Patent US3878232A successfully refreshed from Google Patents.
US3878232A
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Extraction process to improve the quality and yield of crude vegetable oils
Assignee: Central Soya Co Inc
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Filing: 1973-05-21
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Granted: 1975-04-15
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Expires: 1993-05-21
Abstract
Abstract Soybean solids and lecithin oils essentially free from objectionable flavors and odors are obtained by initially extracting undesirable lipid components from oil containing seed materials. These undesirable lipids can be extracted with an azeotropic mixture of hexane and alcohol. A debittered, high lecithin-containiing oil is obtained by admixing the resultant lipid extract with aqueous alcohol and then effectuating an oil phase separation therefrom. The oil, essentially free from the undesirable lipid contaminants, is recovered from the hexane-oil phase.
Inventors
- 👤 Lester P Hayes
- 👤 Ross P Simms
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-07 21:11
CPC Classifications
A; A23; A23J; A23J1/00; A23J1/14; A23J1/142; C; C11; C11B; C11B1/00; C11B1/10
Claims Analysis
Total Claims: 16
Claim 1
Independent Claim
247 words
A PROCESS FOR RECOVERING A LECITHIN RICH OIL FROM VEGETABLE SEED MATERIAL WHICH CONTAINS LIPIDS AND SUBSTANTIALLY ALL OF THE WATER SOLUBLE CONSTITUENTS OF THE NATIVE SEED MATERIAL, SAID PROCESS COMPRISING THE STEPS OF: A. EXTRACTING LIPID CONSTRUCTIONS FROM VEGETABLE SEED MATETRIAL BY SUBJECTING THE SEED MATERIAL TO A LIPID EXTRACTION MEDIUM CONTAINING A HYDROCARBON SOLVENT AND FROM ABOUT 2 TO ABOUT 30 PARTS BY WEIGHT MONOHYDRIC ALCOHOL FOR EACH 80 PARTS BY WEIGHT HYDROCARBON SOLVENT, SAID EXTRACTION OF LIPIDS BEING CONDUCTED UNDER CONDITIONS WHEREBY THE AMOUNT OF ALCOHOL IS MAINTAINED AT A LEVEL OF AT LEAST 2% TO ABOUT 40% BY WEIGHT OF THE VEGETABLE SEED MATERIAL DRY WEIGHT AND THE AMOUNT OF LIPID CONSITUENTS EXTRACTION FROM THE SEED MATERIAL IS AT LEAST EQUAL TO THE AC3-44 LIPID CONTENT OF THE VEGETABLE SEEB MATERIAL PRIOR TO THE EXTRACTION OF THE LIPIDS THEREFROM; B. SEPARATING THE RESULTANT LIPID MISCELLA FROM THE VEGETABLE SEED MATERIAL; C. MIXING THE SEPARATED LIPIDS OF STEP (B) IN THE PRESENCE OF A HYDROCARBON SOLVENT, WATER AND ALCOHOL TO PROVIDE AN ADMIXTURE THEREOF, SAID ADMIXTURE CONTAINING SUFFICIENT AMOUNT OF MONOHYDRIC ALCOHOL AND WATER TO PROVIDE A POLAR PHASE CONTAINING ON A TOTAL WEIGHT BASIS FROM ABOUT 40% TO ABOUT 70% BY WEIGHT MONOHYDRIC ALCOHOL; D. ALLOWING THE ADMIXTURE TO SEPERATE INTO A NON-POLAR PHASE CONTAINING LIPID EXTRACT AND A POLAR PHASE CONTAINING WATER-SOLUBLE ECTRACT; E. PARTITIONING THE POLAR PHASE FROM THE NON-POLAR PHASE; AND F. RECOVERING A LIPID CONCENTRATION FROM THE NON-POLAR PHASE.
Claim 2
Dependent Claim
247 words
A PROCESS FOR RECOVERING A LECITHIN RICH OIL FROM VEGETABLE SEED MATERIAL WHICH CONTAINS LIPIDS AND SUBSTANTIALLY ALL OF THE WATER SOLUBLE CONSTITUENTS OF THE NATIVE SEED MATERIAL, SAID PROCESS COMPRISING THE STEPS OF: A. EXTRACTING LIPID CONSTRUCTIONS FROM VEGETABLE SEED MATETRIAL BY SUBJECTING THE SEED MATERIAL TO A LIPID EXTRACTION MEDIUM CONTAINING A HYDROCARBON SOLVENT AND FROM ABOUT 2 TO ABOUT 30 PARTS BY WEIGHT MONOHYDRIC ALCOHOL FOR EACH 80 PARTS BY WEIGHT HYDROCARBON SOLVENT, SAID EXTRACTION OF LIPIDS BEING CONDUCTED UNDER CONDITIONS WHEREBY THE AMOUNT OF ALCOHOL IS MAINTAINED AT A LEVEL OF AT LEAST 2% TO ABOUT 40% BY WEIGHT OF THE VEGETABLE SEED MATERIAL DRY WEIGHT AND THE AMOUNT OF LIPID CONSITUENTS EXTRACTION FROM THE SEED MATERIAL IS AT LEAST EQUAL TO THE AC3-44 LIPID CONTENT OF THE VEGETABLE SEEB MATERIAL PRIOR TO THE EXTRACTION OF THE LIPIDS THEREFROM; B. SEPARATING THE RESULTANT LIPID MISCELLA FROM THE VEGETABLE SEED MATERIAL; C. MIXING THE SEPARATED LIPIDS OF STEP (B) IN THE PRESENCE OF A HYDROCARBON SOLVENT, WATER AND ALCOHOL TO PROVIDE AN ADMIXTURE THEREOF, SAID ADMIXTURE CONTAINING SUFFICIENT AMOUNT OF MONOHYDRIC ALCOHOL AND WATER TO PROVIDE A POLAR PHASE CONTAINING ON A TOTAL WEIGHT BASIS FROM ABOUT 40% TO ABOUT 70% BY WEIGHT MONOHYDRIC ALCOHOL; D. ALLOWING THE ADMIXTURE TO SEPERATE INTO A NON-POLAR PHASE CONTAINING LIPID EXTRACT AND A POLAR PHASE CONTAINING WATER-SOLUBLE ECTRACT; E. PARTITIONING THE POLAR PHASE FROM THE NON-POLAR PHASE; AND F. RECOVERING A LIPID CONCENTRATION FROM THE NON-POLAR PHASE.
Claim 3
Dependent Claim
24 words
The process according to claim 1 wherein the vegetable seed material has a lipid content ranging from about 10% to about 30% by weight.
Claim 4
Dependent Claim
72 words
The process according to claim 2 wherein after extracting the residual lipids from the vegetable seed, at least a major portion of water-soluble constituents of the vegetable seed material are extracted therefrom with an aqueous extraction medium containing from about 40% to about 70% by weight of an aliphatic alcohol to provide an aqueous miscella thereof and the aqueous miscella is thereafter admixed with the lipid miscella to provide an admixture thereof.
Claim 5
Dependent Claim
41 words
The process according to claim 3 wherein the hydrocarbon solvent consists essentially of hexane, the monohydric alcohol consists essentially of ethanol and the vegetable seed material consists essentially of soybean flakes having from about 20% to about 25% by weight lipid.
Claim 6
Dependent Claim
73 words
The process according to claim 2 wherein the residual lipid extraction medium is comprised of about 8 to about 25 parts by weight monohydric alcohol and 80 parts by weight hydrocarbon with the extraction of residual lipids being conducted under conditions whereby the monohydric alcohol concentration is maintained at a level of at least 5% to about 25% of the total dry weight of the seed material submitted to the lipid extraction medium.
Claim 7
Dependent Claim
38 words
The process according to claim 5 wherein the polar solvent portion of the admixture consists essentially of water and a lower aliphatic alcohol with the alcohol comprising from about 45% to 65% of the total polar solvent weight.
Claim 8
Dependent Claim
29 words
The process according to claim 6 wherein the vegetable seed material consists essentially of soybean flakes having a lipid content ranging from about 20% to about 25% by weight.
Claim 9
Dependent Claim
23 words
The process according to claim 7 wherein the non-polaR hydrocarbon solvent consists essentially of hexane and the monohydric alcohol consists essentially of ethanol.
Claim 10
Dependent Claim
35 words
The process according to claim 1 wherein at least a major portion of the total lipid content of the vegetable seed material has been extracted therefrom prior to the extraction of the residual lipids therefrom.
Claim 11
Dependent Claim
17 words
The process according to claim 9 wherein the vegetable seed material consists essentially of defatted soybean flakes.
Claim 12
Dependent Claim
71 words
The process according to claim 10 wherein the residual lipid extraction medium is comprised of about 8 to about 25 parts by weight ethanol and 80 parts by weight hexane with the extraction of residual lipids being conducted under conditions whereby the ethanol concentration is maintained at a level of at least 5 to about 25 of the total dry weight of the seed material submitted to the lipid extraction medium.
Claim 13
Dependent Claim
39 words
The process according to claim 5 wherein the polar solvent phase of the admixture consists essentially of water and a lower aliphatic alcohol with the alcohol comprising from about 45% to about 65% of the total polar solvent weight.
Claim 14
Dependent Claim
26 words
The process according to claim 12 wherein the polar phase is substantially free from water-soluble seed material constituents and the monohydric alcohol consists essentially of ethanol.
Claim 15
Dependent Claim
12 words
The lipid concentrate prepared in accordance with the process of claim 1.
Claim 16
Dependent Claim
21 words
A lecithin rich oil concentrate prepared in accordance with claim 1 wherein the vegetable seed material consists essentially of soybean flakes.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1978-04-14 | 1978-10-14 | 1979-04-15 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1982-04-14 | 1982-10-14 | 1983-04-15 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1986-04-14 | 1986-10-14 | 1987-04-15 | $7700.00 | Window Closed / Lapsed |