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US3880799A Expired / Lapsed US ⏱️ 0.0 years remaining

Thermal oxidatively stable polycarbonate

Assignee: General Electric Co
•
Filing: 1974-01-02
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Granted: 1975-04-29
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Expires: 1994-01-02
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Abstract

Abstract A thermal oxidatively stable polycarbonate composition having a stabilizing amount of an ester of a phosphorohalidous acid and a process for preparing a thermal oxidatively stable polymer. In the process, the ester of a phosphorohalidous acid is reacted with a dihydric-phenol monomer. In addition, an epoxy may be used in admixture with the composition.

Inventors

  • 👤 Thomas J Hoogeboom

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 23:37
CPC Classifications
C; C08; C08G; C08G64/00; C08K; C08K5/00; C08K5/04; C08K5/15; C08L; C08L63/00; C08L69/00

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 43 words
A THERMAL OXIDATIVELY STABLE POLYMER COMPOSITION WHICH IS THE RESIDUE OF THE CONDENSATION REACTION OF A DIHYDRIC PHENOL, A CARBONATE PRECURSOR AND 0.00015 TO ABOUT 0.05 MOLES PER MOLE OF DIHYDRIC PHENOL OF AN ESTER OF A PHOSPHOROHALIDOUS ACID HAVING THE FOLLOWING FORMULA:
Claim 2
Dependent Claim 43 words
A THERMAL OXIDATIVELY STABLE POLYMER COMPOSITION WHICH IS THE RESIDUE OF THE CONDENSATION REACTION OF A DIHYDRIC PHENOL, A CARBONATE PRECURSOR AND 0.00015 TO ABOUT 0.05 MOLES PER MOLE OF DIHYDRIC PHENOL OF AN ESTER OF A PHOSPHOROHALIDOUS ACID HAVING THE FOLLOWING FORMULA:
Claim 3
Dependent Claim 14 words
The composition of claim 1 wherein the ester of phosphorohalidous acid is diphenyl phosphorochloridite.
Claim 4
Dependent Claim 13 words
The composition of claim 1 wherein the polymer composition has the following formula:
Claim 5
Dependent Claim 63 words
In a process for preparing a thermal oxidatively stable aromatic polycarbonate by reacting a dihydric phenol with a carbonate precursor in the presence of an acid acceptor, a catalyst and a molecular weight regulator; wherein the improvement comprises adding to the reaction 0.000015 to about 0.05 mole per mole of dihydric phenol of an ester of a phosphorohalidous acid having the following formula:
Claim 6
Dependent Claim 63 words
In a process for preparing a thermal oxidatively stable aromatic polycarbonate by reacting a dihydric phenol with a carbonate precursor in the presence of an acid acceptor, a catalyst and a molecular weight regulator; wherein the improvement comprises adding to the reaction 0.000015 to about 0.05 mole per mole of dihydric phenol of an ester of a phosphorohalidous acid having the following formula:
Claim 7
Dependent Claim 32 words
The composition of claim 1 having in admixture therewith from 0.01 to 1.0 weight percent based on the weight of the polymer composition of an epoxy composition represented by the following formula:
Claim 8
Dependent Claim 14 words
The composition of claim 4 wherein the epoxy compound is an epoxidized cycloaliphatic compound.
Claim 9
Dependent Claim 14 words
The composition of claim 4 wherein the epoxy compound is 3,4-epoxy-cyclohexylmethyl 3,4-epoxy cyclohexane carboxylate.

References Cited (Backward Citations)

US3489716A Cited
US3578634A Cited
US3634312A Cited
US3711441A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-04-28 1978-10-28 1979-04-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-04-28 1982-10-28 1983-04-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-04-28 1986-10-28 1987-04-29 $7700.00 Window Closed / Lapsed

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