Patent US3879323A successfully refreshed from Google Patents.
US3879323A
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Process for preparing a mixture of bitumen, a high-boiling hydrocarbon and a rubber-like copolymer of ethylene, at least one other alpha-alkene and, if necessary, one or more polyenes
Assignee: Stamicarbon BV
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Filing: 1973-09-18
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Granted: 1975-04-22
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Expires: 1993-09-18
Abstract
Abstract A mixture containing bitumen, a high-boiling hydrocarbon and an EPDM-rubber is prepared by dissolving the EPDM under special conditions in the hydrocarbon and by subsequently mixing the resulting solution with bitumen. An improved bitumen is obtained that can be applied, for instance, in road construction. Preferably during the dissolution of EPDM in hydrocarbon, oxygen is incorporated into the mixture in a forced manner in order to achieve improved dispersion.
Inventors
- 👤 Der Loos Jozef L M Van
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 19:58
CPC Classifications
C; C08; C08L; C08L95/00
Claims Analysis
Total Claims: 16
Claim 1
Independent Claim
146 words
PROCESS FOR PREPARING A MIXTURE OF BITUMEN, SELECTED FROM THE GROUP CONSISTING OF DISTILLATE-BITUMEN, BLOWN BITUMEN, HIGH-VACUUM BITUMEN AND MIXED BITUMEN, A HIGH-BOILING HYDROCARBON HAVING A FLASH POINT OF AT LEAST 200*C AND A RUBBER-LIKE COPOLYMER OF FROM 20 TO 75% BY WEIGHT OF ETHYLENE, 24 TO 70% BY WEIGHT OF PROPYLENE AND/OR BUTYLENE-1 AND POLYENES, THIS PROCESS BEING CHARACTERIZED IN THAT AT A TEMPERATYRE OF BETWEEN 160* AND 260*C BITUMEN IS MIXED WITH 0.1 ATURE OF BETWEEN 160* AND 260*C BITUMEN IS MIXED WITH 0.1 TO 25% BY WEIGHT- REFFERED TO THE BITUMEN - OF THE RUBBERLIKE COPOLYMER IN THE FORM OF A SOLUTION OF THIS COPOLYMER PREPARED AT A TEMPERATURE OF BETWEEN 160* AND 260*C IN 300 TO 1000% BY WEIGHT - REFERED TO THE COPOLYMER - OF THE HIGH-BOILING HYDROCARBON, WHICH SOLUTION HAS A VISCOSITY OF AT MOST 250 POISE MEASURED AT 200*C.
Claim 2
Dependent Claim
146 words
PROCESS FOR PREPARING A MIXTURE OF BITUMEN, SELECTED FROM THE GROUP CONSISTING OF DISTILLATE-BITUMEN, BLOWN BITUMEN, HIGH-VACUUM BITUMEN AND MIXED BITUMEN, A HIGH-BOILING HYDROCARBON HAVING A FLASH POINT OF AT LEAST 200*C AND A RUBBER-LIKE COPOLYMER OF FROM 20 TO 75% BY WEIGHT OF ETHYLENE, 24 TO 70% BY WEIGHT OF PROPYLENE AND/OR BUTYLENE-1 AND POLYENES, THIS PROCESS BEING CHARACTERIZED IN THAT AT A TEMPERATYRE OF BETWEEN 160* AND 260*C BITUMEN IS MIXED WITH 0.1 ATURE OF BETWEEN 160* AND 260*C BITUMEN IS MIXED WITH 0.1 TO 25% BY WEIGHT- REFFERED TO THE BITUMEN - OF THE RUBBERLIKE COPOLYMER IN THE FORM OF A SOLUTION OF THIS COPOLYMER PREPARED AT A TEMPERATURE OF BETWEEN 160* AND 260*C IN 300 TO 1000% BY WEIGHT - REFERED TO THE COPOLYMER - OF THE HIGH-BOILING HYDROCARBON, WHICH SOLUTION HAS A VISCOSITY OF AT MOST 250 POISE MEASURED AT 200*C.
Claim 3
Dependent Claim
149 words
Process for preparing a mixture of bitumen, selected from the group consisting of distillate-bitumen, blown bitumen, high-vacuum bitumen and mixed bitumen, a high-boiling hydrocarbon having a flash point of At least 200*C and a rubber-like copolymer of from 20 to 75% by weight of ethylene, 24 to 79% by weight of propylene and/or butylene-1 and of from 1 to 10% by weight, if necessary, of one or more polyenes, this process being characterized in that at a temperature of between 160* and 260*C bitumen is mixed with 0.1 to 25% by weight - referred to the bitumen - of the rubber-like copolymer in the form of a solution of this copolymer prepared at a temperature of between 160* and 260*C in 300 to 1000% by weight - referred to the copolymer - of the high-boiling hydrocarbon, which solution has a viscosity of at most 250 Poise, measured at 200*C.
Claim 4
Dependent Claim
149 words
Process for preparing a mixture of bitumen, selected from the group consisting of distillate-bitumen, blown bitumen, high-vacuum bitumen and mixed bitumen, a high-boiling hydrocarbon having a flash point of At least 200*C and a rubber-like copolymer of from 20 to 75% by weight of ethylene, 24 to 79% by weight of propylene and/or butylene-1 and of from 1 to 10% by weight, if necessary, of one or more polyenes, this process being characterized in that at a temperature of between 160* and 260*C bitumen is mixed with 0.1 to 25% by weight - referred to the bitumen - of the rubber-like copolymer in the form of a solution of this copolymer prepared at a temperature of between 160* and 260*C in 300 to 1000% by weight - referred to the copolymer - of the high-boiling hydrocarbon, which solution has a viscosity of at most 250 Poise, measured at 200*C.
Claim 5
Dependent Claim
41 words
Process according to claim 1, characterized in that as solution of the rubber-like copolymer a solution is applied of the rubber-like copolymer in 400 to 800% by weight - referred to this copolymer - of a high-boiling hydrocarbon or hydrocarbon mixture.
Claim 6
Dependent Claim
35 words
Process according to claim 1, characterized in that during the preparation of the solution of the copolymer in the high-boiling hydrocarbon, oxygen or oxygen-containing gas mixtures are contacted with the solution in a forced manner.
Claim 7
Dependent Claim
38 words
Process according to claim 3, characterized in that the oxygen-containing gases are contacted with the solution by continuous supply of oxygen or oxygen-containing gas and by increasing the area of contact between the solution and the gas supplied.
Claim 8
Dependent Claim
17 words
Process according to claim 3, characterized in that oxygen or oxygen-containing gases are led through the solution.
Claim 9
Dependent Claim
18 words
Process according to claim 1, characterized in that as copolymer a copolymer is applied containing dicyclopentadiene for polyene.
Claim 10
Dependent Claim
36 words
Process according to claim 6, characterized in that as high-boiling hydrocarbon or hydrocarbon mixture a hydrocarbon or hydrocarbon mixture is applied having a flash point of at least 200* C, preferably of at least 250* C.
Claim 11
Dependent Claim
17 words
Process according to claim 7, characterized in that as hydrocarbon mixture an aromatic-naphthenic hydrocarbon mixture is applied.
Claim 12
Dependent Claim
20 words
Process according to claim 8, characterized in that as hydrocarbon mixture a furfurol extract from lubricating oil fractions is applied.
Claim 13
Dependent Claim
52 words
Process according to claim 1, characterized in that a bitumen a distillate-bitumen is applied, in particular a distillate-bitumen having a penetration at 25* C of between 16 and 21 mm, a softening point (ring-and-ball) of between 37 and 44* C and a breaking point according to Fraass of at most -15* C.
Claim 14
Dependent Claim
25 words
Process according to claim 1, characterized in that in the mixture of bitumen, high-boiling hydrocarbon and rubber-like polymer also sulphur and/or a polyolefin is incorporated.
Claim 15
Dependent Claim
34 words
Process according to claim 11, characterized in that sulphur is applied in a quantity of between 1 and 4 parts by weight to every part by weight of rubber-like copolymer incorporated in the mixture.
Claim 16
Dependent Claim
35 words
Process according to claim 11, characterized in that for the polyolefin polyethylene is applied in a quantity of 1 to 3 parts by weight to every 100 parts of the mixture of bitumen and copolymer.
References Cited (Backward Citations)
US2834742A
Cited
US3336252A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1978-04-21 | 1978-10-21 | 1979-04-22 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1982-04-21 | 1982-10-21 | 1983-04-22 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1986-04-21 | 1986-10-21 | 1987-04-22 | $7700.00 | Window Closed / Lapsed |