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US3878000A Expired / Lapsed US ⏱️ 0.0 years remaining

Recovery of cobalt-rare earth alloy particles by hydration-disintegration in a magnetic field

Assignee: General Electric Co
•
Filing: 1974-06-03
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Granted: 1975-04-15
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Expires: 1994-06-03
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Abstract

Abstract A process for recovering magnetic alloy particles from a reaction product cake. The cake is placed in a reactor where it is contacted with a flowing water vapor-carrying gas which reacts with its calcium content to disintegrate the cake and produce a hydrated powder comprised substantially of calcium hydroxide and the alloy particles. A magnetic zone is generated into a crosssection of the reactor substantially encircling the inside wall thereof. The zone is generated by at least two poles of opposite polarity running the length of the zone. The hydrated powder is fluidized to dissociate and pass the calcium hydroxide out of the reactor. Finer-sized alloy particles carried by the fluidizing gas into the magnetic zone are subjected to the magnetic field where the poles are rotated or reversed at a rate which reverses the positions of the particles sufficiently to release adherent calcium hydroxide leaving the finer-sized alloy particles substantially within the magnetic zone.

Inventors

  • 👤 Charles M Mcfarland
  • 👤 Theodore B Lerman
  • 👤 Alan C Rockwood

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 18:51
CPC Classifications
B; B22; B22F; B22F9/00; B22F9/16; H; H01; H01F; H01F1/00; H01F1/01; H01F1/03; H01F1/032; H01F1/04; H01F1/06

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 362 words
A PROCESS FOR HYDRATING AND DISINTEGRATING A REACTION PRODUCT CAKE AND RECOVERING THE MAGNETIC PORTION THEREOF, SAID REACTION PRODUCT CAKE BEING COMPRISED OF MAGNETIC ALLOY PARTICLES SUBSTANTIALLY OR COMPLETELY SURROUNDED BY CALCIUM AND OR A CALCIUM COMPOUND SELECTED FROM THE GROUP CONSISTING OF CALCIUM OXIDE, CALCIUM HYDRATE AND CALCIUM NITRIDE, SAID MAGNETIC ALLOY PARTICLES CONSISTING ESSENTIALLY OF RARE EARTH METAL AND A METAL SELECTED FROM THE GROUP CONSISTING OF COLBAT, IRON, MANGANESE AND ALLOYS THEREOF, WHICH COMPRISES PROVIDING A SUBSTANTIALLY VERTICAL REACTOR HAVING A GAS INLET AT ITS LOWER END PORTION AND AN OUTLET AT ITS UPPER END PORTION, PLACING SAID REACTION PRODUCT CAKE IN SAID REACTOR SUBSTANTIALLY BETWEEN SAID GAS OUTLET AND SAID INLET, PASSING A WATER VAPORCARRYING GAS THROUGH SAID GAS INLET TO REACT WITH SAID CALCIUM AND OR SAID CALCIUM COMPOUND CAUSING A SIGNIFICANT VOLUME INCREASE WHICH DISINTEGRATES SAID REACTION PRODUCT CAKE, SAID WATER VAPOR-CARRYING GAS INITIALLY HAVING A TEMPERATURE RANGING FROM ABOUT 0*C TO ABOUT 70*C AND A RELATIVE HUMINITY RANGING FROM ABOUT 5% TO 100%, SAID REACTION PRODUCT CAKE BEING SUBSTANTIALLY INERT TO THE GAS COMPONENT OF SAID WATER VAPOR-CARRYING GAS. SAID WATER VAPOR-CARRYING GAS BEING PASSED THROUGH SAID REACTOR AT A RATE WHICH FLUIDIZES SAID DISINTEGRATED CAKE WITHIN SAID REACTOR AND UNTIL SUBSTANTIAL CONVERSION TO CALCIUM HYDROXIDE IS COMPLETED PRODUCING A SUBSTANTIALLY HYDRATED POWER, PROVIDING MEANS FOR GENERATING A MAGNETIC ZONE BETWEEN SAID GAS INLET AND OUTLET A SIGNIFICANT DISTANCE INTO CROSS-SECTION OF THE REACTOR ENCIRCLING THE INSIDE WALL THEREOF TO A SIGNIFICANT EXTENT AND BEING COMPRISED OF AT LEAST TWO MAGNETIC POLES OF OPPOSITE POLARITY RUNNING THE FULL LENGTH OF SAID ZONE AND SUBSTANTIALLY PARALLEL TO THE ASSOCIATED INSIDE WLL OF THE REACTOR, SAID MAGNETIC POLES BEING ROTATABLE OR REVERSIBLE, PASSING AN INERT GAS THROUGH SAID INLET UPWARDLY TO FLUIDIZE SAID HYDRATED POWER DISASSOCIATING AND CARRYING THE CALCIUM HYDROXIDE THROUGH SAID INLET, SAID MAGNETIC ALLOY PARTICLES OF FINER IZE CARRIED BY SAID FLUIDIZING GAS INTO SAID MAGNETIC ZONE BEING CAUGHT BY THE POLES WHICH ARE ROTATED OR REVERSED AT A RATE SUFFICIENT TO SIGNIFICANTLY REVERSE THE POSIIONS OF THE PARTICLES RESULTING IN RELEASE OF ADHERENT CALCIUM HYDROXIDE LEAVING THE FINER-SIZED PARTICLES WITHIN SAID MAGNETIC ZONE.
Claim 2
Dependent Claim 362 words
A PROCESS FOR HYDRATING AND DISINTEGRATING A REACTION PRODUCT CAKE AND RECOVERING THE MAGNETIC PORTION THEREOF, SAID REACTION PRODUCT CAKE BEING COMPRISED OF MAGNETIC ALLOY PARTICLES SUBSTANTIALLY OR COMPLETELY SURROUNDED BY CALCIUM AND OR A CALCIUM COMPOUND SELECTED FROM THE GROUP CONSISTING OF CALCIUM OXIDE, CALCIUM HYDRATE AND CALCIUM NITRIDE, SAID MAGNETIC ALLOY PARTICLES CONSISTING ESSENTIALLY OF RARE EARTH METAL AND A METAL SELECTED FROM THE GROUP CONSISTING OF COLBAT, IRON, MANGANESE AND ALLOYS THEREOF, WHICH COMPRISES PROVIDING A SUBSTANTIALLY VERTICAL REACTOR HAVING A GAS INLET AT ITS LOWER END PORTION AND AN OUTLET AT ITS UPPER END PORTION, PLACING SAID REACTION PRODUCT CAKE IN SAID REACTOR SUBSTANTIALLY BETWEEN SAID GAS OUTLET AND SAID INLET, PASSING A WATER VAPORCARRYING GAS THROUGH SAID GAS INLET TO REACT WITH SAID CALCIUM AND OR SAID CALCIUM COMPOUND CAUSING A SIGNIFICANT VOLUME INCREASE WHICH DISINTEGRATES SAID REACTION PRODUCT CAKE, SAID WATER VAPOR-CARRYING GAS INITIALLY HAVING A TEMPERATURE RANGING FROM ABOUT 0*C TO ABOUT 70*C AND A RELATIVE HUMINITY RANGING FROM ABOUT 5% TO 100%, SAID REACTION PRODUCT CAKE BEING SUBSTANTIALLY INERT TO THE GAS COMPONENT OF SAID WATER VAPOR-CARRYING GAS. SAID WATER VAPOR-CARRYING GAS BEING PASSED THROUGH SAID REACTOR AT A RATE WHICH FLUIDIZES SAID DISINTEGRATED CAKE WITHIN SAID REACTOR AND UNTIL SUBSTANTIAL CONVERSION TO CALCIUM HYDROXIDE IS COMPLETED PRODUCING A SUBSTANTIALLY HYDRATED POWER, PROVIDING MEANS FOR GENERATING A MAGNETIC ZONE BETWEEN SAID GAS INLET AND OUTLET A SIGNIFICANT DISTANCE INTO CROSS-SECTION OF THE REACTOR ENCIRCLING THE INSIDE WALL THEREOF TO A SIGNIFICANT EXTENT AND BEING COMPRISED OF AT LEAST TWO MAGNETIC POLES OF OPPOSITE POLARITY RUNNING THE FULL LENGTH OF SAID ZONE AND SUBSTANTIALLY PARALLEL TO THE ASSOCIATED INSIDE WLL OF THE REACTOR, SAID MAGNETIC POLES BEING ROTATABLE OR REVERSIBLE, PASSING AN INERT GAS THROUGH SAID INLET UPWARDLY TO FLUIDIZE SAID HYDRATED POWER DISASSOCIATING AND CARRYING THE CALCIUM HYDROXIDE THROUGH SAID INLET, SAID MAGNETIC ALLOY PARTICLES OF FINER IZE CARRIED BY SAID FLUIDIZING GAS INTO SAID MAGNETIC ZONE BEING CAUGHT BY THE POLES WHICH ARE ROTATED OR REVERSED AT A RATE SUFFICIENT TO SIGNIFICANTLY REVERSE THE POSIIONS OF THE PARTICLES RESULTING IN RELEASE OF ADHERENT CALCIUM HYDROXIDE LEAVING THE FINER-SIZED PARTICLES WITHIN SAID MAGNETIC ZONE.
Claim 3
Dependent Claim 17 words
A process according to claim 1 wherein the magnetic alloy particles consist essentially of Co and Sm.
Claim 4
Dependent Claim 18 words
A process according to claim 1 wherein said means is a multi-pole rotatable radially magnetized substantially cylindrical magnet.
Claim 5
Dependent Claim 14 words
A process according to claim 1 wherein said means is an electrically commutated electromagnet.
Claim 6
Dependent Claim 225 words
A process for recovering the magnetic portion of a powdery material comprised substantially of calcium hydroxide and magnetic alloy particles, said alloy particles having an average size less than 40 microns and consisting essentially of rare earth metal and a metal selected from the group consisting of cobalt, iron, manganese and alloys thereof, which comprises providing a substantially vertical reactor having a gas inlet at its lower end portion and an outlet at its upper end portion, placing said powdery material in said reactor between said gas inlet and said outlet, providing means for generating a magnetic zone a significant distance into a cross-section of the reactor significantly encircling the inside wall thereof and being comprised of at least two magnetic poles of opposite polarity running the full length of said zone and substantially parallel to the associated inside wall of the reactor, said magnetic poles being rotatable or reversible, passing an inert gas through said inlet upwardly to fluidize said hydrated powder disassociating and carrying the calcium hydroxide through said outlet, said magnetic alloy particles of finer size carried by said fluidizing gas into said magnetic zone being caught by the poles which are rotated or reversed at a rate sufficient to significantly reverse the positions of the particles resulting in release of adherent calcium hydroxide leaving the finer-sized particles within said magnetic zone.
Claim 7
Dependent Claim 225 words
A process for recovering the magnetic portion of a powdery material comprised substantially of calcium hydroxide and magnetic alloy particles, said alloy particles having an average size less than 40 microns and consisting essentially of rare earth metal and a metal selected from the group consisting of cobalt, iron, manganese and alloys thereof, which comprises providing a substantially vertical reactor having a gas inlet at its lower end portion and an outlet at its upper end portion, placing said powdery material in said reactor between said gas inlet and said outlet, providing means for generating a magnetic zone a significant distance into a cross-section of the reactor significantly encircling the inside wall thereof and being comprised of at least two magnetic poles of opposite polarity running the full length of said zone and substantially parallel to the associated inside wall of the reactor, said magnetic poles being rotatable or reversible, passing an inert gas through said inlet upwardly to fluidize said hydrated powder disassociating and carrying the calcium hydroxide through said outlet, said magnetic alloy particles of finer size carried by said fluidizing gas into said magnetic zone being caught by the poles which are rotated or reversed at a rate sufficient to significantly reverse the positions of the particles resulting in release of adherent calcium hydroxide leaving the finer-sized particles within said magnetic zone.
Claim 8
Dependent Claim 17 words
A process according to claim 5 wherein said magnetic alloy particles consist essentially of Co and Sm.

References Cited (Backward Citations)

US2633987A Cited
US2683685A Cited
US3625779A Cited
US3687284A Cited
US3748193A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-04-14 1978-10-14 1979-04-15 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-04-14 1982-10-14 1983-04-15 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-04-14 1986-10-14 1987-04-15 $7700.00 Window Closed / Lapsed

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