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US3882006A Expired / Lapsed US ⏱️ 0.0 years remaining

Method for curing alkyd resin compositions by applying ionizing radiation

Assignee: Kansai Paint Co Ltd
•
Filing: 1973-11-05
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Granted: 1975-05-06
•
Expires: 1993-11-05
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Abstract

Abstract An alkyd resin composition is prepared by dissolving a polymerizable alkyd resin having from 10 to 50% of oil length into a vinyl monomer. The polymerizable alkyd resin is obtained by a half-esterification reaction of an acid anhydride having a polymerizable unsaturated group and an alkyd resin modified with conjugated unsaturated fatty acid and/or conjugated unsaturated oil having at least one reactive hydroxyl group per one molecule. The alkyd resin composition thus obtained is coated on an article, and ionizing radiation is applied on the article to cure the coated film thereon.

Inventors

  • 👤 Tadashi Watanabe
  • 👤 Koichiro Murata
  • 👤 Tsutomu Maruyama

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 10:17
CPC Classifications
C; C08; C08G; C08G63/00; C08G63/02; C08G63/12; C08G63/52; C08F; C08F283/00; C08F283/01; Y; Y10; Y10S; Y10S522/00; Y10S522/911; Y10S522/912

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 134 words
A METHOD FOR CURING ALKYD RESIN COMPOSITIONS WHICH COMPRISES APPLYING IONIZING RADIATION IN A TOTAL RADIATION DOSE OF FROM 0.1 TO 50 M RAD TO AN ALKYD RESIN COMPOSITION COMPRISING A. STYRENE; AND B. AN ALKYD RESIN PRODUCT CONSISTING ESSENTIALLY OF THE HALFESTERIFICATION PRODUCT OF (1) A CONJUGATED UNSATURATED FATTY ACID OR CONJUGATED UNSATURATED FATTY OIL, SELECTED FROM THE GROUP CONSISTING OF TUNG OIL, LINSEED OIL, LINOLIC AND DEHYDRATED CASTOR OIL, MODIFIED ALKYD RESIN, SAID ALKYD RESIN OF INGREDIENTS COMPRISING PHTHALIC ANHYDRIDE, PENTAERYTHRIOTOL, AND TRIMETHYLOL ETHANE OR GLYCERINE HAVING AN OIL LENGTH OF FROM 10 TO 50 PERCENT AND A HYDROXYL EQUIVALENT OF 300-2OOO, AND (2) MALEIC ANHYDRIDE OR CITRACONIC ANHYDRIDE, SAID ANHYDRIDE BEING IN AN AMOUNT SUFFICIENT TO REACT WITH AT LEAST 30 PERCENT OF THE HYDROXYL GROUPS OF SAID MODIFIED ALKYD RESIN.
Claim 2
Independent Claim 134 words
A METHOD FOR CURING ALKYD RESIN COMPOSITIONS WHICH COMPRISES APPLYING IONIZING RADIATION IN A TOTAL RADIATION DOSE OF FROM 0.1 TO 50 M RAD TO AN ALKYD RESIN COMPOSITION COMPRISING A. STYRENE; AND B. AN ALKYD RESIN PRODUCT CONSISTING ESSENTIALLY OF THE HALFESTERIFICATION PRODUCT OF (1) A CONJUGATED UNSATURATED FATTY ACID OR CONJUGATED UNSATURATED FATTY OIL, SELECTED FROM THE GROUP CONSISTING OF TUNG OIL, LINSEED OIL, LINOLIC AND DEHYDRATED CASTOR OIL, MODIFIED ALKYD RESIN, SAID ALKYD RESIN OF INGREDIENTS COMPRISING PHTHALIC ANHYDRIDE, PENTAERYTHRIOTOL, AND TRIMETHYLOL ETHANE OR GLYCERINE HAVING AN OIL LENGTH OF FROM 10 TO 50 PERCENT AND A HYDROXYL EQUIVALENT OF 300-2OOO, AND (2) MALEIC ANHYDRIDE OR CITRACONIC ANHYDRIDE, SAID ANHYDRIDE BEING IN AN AMOUNT SUFFICIENT TO REACT WITH AT LEAST 30 PERCENT OF THE HYDROXYL GROUPS OF SAID MODIFIED ALKYD RESIN.
Claim 3
Dependent Claim 38 words
A method for curing alkyd resin compositions according to claim 1, in which said ionizing radiation is carried out by a member selected from the group consisting of proton rays, alpha-rays, beta-rays, gamma-rays, accelerated electron rays, and X-rays.
Claim 4
Dependent Claim 30 words
A method for curing alkyd resin compositions according to claim 1, in which said ionizing radiation is applied in a total radiation dose of from 0.5 to 10.0 M rad.
Claim 5
Dependent Claim 31 words
The method of claim 1 wherein the alkyd resin is of ingredients consisting of phthalic anhydride, pentaerythritol, trimethylol ethane, and tung oil fatty acid, and the acid anhydride is maleic anhydride.
Claim 6
Dependent Claim 32 words
The method of claim 1 wherein the alkyd resin is of ingredients consisting of phthalic anhydride, pentaerythritol, trimethylol ethane, and isomerized linseed oil fatty acid, and the acid anhydride is citraconic anhydride.
Claim 7
Dependent Claim 29 words
The method of claim 1 wherein the alkyd resin is of ingredients consisting of dehydrated castor oil, pentaerythritol, glycerine and phthalic anhydride, and the acid anhydride is maleic anhydride.
Claim 8
Dependent Claim 17 words
The method of claim 1 wherein said ionizing radiation is applied at a temperature of 5*-50* C.

References Cited (Backward Citations)

US3350335A Cited
US3437512A Cited
US3542587A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-05-05 1978-11-04 1979-05-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-05-05 1982-11-04 1983-05-06 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-05-05 1986-11-04 1987-05-06 $7700.00 Window Closed / Lapsed

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