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US3884830A Expired / Lapsed US ⏱️ 0.0 years remaining

Controlled selectivity activated carbon

Assignee: Calgon Carbon Corp
•
Filing: 1973-10-02
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Granted: 1975-05-20
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Expires: 1993-10-02
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Abstract

Abstract A series of fast acting activated carbons is made having high surface areas and at the same time very small pore size. The method of manufacturing them, which specifies certain carbonaceous starting materials and pulverizing, agglomerating, crushing and oxidizing steps, determines or controls the pore sizes and surface areas. My activated carbon has highly uniform, very small pore sizes and at the same time a large surface area per unit of weight and a large macropore volume. New methods of separating mixtures of compounds, such as mixtures of hydrocarbons, are disclosed employing my new molecular sieve activated carbon. In my fast-adsorbing molecular sieve, molecules of generally lower molecular weight are adsorbed by the carbon rather than the usual case for activated carbon, which is that the carbon tends to adsorb generally larger molecules in preference to smaller ones.

Inventors

  • 👤 Richard John Grant

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 14:58
CPC Classifications
C; C07; C07C; C07C51/00; C07C51/42; C07C51/47; C01; C01B; C01B32/00; C01B32/30; C01B32/306

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 105 words
METHOD OF MAKING A MOLECULAR SIEVE IN GRANULAR FORM, COMPRISING AGGLOMERATING PULVERIZED BITUMINOUS COAL OR CHARRED NATURALLY-OCCURRING CARBONACEOUS MATERIAL WITH PITCH, CRUSHING THE AGGLOMERATIONS THEREOF, ACTIVATING THE GRANULAR MATERIAL THUS OBTAINED BY TREATING IT IN A HEATING ZONE AT FROM 300*C TO 400*C FOR A PERIOD OF AT LEAST 120 MINUTES WITH ABOUT 5 TO 18 LITERS OF AIR PER GRAM OF CARBON, SUBSEQUENTLY CALCINING IT AT A TEMPERATURE OF 850*C TO 960*C FOR A PERIOD OF 5 TO 20 MINUTES, AND RECOVERING A GRANULAR, HIGHLY ACTIVATED CARBON HAVING AN IODINE NUMBER OF AT LEAST 450 AND A CARBONTETRACHLORIDE NUMBER OF NO GREATER THAN 2.
Claim 2
Dependent Claim 105 words
METHOD OF MAKING A MOLECULAR SIEVE IN GRANULAR FORM, COMPRISING AGGLOMERATING PULVERIZED BITUMINOUS COAL OR CHARRED NATURALLY-OCCURRING CARBONACEOUS MATERIAL WITH PITCH, CRUSHING THE AGGLOMERATIONS THEREOF, ACTIVATING THE GRANULAR MATERIAL THUS OBTAINED BY TREATING IT IN A HEATING ZONE AT FROM 300*C TO 400*C FOR A PERIOD OF AT LEAST 120 MINUTES WITH ABOUT 5 TO 18 LITERS OF AIR PER GRAM OF CARBON, SUBSEQUENTLY CALCINING IT AT A TEMPERATURE OF 850*C TO 960*C FOR A PERIOD OF 5 TO 20 MINUTES, AND RECOVERING A GRANULAR, HIGHLY ACTIVATED CARBON HAVING AN IODINE NUMBER OF AT LEAST 450 AND A CARBONTETRACHLORIDE NUMBER OF NO GREATER THAN 2.
Claim 3
Dependent Claim 43 words
The method of claim 1 wherein the starting material is bituminous coal and wherein the granular material is introduced into the baking zone at 150*C to 250*C and gradually brought up to the activation temperature over a period of 45 to 60 minutes.
Claim 4
Dependent Claim 17 words
The method of claim 1 wherein calcining is performed within a period of 5 to 10 minutes.
Claim 5
Dependent Claim 17 words
The method of claim 2 wherein calcining is performed within a period of 5 to 10 minutes.
Claim 6
Dependent Claim 13 words
The method of claim 1 wherein the naturally-occurring carbonaceous material is coconut char.
Claim 7
Dependent Claim 13 words
A granular, highly activated carbon prepared according to the process of claim 1.
Claim 8
Dependent Claim 36 words
The activated carbon of claim 6 wherein the granular material is introduced into the baking zone at 150*C. to 250*C. and gradually brought up to the activation temperature over a period of 45 to 60 minutes.
Claim 9
Dependent Claim 18 words
The activated carbon of claim 6 wherein calcining is performed within a period of 5 to 10 minutes.
Claim 10
Dependent Claim 18 words
The activated carbon of claim 7 wherein calcining is performed within a period of 5 to 10 minutes.
Claim 11
Dependent Claim 14 words
The activated carbon of claim 6 wherein the naturally-occurring carbonaceous material is coconut char.

References Cited (Backward Citations)

US2008148A Cited
US3222412A Cited
US3793224A Cited
US3778387A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-05-19 1978-11-18 1979-05-20 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-05-19 1982-11-18 1983-05-20 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-05-19 1986-11-18 1987-05-20 $7700.00 Window Closed / Lapsed

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