ZEOLITE DISPERSED THEREIN; E. AMMONIUM EXCHANGING SAID COMPOSITE TO LOWER THE NA2O CONTENT THEREOF TO BELOW ABOUT 1% BY WEIGHT; F. EXCHANGING SAID AMMONIUM EXCHANGED PRODUCT WITH A RARE EARTH SALT SOLUTION; G. WASHING AND DRYING SAID COMPOSITE TO PRODUCE A PARTICULATE CATALYST.
Claim 2
Dependent Claim 179 words
A PROCESS FOR PREPARING CRYSTALLINE ALUMINO SILICATE CONTAINING CATALYSTS WHICH COMPRISES: T A. FORMING A ZEOLITE PRECURSOR REACTION MIXTURE CONTAINING SILICA, ALUMINA, SODIUM HYDROXIDE AND WATER AND CRYSTALLIZATION INITIATING AMORPHOUS SILICA-ALUMINA NUCLEATION CENTERS HAVING A PARTICLE SIZE BELOW ABOUT 0.1 MICRON; B. HEATING SAID REACTION MIXTURE TO A TEMPERATURE OF FROM ABOUT 90* TO 110*C. FOR ABOUT 15 TO 120 MINUTES TO PRODUCE ABOUT 15 TO 100% OF THE CRYSTALLINE ZEOLITE THEORETICALLY AVAILABLE TO SAID REACTION MIXTURE; C. DILUTING SAID REACTION MIXTURE WITH SUFFICIENT WATER TO YIELD A SODIUM SILICATE SOLUTION CONCENTRATION OF FROM ABOUT 3 TO 7% BY WEIGHT SIO2 IN SAID REACTION MIXTURE; D. GELLING SAID REACTION MIXTURE WITH A GELLING MIXTURE SELECTED FROM THE GROUP CONSISTING OF MINERAL ACIDS, CO2, ALUMINIUM SALTS AND MIXTURES THEREOF TO PRODUCE AN AMORPHOUS HYDROGEL COMPOSITE HAVING CRYSTALLINE ZEOLITE DISPERSED THEREIN; E. AMMONIUM EXCHANGING SAID COMPOSITE TO LOWER THE NA2O CONTENT THEREOF TO BELOW ABOUT 1% BY WEIGHT; F. EXCHANGING SAID AMMONIUM EXCHANGED PRODUCT WITH A RARE EARTH SALT SOLUTION; G. WASHING AND DRYING SAID COMPOSITE TO PRODUCE A PARTICULATE CATALYST.
Claim 3
Dependent Claim 14 words
The process of claim 1 wherein the process is conducted on a continuous basis.
Claim 4
Dependent Claim 25 words
The process of claim 1 wherein the said crystalline zeolite has a silica to alumina ratio on the order of from about 2.5 to 6.
Claim 5
Dependent Claim 28 words
The method of claim 1 wherein said composite is spray dried to produce a microspheroidal product having a particle size on the order of 50 to 300 microns.
Claim 6
Dependent Claim 28 words
The method of claim 1 wherein said partially crystalline zeolite reaction mixture is admixed with clay in an amount equal to from about 10 to 30% by weight.

References Cited (Backward Citations)

US3275571A Cited
US3595611A Cited
US3671191A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-05-26 1978-11-25 1979-05-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-05-26 1982-11-25 1983-05-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-05-26 1986-11-25 1987-05-27 $7700.00 Window Closed / Lapsed

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