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US3883145A Expired / Lapsed US ⏱️ 0.0 years remaining

Golf ball and composition for forming the same

Assignee: Faultless Rubber Co
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Filing: 1967-10-09
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Granted: 1975-05-13
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Expires: 1987-10-09
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Abstract

Abstract This invention relates to a composition for forming a unitary molded golf ball and which composition comprises essentially highly resilient polybutadiene rubber, a cross linking agent, such as trimethylol propane trimethacrylate, a curative agent, non-black reenforcement and/or filler material, and a high density olefin, specifically an ultra high molecular weight linear polyethylene, which composition can be molded to form a golf ball having highly desirable properties.

Inventors

  • 👤 Alvon R Cox
  • 👤 William W Latou

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 23:31
CPC Classifications
A; A63; A63B; A63B37/00; A63B37/0003; A63B37/005; A63B37/006; A63B37/0067; A63B37/007; A63B37/0072; A63B37/0073

Claims Analysis

Total Claims: 27
Claim 1
Independent Claim 123 words
A GOLF BALL COMPRISING A UNITARY, SOLID, CURED ELASTOMER MADE BY VULCANIZATION OF THE COMPOSITION CONSISTING ESSENTIALLY OF THE FOLLOWING INGREDIENTS IN THE RATIOS STATED: HIGHLY RESILIENT POLYBUTADIENE ELASTOMER MATERIALS HAVING AT LEAST 30 PERCENT CIS CONFIGURATION ABOUT 80 TO 100 PARTS. ABOUT 25 TO 50 PARTS OF A MATERIAL FROM THE CLASS CONSISTING OF 1,3 BUTYLENE GLYCOL DIMETHACRYLATE, AND DIMETHACRYLATE, POLYETHYLENE GLYCOL DIMETHACRYLATE, AND TRIMETHYLOL PROPANE TRIMETHACRYLATE HIGH DENSITY AND MOLECULAR WEIGHT LINEAR POLYETHLENE HAVING A MOLECULAR WEIGHT OF BETWEEN 1.5 AND 2 MILLON AND A MELT INDEX OF 0 IN SMALL PARTICLES SIZE FROM ABOUT 2 TO ABOUT 40 PARTS, A PEROXIDE CURING AGENT ABOUT 0.5 TO 10 PARTS AND FINELY DIVIDED REENFORCING AND FILTER MATERIALS ABOUT 30 TO 60 PARTS.
Claim 2
Dependent Claim 123 words
A GOLF BALL COMPRISING A UNITARY, SOLID, CURED ELASTOMER MADE BY VULCANIZATION OF THE COMPOSITION CONSISTING ESSENTIALLY OF THE FOLLOWING INGREDIENTS IN THE RATIOS STATED: HIGHLY RESILIENT POLYBUTADIENE ELASTOMER MATERIALS HAVING AT LEAST 30 PERCENT CIS CONFIGURATION ABOUT 80 TO 100 PARTS. ABOUT 25 TO 50 PARTS OF A MATERIAL FROM THE CLASS CONSISTING OF 1,3 BUTYLENE GLYCOL DIMETHACRYLATE, AND DIMETHACRYLATE, POLYETHYLENE GLYCOL DIMETHACRYLATE, AND TRIMETHYLOL PROPANE TRIMETHACRYLATE HIGH DENSITY AND MOLECULAR WEIGHT LINEAR POLYETHLENE HAVING A MOLECULAR WEIGHT OF BETWEEN 1.5 AND 2 MILLON AND A MELT INDEX OF 0 IN SMALL PARTICLES SIZE FROM ABOUT 2 TO ABOUT 40 PARTS, A PEROXIDE CURING AGENT ABOUT 0.5 TO 10 PARTS AND FINELY DIVIDED REENFORCING AND FILTER MATERIALS ABOUT 30 TO 60 PARTS.
Claim 3
Dependent Claim 42 words
A golf ball as in claim 1 where 2 to 12 parts of a butadienestyrene resin are present in the initial composition, which resin is made from about 70 to 90 percent styrene and about 30 to 10 percent butadiene by weight.
Claim 4
Dependent Claim 22 words
A golf ball as in claim 1 where about 25 parts of the high density polyethylene are present in the initial composition.
Claim 5
Dependent Claim 22 words
A golf ball as in claim 1 wherein the initial composition includes up to 10 parts of whitener, accelerator and pigment materials.
Claim 6
Dependent Claim 38 words
A golf ball as in claim 1 where the initial composition includes from about 10 to about 40 parts of hydrated silica and from about 10 to about 40 parts of barytes as said reenforcing and filler materials.
Claim 7
Dependent Claim 22 words
A golf ball as in claim 1 where the initial composition has natural rubber therein between about 2 to about 20 parts.
Claim 8
Dependent Claim 108 words
A golf ball comprising a unitary, solid, cured elastomer made by vulcanization of the composition consisting essentially of the following ingredients: highly resilient polybutadiene elastomer material about 100 parts, about 20 to 50 parts of a material from the class consisting of 1, 3 butylene glycol dimethacrylate, ethylene glycol dimethacrylate, polyethylene glycol dimethacrylate and trimethylol propane trimethacrylate, high density and molecular weight linear polyethylene that has a molecular weight of between 1.5 and 2.0 million in small particle size from about 2 up to about 40 parts, a peroxide curing agent about 0.5 to 10 parts, and finely divided reenforcing and filler materials about 30 to 60 parts.
Claim 9
Dependent Claim 108 words
A golf ball comprising a unitary, solid, cured elastomer made by vulcanization of the composition consisting essentially of the following ingredients: highly resilient polybutadiene elastomer material about 100 parts, about 20 to 50 parts of a material from the class consisting of 1, 3 butylene glycol dimethacrylate, ethylene glycol dimethacrylate, polyethylene glycol dimethacrylate and trimethylol propane trimethacrylate, high density and molecular weight linear polyethylene that has a molecular weight of between 1.5 and 2.0 million in small particle size from about 2 up to about 40 parts, a peroxide curing agent about 0.5 to 10 parts, and finely divided reenforcing and filler materials about 30 to 60 parts.
Claim 10
Dependent Claim 20 words
A golf ball as in claim 7 wherein the initial composition includes from about 10 to about 25 parts polyethylene.
Claim 11
Dependent Claim 36 words
A golf ball as in claim 7 where the curing agent is selected from the class consisting of dicumyl peroxide, 2, 4 dichlorobenzoyl peroxide, 2, 5 dimethyl-2-5-di (t-butyl-peroxy) hexane, and 2, 5 dimethyl-2-5-di (t-butyl-peroxy) hexane. 3.
Claim 12
Dependent Claim 29 words
A golf ball as in claim 7 where the linear polyethylene has a particle size to pass through a 0.0165 inch screen opening, and a melt index of 0.
Claim 13
Dependent Claim 23 words
A goLf ball as in claim 1 where the linear polyethylene has a particle size to pass through a 0.0165 inch screen opening.
Claim 14
Dependent Claim 36 words
A golf ball as in claim 1 where the curing agent is selected from the class consisting of dicumyl peroxide, 2, 4 dichlorobenzoyl peroxide, 2, 5 dimethyl-2-5-di (t-butyl-peroxy) hexane, and 2, 5 dimethyl-2-5-di (t-butyl-peroxy) hexane 3.
Claim 15
Dependent Claim 39 words
A golf ball as in claim 9 where the linear polythylene has a molecular weight of between 1.5 and 2.0 million, a particle size to pass through a 0.0165 inch screen opening, and has a melt index of 0.
Claim 16
Dependent Claim 35 words
A golf ball as in claim 8 where the curing agent is selected from the class consisting of dicumyl peroxide, 2,4 dichlorobenzoyl peroxide, 2, 5 dimethyl-2-5-di (t-butyl-peroxy) hexane, and 2, 5 dimethyl-2-5-di (t-butyl-peroxy) hexane 3.
Claim 17
Dependent Claim 39 words
A gold ball as in claim 14 where the linear polythylene has a molecular weight of between 1.5 and 2.0 million, a particle size to pass through a 0.0165 inch screen opening, and has a melt index of 0.
Claim 18
Dependent Claim 85 words
A molded ball having the gravity and click and rebound of a golf ball and the size of a golf ball which includes elastomeric vulcanizate prepared from a composition consisting essentially of diolefin rubber having at least 30 percent cis configuration, a cross-linking agent, a curing agent, finely divided reinforcing and filler materials and as an impact modifier, finely divided polyethylene dispersed in the vulcanizate, which polyethylene has a molecular weight of 1,500,000 to 2,000,000 and is present as a separate phase in the vulcanizate.
Claim 19
Dependent Claim 85 words
A molded ball having the gravity and click and rebound of a golf ball and the size of a golf ball which includes elastomeric vulcanizate prepared from a composition consisting essentially of diolefin rubber having at least 30 percent cis configuration, a cross-linking agent, a curing agent, finely divided reinforcing and filler materials and as an impact modifier, finely divided polyethylene dispersed in the vulcanizate, which polyethylene has a molecular weight of 1,500,000 to 2,000,000 and is present as a separate phase in the vulcanizate.
Claim 20
Dependent Claim 57 words
A molded ball as in claim 16 where from about 80 to 100 parts of the diolefin rubber, about 20 to 50 parts of a cross-linking agent, about 2 to 40 parts of the polyethylene, and about 0.5 to 10 parts of a peroxide curing agent are present in the composition from which the ball is made.
Claim 21
Dependent Claim 90 words
A molded ball having the gravity and click and rebound of a golf ball and the size of a golf ball which includes elastomeric vulcanizate prepared from a composition consisting essentially of diolefin rubber having at least 30 percent cis configuration, a cross-linking agent, a curing agent, finely divided reinforcing and filler materials and a finely divided polyethylene dispersed in the vulcanizate, which polyethylene has a molecular weight of between 1,500,000 and 2,000,000, a particle size to pass through a 0.0165 inch screen opening, and a melt index of 0.
Claim 22
Dependent Claim 90 words
A molded ball having the gravity and click and rebound of a golf ball and the size of a golf ball which includes elastomeric vulcanizate prepared from a composition consisting essentially of diolefin rubber having at least 30 percent cis configuration, a cross-linking agent, a curing agent, finely divided reinforcing and filler materials and a finely divided polyethylene dispersed in the vulcanizate, which polyethylene has a molecular weight of between 1,500,000 and 2,000,000, a particle size to pass through a 0.0165 inch screen opening, and a melt index of 0.
Claim 23
Dependent Claim 21 words
A molded ball as in claim 18 where from about 20 to 50 parts of a cross linking agent are present.
Claim 24
Dependent Claim 20 words
A molded ball as in claim 18 where from about 2 to about 40 parts of the polyethylene are present.
Claim 25
Dependent Claim 68 words
A molded ball as in claim 18 where from about 80 to 100 parts of the diolefin rubber, about 20 to 50 parts of a cross linking agent, about 2 to 40 parts of the polyethylene, about 30 to 60 parts of reenforcing and filler materials, and about 0.5 to 10 parts of a peroxide curing agent are present in the composition from which the ball is made.
Claim 26
Dependent Claim 72 words
A molded ball having the gravity and click and rebound of a golf ball formed of an elastomeric vulcanizate prepared from a composition consisting essentially of diolefin rubber having at least 30 percent cis configuration, a cross-linking agent, a curing agent, finely divided reinforcing and filler materials and finely divided polyethylene dispersed in the vulcanizate, said polyethylene being an ultra-high molecular weight polyethylene having an average molecular weight of at least 1,500,000.
Claim 27
Dependent Claim 72 words
A molded ball having the gravity and click and rebound of a golf ball formed of an elastomeric vulcanizate prepared from a composition consisting essentially of diolefin rubber having at least 30 percent cis configuration, a cross-linking agent, a curing agent, finely divided reinforcing and filler materials and finely divided polyethylene dispersed in the vulcanizate, said polyethylene being an ultra-high molecular weight polyethylene having an average molecular weight of at least 1,500,000.

References Cited (Backward Citations)

US3313545A Cited
US3421766A Cited
US3478132A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-05-12 1978-11-11 1979-05-13 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-05-12 1982-11-11 1983-05-13 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-05-12 1986-11-11 1987-05-13 $7700.00 Window Closed / Lapsed

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